Cross-linked poly(ethylene vinyl acetate) (EVA)/low density polyethylene (LDPE)/metal hydroxides composites for wire and cable applications

Formulations of chemically cross-linked poly(ethylene vinyl acetate) (EVA) and low density polyethylene (LDPE) blends containing metal hydroxides flame retardants such as aluminum hydroxide (ATH) and magnesium hydroxide (MH) were prepared. Comparison of both type of metal hydroxides in respect of their influence on flammability as well as mechanical, thermal, and electrical properties of EVA/LDPE composites is presented. Most of the investigated properties are better for composites containing MH in comparison with composites containing ATH. Influence of various EVA/LDPE ratios on investigated properties is presented as well. Importance of improving compatibility using compatibilizers to improve some of the investigated properties is described. Polyethylene grafted with maleic anhydride (PEgMA) was found to be better compatibilizer for ATH than vinyl silanes.     

Finite element analysis and structural design of pretensioned inverted T-beams with web openings

This paper presents the results of a research project aimed at providing standard circular web openings to the popular precast pretensioned inverted T-beam. Opening size and placement and required materials strengths were investigated. In this paper the nonlinear analysis and design of simply supported pretensioned inverted T-beam with circular web openings are presented. Two design parameters are varied: opening location and number of openings. The results from nonlinear finite element analysis were substantiated by test results from five pretensioned inverted T-beams with web opening and one solid beam. Good agreement is shown between the theoretical and the experimental results. The test results obtained from this investigation show that the performance of the specimens with web openings is almost identical to that of the specimen without web openings. A simple design method for pretensioned inverted T-beam with circular web openings is proposed.     

Microwave Radiometer Radio-Frequency Interference Detection Algorithms: A Comparative Study

Two algorithms used in microwave radiometry for radio-frequency interference (RFI) detection and mitigation are the pulse detection algorithm and the kurtosis detection algorithm. The relative performance of the algorithms is compared both analytically and empirically. Their probabilities of false alarm under RFI-free conditions and of detection when RFI is present are examined. The downlink data rate required to implement each algorithm in a spaceborne application is also considered. The kurtosis algorithm is compared to a pulse detection algorithm operating under optimal RFI detection conditions. The performance of both algorithms is also analyzed as a function of varying characteristics of the RFI. The RFI detection probabilities of both algorithms under varying subsampling conditions are compared and validated using data obtained from a field campaign. Implementation details, resource usage, and postprocessing requirements are also addressed for both algorithms.     

Ultra acidic strong cation exchange enabling the efficient enrichment of basic phosphopeptides

We present a straightforward method to enrich phosphopeptides with multiple basic residues, an under-represented class in common enrichment strategies. Our method is based on a two-dimensional strong cation exchange (SCX) strategy, operating at two different acidic pHs, enabling both separation and enrichment of different classes of phosphopeptides. The principle of enrichment is based on the change of net charge of phosphorylated peptides under strong acidic conditions in the second SCX, whereas the net charge of regular peptides remains unchanged, thus enabling separation based on net charge. Application of our tandem SCX approach to a modest amount of human cells allowed the identification of over 10,000 unique "basic" phosphopeptides of which many represent putative targets of basophilic kinases.     

MHD natural convection inside an inclined trapezoidal porous enclosure with internal heat generation or absorption subjected to isoflux heating

A steady laminar two‐dimensional magneto‐hydrodynamic natural convection flow in an inclined trapezoidal enclosure filled with a fluid‐saturated porous medium is investigated numerically using a finite difference method. The left and right vertical sidewalls of the trapezoidal enclosure are maintained at a cold temperature. The horizontal top wall is considered adiabatic while the bottom wall is subjected to isoflux heating. A volumetric internal heat generation or absorption is embedded inside the trapezoidal enclosure while an external magnetic field is applied on the left sidewall of the enclosure. In the current work, the following parametric ranges of the non‐dimensional groups are used: Hartmann number is varied as , Darcy number is taken as , 10^?4, and 8 × 10^?5, Rayleigh number is varied as , Prandtl number is considered constant at Pr = 0.7, the dimensionless internal heat generation or absorption parameter is varied as Δ = ?0.2, 0, 1, and 2.0, while the trapezoidal enclosure inclination angle is varied as . The results indicated a strong flow circulation occurs when the Darcy and the Rayleigh numbers are high. In addition, it is found that the Hartmann number, internal heat generation or absorption parameter and inclination angle have an important role on the flow and thermal characteristics. It is also found that when the enclosure inclination angle and Hartmann number increase the average Nusselt number along the hot bottom wall decreases. © 2012 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.21013     

Effects of diameter ratio of adiabatic circular cylinder and tilt angle on natural convection from a square open tilted cavity

A numerical analysis is carried out to study the performance of natural convection inside a square open tilted cavity filled with air. An adiabatic circular solid cylinder is placed at the center of the cavity and the sidewall in front of the breathing space is heated by a constant heat flux. The top and bottom walls are kept at the ambient constant temperature. Two‐dimensional forms of Navier–Stokes equations along with the energy equations are solved using the Galerkin finite element method. Results are obtained for a range of Grashof numbers from 10³ to 10⁶ at Pr = 0.71 while the tilt angle varies from 0 to 45° and the diameter ratio of the cylinder is considered to be 0.2, 0.3, and 0.4 with constant physical properties. The parametric studies for a wide range of cylinder diameter ratios and cavity tilt angles show significant features of the present problem in terms of stream functions and temperature profiles. The computational results indicate that the heat transfer coefficient is strongly influenced by the above governing parameters. It is also found that the average Nusselt number decreases when the diameter ratio increases. © 2012 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.21001     

Status of biodiesel research and development in Pakistan

Performance of biodiesel in engines is well established and biodiesel is currently adjudged as a low carbon fuel with the most potential of replacing fossil fuels. The fossil fuel sources are dwindling in Pakistan resulting in importation of about 8.1 million tonnes at approximately US$ 9.4 billion per annum. In the ambit of this justification, augmenting the energy scarce resources in Pakistan through intense harnessing of the varied biodiesel sources can adequately address the deficiency and can ensure energy security. Towards this end, the progress attained in biodiesel related researches in Pakistan are evaluated and presented with the view of highlighting ways of achieving the target set by the Government. A feedstock that drew less attention is spent triglycerides, and the little work reported by some organizations appeared promising. Now the onus is upon organizations such as the Alternative Energy Development Board and Pakistan State Oil to harness the research results from several indigenous Universities and develop a full-scale biodiesel economy in Pakistan.     

On the electronic nature of silicon and germanium based oxynitrides and their related mechanical,optical and vibrational properties as obtained from DFT and DFPT

Electronic structure, bonding and optical properties of the orthorhombic oxynitrides Si₂N₂O and Ge₂N₂O are studied using the density function theory as implemented in pseudo-potential plane wave and full-potential (linearized) augmented plane wave plus local orbitals methods. Generalized gradient approximation is employed in order to determine the band gap energy. Indeed, the Si₂N₂O exhibits a large direct gap whereas Ge₂N₂O have an indirect one. Bonding is analyzed via the charge densities and Mulliken population, where the role of oxygen is investigated. The analysis of the elastic constants show the mechanical stability of both oxynitrides. Their bulk and shear modulus are slightly smaller than those reported on nitrides semiconductors due to the oxygen presence. The optical properties, namely the dielectric function, optical reflectivity, refractive index and electron energy loss, are reported for radiation up to 30 eV. The phonon dispersion relation, zone-center optical mode frequency, density of phonon states are calculated using the density functional perturbed theory. Thermodynamic properties of Si₂N₂O and Ge₂N₂O, such as heat capacity and Debye temperature, are given for reference. Our study suggests that Si₂N₂O and Ge₂N₂O could be a promising potential materials for applications in the microelectronics and optoelectronics areas of research.     

Triple junction transport and the impact of grain boundary width in nanocrystalline Cu

Triple junctions (TJ), singular topological defects of the grain boundary (GB) structure, get a dominant role for grain growth and atomic transport in nanocrystalline matter. Here, we present detailed measurements by atom probe tomography, even of the temperature dependence of TJ transport of Ni in nanocrystalline Cu in the chemical regime of interdiffusion. An unexpected variation of the effective width of merging GBs with temperature is detected. It is demonstrated that proper measurement of TJ transport requires taking into account this remarkable effect. TJ diffusion is found to be a factor of about 200 faster than GB diffusion. Its activation energy amounts to only two-thirds of that of the GB.     

Repeated oral dose toxicity of iron oxide nanoparticles: biochemical and histopathological alterations in different tissues of rats

Iron oxide (Fe2O3) nanoparticles are widely used in different fields of nanotechnology. However, studies on its toxicological effects in humans and the environment are scarce. Therefore in this investigation 28 days repeated dose oral toxicity studies were conducted on Fe2O3-30 nanoparticles and its counterpart Fe2O3-Bulk with special reference to target biochemical enzymes and histopathological changes in different tissues of female albino Wistar rats. The alterations observed after Fe2O3-30 treatment in various tissues of exposed rats were dose dependent. Low dose was less effective than medium and high doses with low dose demonstrating "no observed adverse effect" (NOAEL). Further, high dose treated rats showed toxic sign and symptoms but no mortality. Due to the repeated doses of Fe2O3-30 nanoparticles, significant inhibition was observed in total, Na(+)-K+, Mg2+ and Ca(2+)-ATPases in brain of exposed rats. Similarly, significant inhibition was recorded in RBC and brain acetylcholinesterase indicating that both synaptic transmission and nerve conduction were affected by this compound. Fe2O3-30 significantly increased aspartate amino transferase, alanine amino transferase and lactate dehydrogenase in serum and liver, whereas, these enzymes were significantly decreased in kidney indicating tissue necrosis and possible leakage of these enzymes into the blood stream. Increased levels of these enzymes in liver as well as in serum might be an adaptive mechanism due to the stress of iron nanoparticles. High dose treated rats of Fe2O3-30 showed dilated central vein, perivascular round cell collections in liver along with focal areas of necrosis, whereas kidney showed focal tubular damage and red pulp congestion, whereas prominent white pulp indices were observed in spleen. However, histopathological analysis of heart and brain tissues failed to show any adverse changes in their architecture exposed to repeated doses of Fe2O3-30 when compared with controls. Fe2O3-Bulk did not induce any adverse effects in either biochemical parameters or histopathology in the treated rats and the changes observed were near to controls and mostly insignificant, indicating that the counter part of nanoparticles i.e., bulk material is less potent than the nanoparticles in causing toxicity in the exposed animals. These results suggested that as particle size decreases, this iron nanoparticle showed increased toxicity, even though the same material is relatively inert in bulk form. The changes observed in these target enzyme activities could be useful as biomarkers of exposure to nanoparticles.