Optimization of the activity of CaO/Al2O3 catalyst for biodiesel production using response surface methodology

In this work the response surface methodology (RSM) in conjunction with the central composite design (CCD) were used to optimize the activity of CaO/Al₂O₃ solid catalysts for the production of biodiesel. In order to measure the catalyst activity, we used palm oil as a representative raw material for the conversion to biodiesel. The biodiesel production was carried out in a batch laboratory scale reactor. The results showed that both the calcination temperature and the amount of calcium oxide loaded on the support had significant positive effects on the biodiesel yield. The maximum basicity and biodiesel yield obtained were about 194 μmol/g and 94%, respectively. Overall, the catalyst showed high performance at moderate operating conditions and its activity was maintained after two cycles.     

Effect of Doping of Zn and Ca into ErBa2Cu3O7?δ Superconductor Prepared via Co-precipitation Method

Zn- and Ca-doped ErBa₂Cu₃O_7−δ were successfully prepared via coprecipitation method using metal acetates as the starting salts. The precipitated samples were calcined for 20 h at 900 °C and sintered at 920 °C for 24 h. All heat treatments were carried out under oxygen environment. Results show that there is a selectivity of the doping site depending on the ionic radius of the dopant. Furthermore, increase in the critical temperature, T _c , was observed in 0.05 mole of calcium and zinc doped samples. The difference in ionic radius of the dopant led to the increase in porosity as the ionic radius decreases. On the other hand, structural distortion increased as the difference of ionic radius became larger.     

Preparation,FTIR spectroscopic characterization and isothermal stability of differently doped conductive fibers based on polyaniline and polyacrylonitrile

Conductive fibers based on polyaniline (PANI) and polyacrylonitrile (PAN) were obtained by stirring with magnetic bar. This research was conducted to investigate conducting fibers of polyaniline:polyacrylonitrile (PANI:PAN) composite with different weight ratios of aniline in PAN matrix. The fibers were prepared by stirring process. The best conductivity behavior of the fibers was obtained with 5 mL of aniline. The fibers obtained were characterized using Fourier-transform infrared spectra (FTIR), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). The variation of electrical conductivity with different type doping agents (HCl, H₂SO₄ and HClO₄) and the stability in terms of DC electrical conductivity retention was studied in an oxidative environment by isothermal characteristics.     

Effects of Pretreatment on Properties of Gelatin from Perch (Lates Niloticus) Skin

Fish gelatins obtained from perch fish skin pretreated with various solutions containing acetic acid, sodium hydroxide (NaOH) and sodium chloride (NaCl) were successfully characterized for their nanostructure pattern using field emission scanning electron microscopy. Each pretreatment transformed collagen to gelatin with fibril, zigzag cracks, straight rods, and cross-linked rods nanostructure patterns. Pretreatment solutions also affect the gel yield, gel strength, amino acid profile, and functional groups in perch gelatin as analyzed by Fourier transform infrared spectroscopy. Samples pretreated with NaCl, NaOH, and acetic acid solution showed the highest gel yield (22.84%) and gel strength (179.84 g). Fourier transform infrared spectra for perch gelatins also revealed weak C–N amide II and III bond stretches as well as weak C=O bond stretch.     

Effect of inoculation and nodularisation treatment temperature on recalescence and eutectic undercooling temperature in Spheroidal graphite (SG) cast iron

In this study, the effect of inoculant composition and nodularisation treatment temperature on recalescence temperature (TER) and undercooling temperature (TEU) in SG iron has been studied by using thermal analysis. 0·1, 0·2 and 0·3 wt-% of three types of inoculants Ca,Ce,Al–FeSi, Ca,Sr,Al–FeSi and Ca,Ba,Al–FeSi were used as so called stream inoculation. Ca,Ce,Al–FeSi was found to be the most potent one in reducing both recalescence (?T _r ) and eutectic undercooling (?T). The nodule count has also been found higher in Ca,Ce,Al–FeSi inoculated SG iron samples compared to other two inoculants. It has been observed that higher the nodule count lower is the ?T _r and ?T and vice versa. The recalescence and shrinkage relationship of 24 heats of differential case castings has been established; it was observed that the number of castings containing shrinkage in respective heats increase as the recalescence and nodularisation treatment temperature increases.     

Single-Row Transformation of Complete Graphs

A complete graph is a fully-connected graph where every node is adjacent to all other nodes in the graph. Very often, many applications in science and engineering are reducible to this type of graph. Hence, a simplified form of a complete graph contributes in providing the solutions to these problems. In this paper, we present a technique for transforming a complete graph into a single-row routing problem. Single-row routing is a classical technique in the VLSI design that is known to be NP-complete. We solved this problem earlier using a method called ESSR, and, the same technique is applied to the present work to transform a complete graph into its single-row routing representation. A parallel computing model is proposed which contributes in making the problem modular and scalable. We also discuss the application of this work on the channel assignment problem in the wireless cellular telephone networks.     

The Implementation of Innovation by a Multinational Operating in Two Different Environments: A Comparative Study

The aim of the paper is to examine the innovation initiatives and processes followed by two subsidiaries of a German multinational company operating in Europe and Asia and to compare the innovativeness of their operations in these two locations. The study examined the innovation processes followed by the two subsidiary firms operating in Germany and Malaysia, the actual problems faced by them, the critical success factors involved in the implementation, and the work climates of the firms. Interestingly, it was found that both firms followed similar innovation processes. Nevertheless, different types of problems and critical success factors were applicable to both firms. The results showed that the Malaysian subsidiary faced more behavioural problems while the German subsidiary encountered more technical problems. Further, the study showed that a lack of knowledge was the common problem faced equally by both firms. The study demonstrated that the German subsidiary had better working climate compared to its counterpart in Malaysia. Finally, the German subsidiary was found to be more innovation–active than the Malaysian subsidiary as it introduced more types of innovation, interacted with more types of entity in the external environment and introduced more types of training.     

A systematic technique for cost-effective CO<Subscript>2</Subscript> emission reduction in process plants

There has been growing interests to reduce the environmental impact caused by greenhouse gas emissions from process plants through various energy conservation strategies. CO₂ emissions are closely linked to energy generation, conversion, transmission and utilisation. Various studies on the design of energy-efficient processes, optimal mix of renewable energy and hybrid power system are driven to reduce reliance on fossil fuel as well as CO₂ emissions reduction. This paper presents a systematic technique in the form of graphical visualisation tool for cost-effective CO₂ emission reduction strategies in industry. The methodology is performed in four steps. The first step involves calculating the energy consumption of a process plant. This is followed by identification of potential strategies to reduce CO₂ emissions using the CO₂ management hierarchy as a guide. In the third step, the development of “Investment” versus “CO₂ Reduction” (ICO₂) plot is constructed to measure the optimal CO₂ emission reductions achieved from the implementation of possible CO₂ reduction strategies. The Systematic Hierarchical Approach for Resilient Process Screening (Wan Alwi and Manan in AIChE J 11:3981–3988, 2006) method is used in the fourth step via substitution or partial implementation of the various CO₂ reduction options in order to meet the cost-effective emission reduction within the desired investment limit or payback period (PP). An illustrative case study on a palm oil refinery plant has been used to demonstrate the implementation of the method in reduction of CO₂ emissions. The developed graphical tool provides an insight-based approach for systematic CO₂ emission reduction in the palm oil refinery considering both heat and power energy sources. Result shows that 31.2 % reduction in CO₂ emissions can be achieved with an investment of USD 38,212 and PP of 10 months based on the present energy prices in Malaysia.     

Effects of computer-based educational achievement test on test performance and test takers’ motivation

There has been an increasing interest in recent years in developing and using computer-based tests in educational assessment. To replace paper-based tests with computer-based ones, the standards for developing computerized-assessment (International Test Commission., 2004) requires equivalent test scores to be established for the new computer-based test and the conventional paper-based test. However, in most test mode comparability studies, the actual test items used have been identical, and yet significant differences have been found in test scores in paper-based and computer-based modes. This has been reported for several subjects, including science, languages and mathematics. The validity of using computer-based tests in educational assessment must therefore be questioned. This study involves a biology test and a biology motivation questionnaire using a Solomon four-group experimental design to examine the validity of the computer-based test and its effects on test performance and the motivation of test-takers. The findings provide supportive evidence for the validity of computer-based test in educational assessment.