Simultaneous determination of Sunset yellow and Tartrazine in soft drinks using gold nanoparticles carbon paste electrode

The monitoring of synthetic dyes in foods is very important due to their potential harmfulness to human beings. Herein, a carbon-paste electrode (CPE) that is chemically modified with gold nanoparticles (nAu) was fabricated and used for the determination of Sunset yellow (SY) and Tartrazine (Tz). Cyclic and differential pulse voltammetry (CV and DPV) results revealed two well-resolved anodic peaks for SY and Tz with remarkably increase in oxidation signals of these colourants. Based on this, a novel electrochemical method was developed for the simultaneous determination of SY and Tz. High sensitivity and selectivity, sub-micromolar detection limit, high reproducibility and regeneration of the electrode surface by simple polishing make the nAu-CPE electrode very suitable for the determination of SY and Tz in commercially available soft drinks. The detection limits was 3.0 × 10⁻⁸ and 2.0 × 10⁻⁹ mol l⁻¹ for SY and Tz, respectively, which are remarkably lower than those reported previously for SY and Tz using other modified electrodes.     

Electron back-scattered diffraction and nanoindentation analysis of nanostructured Al tubes processed by multipass tubular-channel angular pressing

Microstructural evolution and mechanical properties of nanostructured 1060 aluminum alloy tubes processed by tubular-channel angular pressing (TCAP) process were investigated using electron back-scattered diffraction (EBSD), transmission electron microscopy (TEM) and nanoindentation analyzes. EBSD scans revealed a homogeneous ultrafine grained microstructure after the third passes of the TCAP process. Apart from that the mean grain sizes of the TCAP processed tubes were refined to 566 nm, 500 nm and 480 nm respectively after the first, second and third passes. The results showed that after the three TCAP passes, the grain boundaries with a high angle comprised 78% of all the boundaries. This is in comparison to the first pass processed sample that includes approximately 20% HAGBs. The TEM inspection afforded an appreciation of the role of very low-angle misorientation boundaries in the process of refining microstructure. Nanoindentation results showed that hardness was the smallest form of an unprocessed sample while the largest form of the processed sample after the three passes of TCAP indicated the highest resistant of the material. In addition, the module of elasticity of the TCAP processed samples was greater from that of the unprocessed sample.     

An improved mechanism for capacity payment based on system dynamics modeling for investment planning in competitive electricity environment

Many countries have experienced restructuring in their electric utilities. This restructuring has presented the power industries with new challenges, the most important of which is long-term investment planning under uncertain conditions. This paper presents an improved mechanism for capacity payment. The mechanism has been investigated based on system dynamic modeling. In our proposed mechanism, generators will recover a part of their investment through capacity payment. While the payment for any plant remains constant during the operation period, it depends on the investment needed to build it. The main factors affecting long-term planning have been considered in our model. The approach can be used to investigate the effects of fixed as well as variable capacity payment in market investment. We used the probability density function of load as a new concept to calculate average market price. Delays in unit constructions, estimation of demand, and market capacity growth during construction periods have been included in the proposed algorithm as parameters, which affect the regulator's decision for changing capacity payment. The model can be used by regulators to investigate strategies that may affect the fluctuations in the market.     

基于耗散函数的叶顶泄漏流动非定常数值模拟

更进一步的改善间隙泄漏流动需要对其复杂的流动结构作深入的认识，若不能给出间隙泄漏流动影响更真实的表述将导致对其研究无法进行。为了更深入的认识涡轮叶栅流动粘性耗散的细节及分布，作者采用商用N-S求解器对具有动叶顶部间隙的涡轮级非定常流场进行了数值模拟和研究。本文引入耗散函数对间隙泄漏流动的粘性耗散进行评估，这种方法是对粘性影响带来的粘性耗散的最简单也是最直接模拟和计算方法。     

Environmental sustainability assessment of buildings in hot climates: the case of the UAE

Sustainability has acquired great importance due to the negative impact of various developments on the environment. The rapid growth during the last decade has been accompanied by active construction which, in some instances, neglected the impact on the environment and human activities. The impact of developments on the traditional heritage has not been taken into consideration although the latter represents a rich resource for sustainable building practices. The study aims at examining these developments in the UAE using an assessment tool that measures the performance of buildings in terms of their sustainability. This study attempts to: (a) develop a comprehensive definition of sustainability to suit UAE needs; (b) classify sustainable building practices at international and regional levels; (c) assess building performance in the UAE; and (d) establish guidelines for future sustainable architecture. T-Sol software was used to predict the CO₂ emission level in selected buildings in the UAE. Results illustrate that average energy use/area in domestic buildings is high (213 kWh/m²) and public buildings showed less sustainable measures in terms of energy features, energy performance and environmental features. Issues considered in the assessment of buildings such as energy use per square metre and CO₂ emission are alarming. Traditional buildings in the UAE were more sustainable than contemporary buildings, however.     

Generalized Gabor filters for palmprint recognition

Orientation-based coding approaches have recently been widely employed for face and palmprint recognition where generally, one starts with a set of Gabor filters to extract orientation information and then proceeds to code dominant orientations as features for each point of the palmprint. However, as the Gabor filter is developed to model two-dimensional receptive fields of simple cells in straits cortex, it might not be our best choice when dealing with curved and complex structures inherent in the palmprint texture. Motivated by this intuition, this paper shows that Gabor filters are a subset of a bigger family of filters which we refer to as generalized Gabor filter (GGF). Depending on the values of its parameters, a GGF takes a rather diverse shapes and orientations, which results in a potentially finer feature extraction capability. We show this improved capability by employing GGFs in the palmprint verification process. In applying our method, two different sub-banks of GGFs are defined for the orientation-based feature extraction of palmprints, and when compared with Gabor filters, it will be shown that GGFs have the upper hand in capturing orientation features. Furthermore, compared with the competitive code—one of the well-known orientation-based coding methods—the number of employed orientations is reduced to half. This would automatically compensate for a double usage of the filter banks, which otherwise could increase the time complexity of using GGFs. These ideas are further elaborated using a set of experiments on PolyU II and PolyU 2D/3D palmprint databases. The results show the preeminence of using GGFs both in terms of accuracy and efficiency.     

Bioactive Peptides: Synthesis,Sources, Applications,and Proposed Mechanisms of Action

Bioactive peptides are a group of biological molecules that are normally buried in the structure of parent proteins and become active after the cleavage of the proteins. Another group of peptides is actively produced and found in many microorganisms and the body of organisms. Today, many groups of bioactive peptides have been marketed chemically or recombinantly. This article reviews the various production methods and sources of these important/ubiquitous and useful biomolecules. Their applications, such as antimicrobial, antihypertensive, antioxidant activities, blood-lipid-lowering effect, opioid role, antiobesity, ability to bind minerals, antidiabetic, and antiaging effects, will be explored. The types of pathways proposed for bioactive applications will be in the next part of the article, and at the end, the future perspectives of bioactive peptides will be reviewed. Reading this article is recommended for researchers interested in various fields of physiology, microbiology, biochemistry, and nanotechnology and food industry professionals.     

Effect of Immersion Time on Corrosion Behavior of Single-Phase Alloy and Nanocomposite Bismuth Telluride-Based Thermoelectrics in NaCl Solution

The corrosiveness of bismuth telluride-based thermoelectric materials (n-type single-phase alloy and a nanocomposite with MoS₂ nanoinclusions), in 0.1 molar solution of sodium chloride (NaCl), was investigated. The electrochemical impedance spectroscopy curves obtained after 1, 24, 48 and 72 h immersion time revealed the enhancement of the corrosion resistance of the nanocomposite specimen in a 0.1 molar NaCl solution in comparison with the single-phase bismuth telluride-based alloys, and the passivity increased by immersion time up to 72 h. The nanocomposite sample with submicron grains provided suitable nucleation sites for passive film nucleation that led to higher protective behavior.