Electrode and electrolyte materials for electrochemical capacitors

Among different electric energy storage technologies electrochemical capacitors are used for energy storage applications when high power delivery or uptake is needed. Their energy and power densities, durability and efficiency are influenced by electrode and electrolyte materials however due to a high cost/performance ratio; their widespread use in energy storage systems has not been attained yet.Thanks to their properties such as high surface area, controllable pore size, low electrical resistance, good polarizability and inertness; activated carbons derived from polymeric precursors are the most used electrode materials in electrochemical capacitors at present. Other electrode materials such as shaped nano-carbons or metal oxides are also investigated as electrode materials in electrochemical capacitors, but only as useful research tools.Most commercially used electrochemical capacitors employ organic electrolytes when offering concomitant high energy and high power densities. The use of aqueous based electrolytes in electrochemical capacitor applications is mainly limited to research purposes as a result of their narrow operating voltage. Recent studies on room temperature ionic liquids to be employed as electrolyte for electrochemical capacitor applications are focused on fine tuning their physical and transport properties in order to bring the energy density of the device closer to that of batteries without compromising the power densities.In this paper a performance analysis, recent progress and the direction of future developments of various types of materials used in the fabrication of electrodes for electrochemical capacitors are presented. The influence of different types of electrolytes on the performance of electrochemical capacitors such as their output voltage and energy/power densities is also discussed.     

Prioritizing of wind farm locations for hydrogen production: A case study

Many advantages of renewable energies, especially wind energy, such as abundance, permanence, and lack of pollution has encouraged many industrialized and developing countries to focus more on these clean and economic sources of energy. Identifying a good location that is suitable for the construction of a wind farm is one of the important initial steps in harnessing wind energy which is assessed this study. The purpose of this study is to prioritize and rank 13 cities of Fars province in Iran, in terms of their suitability for the construction of a wind farm. Six important criteria were used to prioritize and rank the cities. Wind power density is the most important criterion among these criteria which is calculated by obtaining the 3-h wind speed data between 2004 and 2013. DEA (Data Envelopment Analysis) method is used for prioritizing and ranking cities, and then AHP (Analytical Hierarchy Process), and FTOPSIS (Technique for Order of Preference by Similarity to Ideal Solution) methods are used to assess the validity of results. It is concluded that Izadkhast city is the suggested location for the construction of wind farm. The utilizing a wind-hydrogen energy conversion system will result in a substantial amount of hydrogen production (averagely 21.9 ton/year) when a 900 kW wind turbine is installed in this location.     

Composition and biological activities of essential oils from four Heracleum species

The composition of essential oils from aerial parts of Heracleum persicum, a widely used medicinal plant, and three other Heracleum species growing wild in Iran were analysed by GC and GC–MS. Myristicin (53.6%), (E)-anethole (25.0%), hexyl butanoate (29.7%) and elemicin (41.1%) were the major compounds of Heracleum pastinacifolium, H. persicum, Heracleum rechingeri and Heracleum transcaucasicum, respectively. Cytotoxic activity assessed on three human cancer cell lines (HeLa, LS180 and Raji), showed that essential oils from H. transcaucasicum (IC₅₀ values; 0.362–0.594 mg/ml) followed by H. pastinacifolium (0.497–1.398 mg/ml) had moderate antitumoral activities. In the DPPH radical scavenging assay, H. pastinacifolium and H. persicum oils showed the highest activities with IC₅₀ values of 7.3 and 7.4 mg/ml, respectively. Antioxidant activity correlated well with the total phenolic content of the oils. None of the essential oils showed significant antimicrobial activities.     

Eye gesture blink password: a new authentication system with high memorable and maximum password length

Multimedia Tools and Applications - Authentication systems in which eye is used for entering the password are categorized into two gaze-based and gesture-based groups. In the accurate...     

Lessons from metal oxides to find why Nature selected manganese and calcium for water oxidation

The problem of finding a way to store energy from abundant sources such as sunlight, wind or geothermal heat is critical. Water splitting toward hydrogen production is a very promising way for the goal. Although the cathodic reaction is of major interest in hydrogen production, the concurrent anodic water oxidation, which provides cheap electrons for the cathodic reaction, is a limitation for hydrogen formation. The best water-oxidizing catalyst was found by Nature million years ago and used in plants, algae and cyanobacteria. We believe learning from the natural system is very promising, because Nature has been successfully splitting water for millions of years, using an inexpensive and environmentally friendly MnCa oxido cluster. Herein we study the phenol oxidation by some nano-sized metal oxides in the presence of H₂O₂. As metal oxides are functional and structural models for the water-oxidizing complex in Photosystem II, the results can be expanded for the natural site. We suggest that low organic compound oxidation under water oxidation is an important issue to select manganese and calcium ions for water oxidation.     

A multi-objective decision approach for optimal augmentation and expansion of transmission network

In this paper, the authors propose a new multi-objective decision making approach for optimal augmentation and expansion of transmission network. Fundamental elements of the proposed approach are value of reliability and electricity market. Investment Cost (IC), Total Congestion Cost (TCOC) and Social Welfare (SW) and also Average Load Interruption Cost (ALIC) are the four objectives considered in the optimization, while short-term and long-term constraints, are modeled as constraints. The proposed model is one of complicated non-convex optimization problem having a nonlinear, mixed-integer nature. Therefore, a new and robust hybrid Improved Harmony Search Algorithm (IHSA) and Quadratic Programming (QP) is used and followed by a Fuzzy Satisfying Method (FSM) to determine the final optimal solution. The feasibility and capabilities of the proposed approach are tested on the 6-machine 8-bus test system. The detailed results of the case studies are presented and thoroughly analyzed. The obtained results illustrate the sufficiency and profitableness of the newly developed method in augmentation and expansion of transmission network when, compared with other methods.     

Buried Target Imaging: A Comparative Study

A wide variety of qualitative methods have been proposed for microwave imaging. It is difficult to select only one of these methods based on a priori information and measurement equipment to achieve a reliable reconstruction. Various arrangements for antennas to be used in, for instance, have been proposed which have direct impacts on the complexity of inverse methods as well as the quality of output images. In this study, four qualitative methods of the linear sampling method (LSM), time reversal (TR), diffraction tomography (DT), and back-projection (BP) have been reviewed in a 2D scenario; the performance of the methods is compared within the same framework of a multi-static configuration. The goal is to compare their resolutions and determine their advantages and drawbacks. It is shown that LSM provides the best azimuth resolution but the worst range resolution. It is almost invariant to dielectric contrast and is appropriate for a wide range of dielectric contrasts and relatively large objects. It is also shown that at relatively low dielectric contrasts, TR images are most similar to the true object, show fewer artifacts, and offer high immunity to noise. While suffering from more artifacts due to the presence of some ghost images, DT offers the best range resolution. The results also show that BP has the worst azimuth resolution when reconstructing deeply-buried targets, although its implementation is straightforward and not computationally complex.     

Study on automatic control of arc gap in robotic TIG welding

This paper presents a method for automatic control of arc length in tungsten inert gas (TIG) welding process using the arc voltage. By using this method, the role of operator in arc length control is played by an automatic control system based on a predefined arc voltage value for any special welding operation. A dynamic model for feed-rate mechanism and the relation between variations of arc length and voltage are described in details. Using a proportional-integral controller, variations of arc length in welding path is compensated with an automatic feed-rate mechanism in a normal direction to the welding path. By keeping the voltage constant during the process, a stable weld with higher quality and better appearance is obtained specially in welding of uneven surfaces. Theoretical and practical investigations show that the suggested method is able to control the TIG welding process successfully. Test results show that an accurate weld is obtained without the interference of the operator, and by comparing the predefined values of arc voltage with what is practically obtained, the welding gap is automatically adjusted.