Berechnung der Schubspannungs-Abgleitungs-Kurven aus Druckversuchen an mittelorientierten Einkristallen

Mittelorientierte Einkristalle verformen sich im Druckversuch über ihre Länge nicht homogen. Es wird ein Rechenverfahren angegeben, in dem diese Inhomogenitäten berücksichtigt werden und Schubspannungs-Abgleitungskurven für den homogen verformten Teil der Probe errechnet werden können. Die Rechnung wird an experimentellen Ergebnissen von Fe—6 Gew.% Si überprüft.     

Microstructure and Compression Strength of Novel TRIP‐Steel/Mg‐PSZ Composites

Novel composites on basis of austenitic stainless TRIP‐steel as matrix with reinforcements of Mg‐PSZ are presented. Compact rods were produced by cold isostatic pressing and sintering, square honeycomb samples by the ceramic extrusion technique. The samples are characterized by optical and scanning electron microscopy before and after deformation, showing the microstructure and the deformation‐ induced martensite formation. The mechanical properties of samples with 5 vol% zirconia are superior compared to zirconia‐free samples and composites with higher zirconia contents in terms of bending and compression tests. The honeycomb samples exhibit extraordinary high specific energy absorption in compression.     

Detection of polyunsaturated omega-6 fatty acid in human malignant prostate tissue by 1D and 2D high-resolution magic angle spinning NMR spectroscopy

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Polyunsaturated omega-6 fatty acids (PUFAs) have been shown to promote prostate cancer. Here, we describe the use of HRMAS NMR spectroscopy to detect omega-6 PUFA species in prostate tissues.     

2-Amino-3-substituted-6-[(E)-1-phenyl-2-(N-methylcarbamoyl)vinyl]imid azo[1,2-a]pyridines as a novel class of inhibitors of human rhinovirus: stereospecific synthesis and antiviral activity

A series of 2-amino-3-substituted-6-[(E)-1-phenyl-2-(N-methylcarbamoyl)vinyl]+ ++imid azo[1,2-a]pyridines 1a-i, structurally related to Enviroxime and its analogous benzimidazoles, was designed and prepared for testing as antirhinovirus agents. The imidazo ring in this class of compounds was constructed starting from the aminopyridine after tosylation and subsequent treatment with the appropriate acetamides. The key steps in the synthesis include the development and use of a new Horner-Emmons reagent for the direct incorporation of methyl vinylcarboxamide. The reaction was stereospecific in the substrates 5a-f leading exclusively to the desired E-isomer and avoiding the use of reverse-phase preparative HPLC for the separation of both possible isomers before antiviral activity evaluation. The isopropylsulfonyl group, known as the best substituent at the 1-position in the benzimidazole SAR in terms of activity, was introduced in this new series of imidazo[1,2-a]pyridines via halogen-metal exchange and subsequent treatment with isopropyl isopropanethiolsulfonate. Compounds 1a-i were evaluated in plaque reduction assay and in a cytopathic effect assay. Compounds 1b-d,h exhibited a strong antirhinovirus activity, and no apparent cellular toxicity was visible. The substitution at the 3-position was required for activity. Surprisingly the isopropylsulfonyl in this family of compounds did not enhance the activity as in the case of benzimidazoles. Instead, compound 1i was 4 times less active than its phenyl and sulfide partners. The chemistry as well as the biological evaluation are discussed.     

Effect of specimen thickness on the growth rate of chromia scales on Ni-base alloys in high- and low-pO2 gases

Two types of experiments were carried out to study the oxidation behaviour of NiCr-base model alloys; thermogravimetric measurements for up to 72 h exposure at 1000 °C in synthetic air and isothermal exposures for up to 100 h at 1000 °C in laboratory air and in Ar–4%H₂–2%H₂O. It was found that there is a significant effect of specimen thickness on the oxidation rate of all studied alloys. The growth rates of the chromia scales decrease with increasing specimen thickness in both air and the Ar–H₂–H₂O mixture. Based on the present results in combination with recent literature data for ferritic steels, it is postulated that the decrease in rate is the result of compressive growth stresses in the scales which can relax by plastic deformation of the substrate for thin specimens but are maintained at significant levels for thick specimens.     

Pore bifurcation, growth and pore termination in nanoporous alumina with concave and convex surfaces

The growth of nanoporous alumina on concave or convex aluminium surfaces has been investigated. The number of pores during anodic oxidation increases or decreases almost linearly with the thickness of the oxide which is due to bifurcation or termination of single pores during alumina growth. The anodic oxidation has been constantly conducted in oxalic acid at 40 V. Therefore the average interpore distance has not changed during alumina growth. In earlier papers it has been shown that a bifurcation of pores is the result of the change of voltage and the electrolyte. In this work we have demonstrated that a termination or a bifurcation of pores is also possible by structuring the aluminium to a curved surface with concave or convex properties before oxidation. Those results do not depend on the substrate characteristics or on the alumina preparation techniques.     

Inclusions in commercial low and medium carbon ferromanganese

The microstructures of commercial low and medium carbon ferromanganese have been studied by optical microscopy and electron microprobe techniques. Element analysis and mapping have been performed on impurities in the matrix and nonmetallic inclusions present. The results show that the most common nonmetallic inclusion is managanese oxide, followed by complex compounds of managanese oxide, silicon oxide, and manganese sulfide. The different inclusions have been assessed according to the SS 111116 method. It follows that over 85 pct of the present nonmetallic inclusions are manganese oxides and that the amount of manganese oxide inclusions is inversely proportional to the carbon content in standard refined ferromanganese.