Electrooxidation of alcohols at a nickel oxide/multi-walled carbon nanotube-modified glassy carbon electrode

Electrocatalytic oxidation of methanol and some other primary alcohols on a glassy carbon electrode modified with multi-walled carbon nanotubes and nano-sized nickel oxide (GCE/MWNT/NiO) was investigated by cyclic voltammetry and chronoamperometry in alkaline medium. The results were compared with those obtained on a nickel oxide-modified glassy carbon electrode (GCE/NiO). Both the electrodes were conditioned by potential cycling in the range of 0.1–0.6 V versus Ag/AgCl in a 0.10 M NaOH solution. The effects of various parameters such as scan rate, alcohol concentration, thickness of NiO film, and real surface area of the modified electrodes were also investigated and compared. It was found that the GCE/MWNT/NiO-modified electrode possesses an improved electrochemical behavior over the GC/NiO-modified electrode for methanol oxidation.     

Surface modification of ultra‐high‐molecular‐weight polyethylene. II. Effect on the physicomechanical and tribological properties of ultra‐high‐molecular‐weight polyethylene/poly(ethylene terephthalate) composites

We performed surface modification of ultra‐high‐molecular‐weight polyethylene (UHMWPE) through chromic acid etching, with the aim of improving the performance of its composites with poly(ethylene terephthalate) (PET) fibers. In this article, we report on the morphology and physicomechanical and tribological properties of modified UHMWPE/PET composites. Composites containing chemically modified UHMWPE had higher impact properties than those based on unmodified UHMWPE because of improved interfacial bonding between the polymer matrix and the fibers and better dispersion of the fibers within the modified UHMWPE matrix. Chemical modification of UHMWPE before the introduction of PET fibers resulted in composites exhibiting improved wear resistance compared to the base material and compared to unmodified UHMWPE/PET composites. On the basis of the morphological studies of worn samples, microploughing and fatigue failure associated with microcracking were identified as the principle wear mechanisms. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006     

Mechanically Fastened FRP-Strengthened Two-Way Concrete Slabs with and without Cutouts

The feasibility of strengthening concrete slabs in flexure, with and without cutouts, using the mechanically fastened (MF) FRP technique is investigated. Two series of large-scale reinforced concrete slabs are tested. The first series is comprised of five slabs without a cutout, and measuring 2,600×2,600×120?mm; the second series consists of four slabs of the same dimensions with a central cutout measuring 800×800?mm. The mechanically fastened system is found to be a valid alternative to the externally bonded system resulting in a rapid, economic, and effective strengthening technique for two-way concrete slabs. The increases in ultimate capacities of the MF FRP-strengthened slabs range between 30 and 70% over those of the unstrengthened specimens. In addition, finite-element modeling of MF FRP-strengthened slabs is introduced in this study. The interfacial behavior between the MF FRPs and the concrete substrate is accounted for by using appropriate interfacial models. Very good agreement is obtained between the test results and the numerical predictions.     

Shades of green: A psychographic segmentation of the green consumer in Kuwait using self-organizing maps

This study uses self-organizing maps (SOM) to examine the effect of various psychographic and cognitive factors on green consumption in Kuwait. SOM is a machine learning method that can be used to explore patterns in large and complex datasets for linear and non-linear patterns. The results show that major variables affecting green consumption are related to altruistic values, environmental concern, environmental knowledge, skepticism towards environmental claims, attitudes toward green consumption, and intention to buy green products. The study also shows that SOM models are capable of improving clustering quality while extracting valuable information from multidimensional data.     

Effect of curing under pressure on compressive strength development of cemented paste backfill

The mechanical performance of cemented paste backfill (CPB) placed in underground openings (e.g., mine stopes) often differs from laboratory-predicted performance, even under the same atmospheric curing conditions (ambient temperature and relative humidity). This is probably due to the specific self-weight consolidation, different drainage conditions and confinement pressures encountered in the paste backfilled stopes. A new test system named CUAPS (Curing Under Applied Pressure System) was designed at the Université du Québec en Abitibi-Témiscamingue (UQAT) to assess the hydro-mechanical performance of in situ CPB samples at laboratory scale. The CUAPS apparatus allows the effective curing of CPB samples subjected to an assortment of vertical pressure applications (curing under stresses) that can mimic in situ placement and consolidation conditions. The compressive strength development of CPB samples prepared from sulphide-rich mine tailings from Garpenberg polymetallic mine (Sweden) was investigated using CUAPS apparatus and conventional plastic moulds (unconsolidated undrained samples) in parallel. The effect of curing stress (i.e. simulating different consolidation conditions) on resultant geotechnical index parameters and hydromechanical properties of CPB samples was analyzed. The primary observation is the confirmation that the compressive strength development of the consolidated CPB samples is higher than that of unconsolidated undrained ones. It could be attributed to the removal of excess pore water mainly due to the applied pressure during the effective curing process, which seems to improve consolidation process of the CPB material. The results also account for the differences in the CPB strength observed between laboratory samples and in situ samples. Thus, CUAPS would be more suitable than conventional plastic moulds to collect data for preliminary and final design of CPB systems.     

Modeling the efficiency of top Arab banks: A DEA–neural network approach

This study investigates the efficiency of top Arab banks using two quantitative methodologies: data envelopment analysis and neural networks. The study uses a probabilistic neural network (PNN) and a traditional statistical classification method to model and classify the relative efficiency of top Arab banks. Accuracy indices are used to assess the classification accuracy of the models. Results indicate that the predictive accuracy of NN models is quite similar to that of traditional statistical methods. The study shows that the NN models have a great potential for the classification of banks’ relative efficiency due to their robustness and flexibility of modeling algorithms. From a policy perspective, this study highlights the economic importance of encouraging increased efficiency throughout the banking industry in the Arab world.     

In vivo lipolysis induced by heparin injection or fasting: a proton MR spectroscopy analysis of human plasma

The impact of induced lipolysis on the composition of plasma lipids is analyzed by proton magnetic resonance spectroscopy (MRS) in humans. The variations of the methylene and methyl resonances from lipids in lipoproteins are studied under two sets of lipolytic conditions: acute endovascular lipolysis induced by an intravenous injection of heparin and subacute lipolysis induced by short fasting. During acute lipolysis, the degradation of the very low density lipoproteins structures is well correlated to the modifications observed in the areas of CH₂ and CH₃ MRS signals. The comparison of regular spectra, spectra with water signal suppression, and spectra recorded with a spin-echo sequence provides information on the behavior of the different parts of the lipoproteins, that is, the neutral core, little affected by heparine-induced lipoprotein lipase (LPL) activation, and the surface layer supplying substrates to LPL. During 48 h of fasting, only limited modifications occur on the MR spectra, and lipolysis cannot be documented in details.Address for correspondence: CRMBM-CNRS, Faculté de Médecine, 27, bd Jean Moulin, 13005 Marseille, France.