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41.
High thermal conductivity of spark plasma sintered silicon carbide ceramics with yttria and scandia 下载免费PDF全文
Yu‐Kwang Seo Young‐Wook Kim Toshiyuki Nishimura Won‐Seon Seo 《Journal of the American Ceramic Society》2017,100(4):1290-1294
A fully dense SiC ceramic with a room‐temperature thermal conductivity of 262 W·(m·K)?1 was obtained via spark plasma sintering β‐SiC powder containing 0.79 vol% Y2O3‐Sc2O3. High‐resolution transmission electron microscopy revealed two different SiC‐SiC boundaries, that is, amorphous and clean boundaries, in addition to a fully crystallized junction phase. A high thermal conductivity was attributed to a low lattice oxygen content and the presence of clean SiC‐SiC boundaries. 相似文献
42.
Wan-Ho?JeonEmail author Ho?Seon?Rew Chang-Joon?Kim 《Journal of Mechanical Science and Technology》2004,18(2):185-192
The aeroacoustic characteristics of a centrifugal fan for a vacuum cleaner and its noise reduction method are studied in this
paper. The major noise source of a vacuum cleaner is the centrifugal fan. The impeller of the fan rotates at over 3000 rpm,
and generates very high-level noise. It was revealed that the dominant noise source is the aerodynamic interaction between
the rotating impeller and stationary diffuser. The directivity of acoustic pressure showed that most of the noise propagates
backward direction of the fan-motor assembly. In order to reduce the high tonal sound generated from the aerodynamic interaction,
unevenly pitched impeller and diffuser, and tapered impeller designs were proposed and experiments were performed. Uneven
pitch design of the impeller changes the sound quality while the overall sound power level (SPL) and the performance remains
similar. The effect of the tapered design of impeller was evaluated. The trailing edge of the tapered fan is inclined. This
reduces the flow interaction between the rotating impeller and the stationary diffuser because of some phase shifts. The static
efficiency of the new impeller design is slightly lower than the previous design. However, the overall SPL is reduced by about
4 dB(A). The SPL of the fundamental blade passing frequency (BPF) is reduced by about 6 dB(A) and the 2nd BPF is reduced about 20 dB(A). The vacuum cleaner with the tapered impeller design produces lower noise level than the previous
one, and the strong tonal sound was dramatically reduced. 相似文献
43.
Layered Orthorhombic Nb2O5@Nb4C3Tx and TiO2@Ti3C2Tx Hierarchical Composites for High Performance Li‐ion Batteries 下载免费PDF全文
Chuanfang Zhang Seon Joon Kim Michael Ghidiu Meng‐Qiang Zhao Michel W. Barsoum Valeria Nicolosi Yury Gogotsi 《Advanced functional materials》2016,26(23):4143-4151
Engineering electrode nanostructures is critical in developing high‐capacity, fast rate‐response, and safe Li‐ion batteries. This study demonstrates the synthesis of orthorhombic Nb2O5@Nb4C3Tx (or @Nb2CTx) hierarchical composites via a one‐step oxidation —in flowing CO2 at 850 °C —of 2D Nb4C3Tx (or Nb2CTx) MXene. The composites possess a layered architecture with orthorhombic Nb2O5 nanoparticles decorated uniformly on the surface of the MXene flakes and interconnected by disordered carbon. The composites have a capacity of 208 mAh g?1 at a rate of 50 mA g?1 (0.25 C) in 1–3 V versus Li+/Li, and retain 94% of the specific capacity with 100% Coulombic efficiency after 400 cycles. The good electrochemical performances could be attributed to three synergistic effects: (1) the high conductivity of the interior, unoxidized Nb4C3Tx layers, (2) the fast rate response and high capacity of the external Nb2O5 nanoparticles, and (3) the electron “bridge” effects of the disordered carbon. This oxidation method was successfully extended to Ti3C2Tx and Nb2CTx MXenes to prepare corresponding composites with similar hierarchical structures. Since this is an early report on producing this structure, there is much room to push the boundaries further and achieve better electrochemical performance. 相似文献
44.
Rising energy costs and growing environmental awareness motivate a critical revision of the design of distillation units. Systematic design techniques, such as the rectification body, column profile map, and temperature collocation methods, require exact knowledge of all pinch points in a particular system, because these stationary points delineate the possible composition trajectories realizable in separation columns. This paper demonstrates novel methods for rigorously determining all pinch points for the... 相似文献
45.
Neung‐Ju Lee Nam‐In Kang Won‐Jei Cho Seon‐Hee Kim Kyung‐Tae Kang Emmanuel A Theodorakis 《Polymer International》2001,50(9):1010-1015
A new monomer, exo‐3,6‐epoxy‐1,2,3,6‐tetrahydrophthalimidocaproic acid (ETCA), was prepared by reaction of maleimidocaproic acid and furan. The homopolymer of ETCA and its copolymers with acrylic acid (AA) or with vinyl acetate (VAc) were obtained by photopolymerizations using 2,2‐dimethoxy‐2‐phenylacetophenone as an initiator at 25 °C. The synthesized ETCA and its polymers were identified by FTIR, 1H NMR and 13C NMR spectroscopies. The apparent average molecular weights and polydispersity indices determined by gel permeation chromatography (GPC) were as follows: Mn = 9600 g mol?1, Mw = 9800 g mol?1, Mw/Mn = 1.1 for poly(ETCA); Mn = 14 300 g mol?1, Mw = 16 200 g mol?1, Mw/Mn = 1.2 for poly(ETCA‐co‐AA); Mn = 17 900 g mol?1, Mw = 18 300 g mol?1, Mw/Mn = 1.1 for poly(ETCA‐co‐VAc). The in vitro cytotoxicity of the synthesized compounds against mouse mammary carcinoma and human histiocytic lymphoma cancer cell lines decreased in the following order: 5‐fluorouracil (5‐FU) ≥ ETCA > polymers. The in vivo antitumour activity of the polymers against Balb/C mice bearing sarcoma 180 tumour cells was greater than that of 5‐FU at all doses tested. © 2001 Society of Chemical Industry 相似文献
46.
47.
A composite chemical heat storage material (EMC) comprising a mixture of expanded graphite (EG), magnesium hydroxide (Mg(OH)2), and calcium chloride (CaCl2) was developed as a magnesium oxide/water chemical heat pump reactant. The optimization of a mixing weight ratio between the Mg(OH)2 content of EMC and EMC itself was discussed from the viewpoints of both heat storage capacity and reactivity by considering the reaction rate constants from a kinetic analysis. It was confirmed that the dehydration reactivity of EMC increased as the mixing weight ratio decreased; however, the heat capacity of the EMC unit mass decreased. A multiplied factor consisting of the multiplied value dehydration rate constant and mixing weight ratio was introduced. It was suggested that a weight ratio of approximately 0.80 was the optimized value when the mixing molar ratio between CaCl2 and Mg(OH)2 was 0.10. Dehydration of EMC with an optimized mixing weight ratio and dehydration of pure Mg(OH)2 were conducted under various temperatures to compare the reaction rate constants of each material. From this study, it was demonstrated that EMC performed better on dehydration than pure Mg(OH)2. 相似文献
48.
Ui-Su Im Jiyoung Kim Seon Ho Lee Byung-Rok Lee Dong-Hyun Peck Doo-Hwan Jung 《JOM Journal of the Minerals, Metals and Materials Society》2017,69(12):2460-2466
In the present study, surface texture features and chemical properties of two types of cokes, made from coal tar by either 1-stage heat treatment or 2-stage heat treatment, were researched. The relationship between surface texture characteristics and the chemical properties was identified through molecular weight distribution, insolubility of coal tar, weight loss with temperature increase, coking yield, and polarized light microscope analysis. Rapidly cleared anisotropy texture in cokes was observed in accordance with the coking temperature rise. Quinoline insolubility and toluene insolubility of coal tar increased with a corresponding increases in coking temperature. In particular, the cokes produced by the 2-stage heat treatment (2S-C) showed surface structure of needle cokes at a temperature approximately 50°C lower than the 1-stage heat treatment (1S-C). Additionally, the coking yield of 2S-C increased by approximately 14% in comparison with 1S-C. 相似文献
49.
Ki Nam Kim Byung Sik Kim Gyeong Su Shin Myung Chul Park Deok Hyun Lee Seon Jin Kim 《Metals and Materials International》2011,17(4):587-592
Newly developed self-lubricating Fe-Cr-C-Mn-Cu cast composite alloys were investigated to study the role of Cu-rich second
phase particles which smear on the wear surface during sliding. The wear resistance of the material was improved with an increasing
copper concentration. The improved wear resistance was probably obtained by forming a protective tribofilm, which prevented
metal-to-metal contact through smearing of the embedded Cu-rich second phase particles. This formation of protective oxide
films during sliding is likely to improve the wear resistance of austenitic Fe-Cr-C-Mn-Cu cast composite alloys. 相似文献
50.
Inherent and apparent scattering properties of coated or uncoated spheres embedded in an absorbing host medium 总被引:1,自引:0,他引:1
Yang P Gao BC Wiscombe WJ Mishchenko MI Platnick SE Huang HL Baum BA Hu YX Winker DM Tsay SC Park SK 《Applied optics》2002,41(15):2740-2759
The conventional Lorenz-Mie formalism is extended to the case for a coated sphere embedded in an absorbing medium. The apparent and inherent scattering cross sections of a particle, derived from the far field and near field, respectively, are different if the host medium is absorptive. The effect of absorption within the host medium on the phase-matrix elements associated with polarization depends on the dielectric properties of the scattering particle. For the specific cases of a soot particle coated with a water layer and an ice sphere containing an air bubble, the phase-matrix elements -P12/P11 and P33/P11 are unique if the shell is thin. The radiative transfer equation for a multidisperse particle system embedded within an absorbing medium is discussed. Conventional multiple-scattering computational algorithms can be applied if scaled apparent single-scattering properties are applied. 相似文献