Characterization of boride coatings on a ductile cast iron

In this work, the EN-GJS-400-15 cast iron was pack-borided in a powder mixture composed of 5% B₄C, 5% NaBF₄ and 90% SiC at the three temperatures: 900, 950 and 1000°C for 2, 4 and 6 h, respectively. The pack-borided EN-GJS-400-15 cast iron was characterized by the following experimental techniques: optical microscopy, XRD analysis and Microhardness Vickers tester. The growth kinetics of boride layers was also investigated. As a consequence, the boron activation energy was found to be 212.28 kJ mol^–1 for the EN-GJS-400-15 cast iron. Based on a regression model, a useful equation was derived to estimate the boride layer thickness as a function of the boriding parameters (time and temperature). A good agreement was then obtained between the predicted values of boride layers thicknesses and those measured experimentally. In addition, an iso-thickness diagram was proposed to be used as a simple tool to select the boride layers thicknesses according to the potential applications of EN-GJS-400-15 cast iron in industry.     

Synthesis,characterization, and drug‐release behavior of amphiphilic quaternary ammonium chitosan derivatives

A new type of amphiphilic quaternary ammonium chitosan derivative, 2‐N‐carboxymethyl‐6‐O‐diethylaminoethyl chitosan (DEAE–CMC), was synthesized through a two‐step Schiff base reaction process and applied to drug delivery. In the first step, benzaldehyde was used as a protective agent for the incorporation of diethylaminoethyl groups to form the intermediate (6‐O‐diethylaminoethyl chitosan). On the other hand, NaBH₄ was used as a reducing agent to reduce the Schiff base, which was generated by glyoxylic acid, for the further incorporation of carboxymethyl groups to produce DEAE–CMC. The structure, thermal properties, surface morphology, and diameter distribution of the resulting chitosan graft copolymers were characterized by Fourier transform infrared spectroscopy, ¹H‐NMR, thermogravimetric analysis, differential scanning calorimetry, X‐ray powder diffraction, scanning electron microscopy, and laser particle size analysis. Benefiting from the amphiphilic structure, DEAE–CMC was able to be formed into microspheres in aqueous solution with an average diameter of 4.52 ± 1.21 μm. An in vitro evaluation of these microspheres demonstrated their efficient controlled release behavior of a drug. The accumulated release ratio of vitamin B₁₂ loaded DEAE–CMC microspheres were up to 93%, and the duration was up to 15 h. The grafted polymers of DEAE–CMC were found to be blood‐compatible, and no cytotoxic effect was shown in human SiHa cells in an MTT [3‐(4, 5‐dimethyl‐thiazol‐2‐yl)‐2, 5‐diphenyltetrazolium bromide] cytotoxicity assay. These results indicate that the DEAE–CMC microspheres could be used as safe, promising drug‐delivery systems. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39890.     

Thermo-mechanical characteristics of thermally aged polyethylene/polypropylene blends

Polyethylene (PE), polypropylene (PP) and their blends have attracted a lot of attention due to their potential industrial applications. Therefore, the current work has been carried out with the main objective of investigating the impact of the thermal aging/treatment and blend ratio (composition range) on the mechanical (tensile and hardness) and thermal characteristics (using thermogravimetric analysis in a dynamic air atmosphere) of PE, PP and PE/PP binary blends. Samples of PE/PP blends containing 100/00, 75/25, 50/50, 25/75 and 0/100 wt.% were prepared via injection moulding technique and thermally treated/aged at 100 °C for 0, 2, 4, 7, 14 days. The tensile measurements indicated that the yield strength and the modulus decrease with increasing PE content. It was also observed that PE, PP and their blends deform in ductile modes. They undergo a uniform yielding over a wide range of deformation, which is followed by strain hardening and then failure. The strain to break for pure PE is found to be much higher than that for pure PP and for their blends, intermediate values have been observed. The hardness measurements have also revealed that increasing PE content in PE/PP blends reduced the hardness value of PP, however, thermal aging at 100 °C has not affected the polymers hardness which holds also true for the tensile properties, showing a good correlation between tested mechanical properties. The thermogravimetric analysis (TGA) in a dynamic air atmosphere and derivative thermogravimetric analysis (DTA) were conducted to study the thermal degradation and stability of thermally unaged and aged PE, PP and PE/PP blends in terms of the initial (T_d and T_d(1%)) and final (T_d(99%)) decomposition temperatures and maximum decomposition rate temperature (T_max). All polymers start to decompose at no less than 365 °C. As for mechanical properties, the blend ratio has affected the thermal properties however, aging time has not.     

Can distributed generation offer substantial benefits in a Northeastern American context? A case study of small-scale renewable technologies using a life cycle methodology

Renewable distributed electricity generation can play a significant role in meeting today's energy policy goals, such as reducing greenhouse gas emissions, improving energy security, while adding supply to meet increasing energy demand. However, the exact potential benefits are still a matter of debate. The objective of this study is to evaluate the life cycle implications (environmental, economic and energy) of distributed generation (DG) technologies. A complementary objective is to compare the life cycle implications of DG technologies with the centralized electricity production representing the Northeastern American context. Environmental and energy implications are modeled according to the recommendations in the ISO 14040 standard and this, using different indicators: Human Health; Ecosystem Quality; Climate Change; Resources and Non-Renewable Energy Payback Ratio. Distinctly, economic implications are modeled using conventional life cycle costing. DG technologies include two types of grid-connected photovoltaic panels (3 kWp mono-crystalline and poly-crystalline) and three types of micro-wind turbines (1, 10 and 30 kW) modeled for average, below average and above average climatic conditions in the province of Quebec (Canada). A sensitivity analysis was also performed using different scenarios of centralized energy systems based on average and marginal (short- and long-term) technology approaches. Results show the following. First, climatic conditions (i.e., geographic location) have a significant effect on the results for the environmental, economic and energy indicators. More specifically, it was shown that the 30 kW micro-wind turbine is the best technology for above average conditions, while 3 kWp poly-crystalline photovoltaic panels are preferable for below average conditions. Second, the assessed DG technologies do not show benefits in comparison to the centralized Quebec grid mix (average technology approach). On the other hand, the 30 kW micro-wind turbine shows a potential benefit as long as the Northeastern American electricity market is considered (i.e., oil and coal centralized technologies are affected for the short- and long-term marginal scenarios, respectively). Photovoltaic panels could also become more competitive if the acquisition cost decreased. In conclusion, DG utilization will represent an improvement over centralized electricity production in a Northeastern American context, with respect to the environmental, energy and economic indicators assessed, and under the appropriate conditions discussed (i.e., geographical locations and affected centralized electricity production scenarios).     

Electric load forecasting by using dynamic neural network

Electrical energy is fundamental for the wellbeing and for the economic development of any country. However, all countries must ensure access to essential resources and ensure the continuity of its supply. Due to the non-storable nature of electrical energy, the amount of consumed active power should always be equal the produced active power just to avoid power system frequency deviation problem. In order to keep the relationship production–consumption relation in compliance with different standards and to secure profitable operations of power system, electric load consumption must be predicted and controlled instantaneously. Several statistical and classical techniques are proposed in the literature but unfortunately all these methods are not accurate in a satisfactory manner. In this paper, a dynamic neural network is used for the prediction of daily power consumption. The suitability and the performance of the proposed approach is illustrated and verified with simulations on load data collected from French Transmission System Operator (RTE) website. The obtained results show that the accuracy and the efficiency are improved comparatively to conventional methods widely used in this field of research.     

Wavelet network for recognition system of Arabic word

Focusing on the development of new technologies of information, research in the speech communication field is an activity in full expansion. Several disciplines and skills interact in order to improve performance of Human Machine Communication Systems (HMC). In order to increase the performance of these systems, various techniques, including Hidden Markov Models (HMM) and Neural Network (NN), are implemented.     

Effect of seed coat fragments on cotton yarn structure: impact of fragment size,attached fibres and position within yarn core

Seed coat fragments are a major source of cotton yarn imperfections. This article discusses the factors influencing the disruption caused by seed coat fragments in ring-spun yarn structure with a focus on three characteristics: the fragment's size, the amount of fibres attached to it and its position relative to the yarn core. The three characteristics were investigated through two experiments involving various types of yarn defects and a range of ring-spun yarn counts. Results presented in this article indicate that the three factors considered have a significant influence on the intensity of the disruption the seed coat fragment causes in the yarn structure, and are determinant of the type of defect that this disruption engenders (short/long defect).     

Iron oxide (n-Fe2O3) nanowire films and carbon modified (CM)-n-Fe2O3 thin films for hydrogen production by photosplitting of water

Iron oxide n-Fe₂O₃ nanowire photoelectrodes were synthesized by thermal oxidation of Fe metal sheet (Alfa Co. 0.25 mm thick) in an electric oven then tested for their photoactivity. The photoresponse of the n-Fe₂O₃ nanowires was evaluated by measuring the rate of water splitting reaction to hydrogen and oxygen, which is proportional to photocurrent density, J_p. The optimized electric oven-made n-Fe₂O₃ nanowire photoelectrodes showed photocurrent densities of 1.46 mA cm⁻² at measured potential of 0.1 V/SCE at illumination intensity of 100 mW cm⁻² from a Solar simulator with a global AM 1.5 filter. For the optimized carbon modified (CM)-n-TiO₂ synthesized by thermal flame oxidation the photocurrent density for water splitting was found to increase by two fold to 3.0 mA cm⁻² measured at the same measured potential and the illumination intensity. The carbon modified (CM)-n-Fe₂O₃ electrode showed a shift of the open circuit potential by −100 mV/SCE compared to undoped n-Fe₂O₃ nanowires. A maximum photoconversion efficiency of 2.3% at applied potential of 0.5 V/E_aoc was found for CM-n-Fe₂O₃ compared to 1.69% for n-Fe₂O₃ nanowires at higher applied potential of 0.7 V/E_aoc. These CM-n- Fe₂O₃ and n- Fe₂O₃ nanowires thin films were characterized using photocurrent density measurements under monochromatic light illumination, UV-Vis spectra, X-ray diffraction (XRD) and scanning electron microscopy (SEM).     

Doubly-striped disk mirroring: Reliable storage for video servers

Disk striping is essential in Video-On-Demand servers to allow concurrent access for a large number of users to the same copy of a video object. On the other hand, disk striping makes the system more vulnerable to component failures. We propose a replication scheme for video content and an associated I/O scheduling algorithm that enables the system to tolerate a component failure. The scheme, called doubly-striped mirrors, compares favorably to other approaches for implementing redundancy such as RAID in terms of cost, bandwidth efficiency, buffer usage and system availability.     

A MC-CDMA Mobile Communication System Employing Pre-Rake and Transmit Diversity

In this paper, a multi-carrier code division multiple access (MC-CDMA) downlink mobile communication system employing pre-rake and dual transmit diversity is proposed. It combines high spectral efficiency with an immunity to channel dispersion and fading. It also ensures small size, cost and power consumption of the terminal. Theoretical and simulation results for the system under consideration are obtained. Depicted results show appreciable improvements of the proposed system over those previously known.Emad K. Al-Hussaini received his B.Sc degree in Electrical Communication Engineering from Ain-Shams University, Cairo, Egypt, in 1964 and his M.Sc and Ph.D. degrees from Cairo University, Giza, Egypt, in 1974 and 1977, respectively. From 1964 to 1970, he was with the General Egyptian Aeroorganization. Since 1970, he has been with the Department of Electronics and Communications, Faculty of Engineering, Cairo University, and is currently professor there. He was a research fellow at Imperial College, London, UK, and at the Moore School of Electrical Engineering, University of Pennsylvania, Philadelphia, PA, USA, in the academic years 1976/1977 and 1981/1982, respectively. In 1990, he received the Egyptian national encouragement award for outstanding engineering research. He has written several papers for technical international journals and conferences. His research interests include signal processing, fading channel communication, modulation, and cellular mobile radio systems. Dr Al-Hussaini is a senior member of IEEE. He is listed in Marquis Whos Who in the World and in the IBC (International Biographical Center, Cambridge) for outstanding people of the 20th century.Hebat-Allah M.Mourad received her B.Sc, M.Sc and Ph.D degrees in Electrical Communication Engineering from Cairo University, Egypt, in 1983, 1987 and 1994 respectively. Since 1983 she has been with the Electronics and Communications Department, Faculty of Engineering Cairo University and is currently associate professor there. Her research interests include mobile communications, satellite communications and optical fiber communications.Fatma A. Newagy received her B.Sc and M.Sc degrees in electrical communication engineering from Cairo University, Egypt in 1998 and 2002 respectively. Since 1999, she has been a research assistant with the Department of Electronics and Communications, Faculty of Engineering, Cairo University. She is pursuing her Ph.D. there. Her research interests include mobile communications and modulation techniques for spread spectrum and wireless communications.