Stability limits and NO emissions of premixed swirl ammonia-air flames enriched with hydrogen or methane at elevated pressures

This study reports measurements of stability limits and exhaust NO mole fractions of technically-premixed swirl ammonia-air flames enriched with either methane or hydrogen. Experiments were conducted at different pressures from atmospheric to 5 bar, representative of commercial micro gas turbines. The full range of ammonia fractions in the fuel blend, x_NH3, was considered, from 0 (pure methane or hydrogen) to 1 (pure ammonia), covering very lean (φ = 0.25) to rich (φ = 1.60) equivalence ratios. Results show that increasing pressure widens the range of stable equivalence ratios for pure ammonia-air flames. Regardless of pressure, there is a critical ammonia fraction above which the range of stable equivalence ratios suddenly widens. This is because flashback does not occur anymore when the equivalence ratio is progressively increased towards stoichiometric and rich blowout occurs instead. This critical ammonia fraction increases with pressure and is larger for ammonia-hydrogen than for ammonia-methane. Provided that enough hydrogen is blended with ammonia (x_NH3 < 0.9), flames with very lean equivalence ratios (φ < 0.7) can be stabilized and these yield competitively low NO emissions (<200 ppm), regardless of pressure. For this reason, very lean swirl ammonia-hydrogen-air flames are promising candidates for micro gas turbines. However, N₂O emissions have the potential to be unacceptably large for these operating conditions if heat loss is too large or residence time is too short. As a consequence, the post flame region must be considered carefully. Due to the lower reactivity of methane compared to that of hydrogen, very lean swirl ammonia-methane-air flames could not be stabilized and good NO performance is limited to rich equivalence ratios for ammonia-methane fuel blends. The equivalence ratio above which good NO performance depends on pressure and bulk velocity.     

State estimation for nonlinear conformable fractional‐order systems: A healthy operating case and a faulty operating case

The issue of estimating states for classical integer‐order nonlinear systems has been widely addressed in the literature. Yet, generalization of existing results to the fractional‐order framework represents a fertile area of research. Note that, recently, a new and advantageous type of fractional derivative, the conformable derivative, was defined. So far, the general query of designing observers for conformable fractional‐order systems has not been investigated. In addition, it has been proved in the literature that some important tools for stability analysis of fractional‐order systems are valid using the conformable derivative concept, but invalid using other fractional derivative concepts. Motivated by the cited facts, this paper presents a first‐state estimation scheme for fractional‐order systems under the conformable derivative concept. A healthy operating case and a faulty operating case are treated. In this paper, a version of Barbalat's lemma, which is invalid using the well‐known Caputo derivative, is exploited to prove the convergence of the estimation errors. In order to validate the theoretical results, a numerical example is studied in the simulation section.     

A theoretical investigation on the properties of the new poly(N‐vinylcarbazole)‐3‐methylthiophene (PVK‐3MeT) synthesized graft copolymer

In this article, we present quantum chemical calculations, based on density functional theory (DFT), performed to investigate the geometries and the opto‐electronic properties of a new synthesized graft copolymer based on poly(N‐vinylcarbazole) (PVK) and poly(3‐methylthiophene) (PMeT) named PVK‐3MeT. First, we have theoretically computed and compared the structural, optical, and vibrational parameters of both neutral and doped states. In addition, the excited state was theoretically obtained by the ab initio RCIS/STO‐3G method. To assign the absorption and emission peaks observed experimentally, we computed the energies of the lowest singlet excited state with the time‐dependent density functional theory (TD‐DFT) method. Electronic parameters such as the HOMO‐LUMO band gap, the ionization potential (IP), and electron affinity (EA) are extracted. Calculations show that the PVK‐3MeT copolymer is nonplanar in its ground neutral state. Meanwhile, upon doping or photoexcitation, an enhancement of the planarity is observed, resulting on a decrease of the inter‐ring torsion angle between 3‐methylthiophene units. Such modifications in the geometric parameters induce a dramatic change on the HOMO and LUMO orbitals in the doped or excited states. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011.     

The effect of sand wind,temperature and exposure time on tri-layer polyethylene film used as greenhouse roof

This work aims at studying the degradable effect of artificial ageing on tri-layer stabilised low-density polyethylene (PE) films used as greenhouse cover in the North Africa environment. The film was supplied by Agrofilm company, Algeria. Colour additives and infra-red and ultraviolet stabilisers were used. Optical, thermal, surface and mechanical properties have been investigated for virgin sample and samples exposed to sand wind for different exposure periods (1, 2, 4 and 8?h) of artificial ageing at a temperature of 40°C simulating Saharan environment. The findings of this study show that the harsh environmental conditions of exposure to temperature and sand wind have significant degradable effects on the properties of the PE film. The transmission of the film and its mechanical properties have reduced significantly due to exposure to sand wind and temperature. The study revealed also that the degradation parameters measured are directly related to the criteria for evaluating the effectiveness of agricultural greenhouse.     

Kinetic Study and Modeling of the Degradation of the Maize Kernels Quality During Drying in Fluidized Bed

Only a few kinetic studies have been reported in the literature on the evolution of comercial quality of maize during drying and to the best of our knowledge no model allows to predict the dynamic coupling of drying and product quality evolution. The aim of this work is to present new information on the effects of the operating conditions (harvest year, weight of maize to be dried, initial moisture content of the grain and air temperature) on the evolution of maize saline-soluble protein denaturation and the wet-milling quality during drying of maize in a batch floatation fluidized bed dryer. Also, kinetic laws are proposed for the quality criteria that will be combined with drying model already derived [1, 2].

The experimental results show that the degradation of the main components of maize (starch and proteins) is considerably affected by the temperature level and to a lesser extent by the initial moisture content of grains. Beyond 70°C, the denaturation of saline-soluble proteins occurs rapidly in the heat-up period of the grains. As for the wet-milling quality degradation, it starts only above 90°C.

Kinetic laws derived from this study express the variation of the degradation rate of proteic and wet milling quality as functions of the solubility of saline-soluble proteins or the starch-gluten separation index, the grain moisture content and temperature.     

Controlled Picard Method for Solving Nonlinear Fractional Reaction–Diffusion Models in Porous Catalysts

This paper discusses the diffusion and reaction behaviors of catalyst pellets in the fractional-order domain as well as the case of nth-order reactions. Two generic models are studied to calculate the concentration of reactant in a porous catalyst in the case of a spherical geometric pellet and a flat-plate particle with different examples. A controlled Picard analytical method is introduced to obtain an approximated solution for these systems in both linear and nonlinear cases. This method can cover a wider range of problems due to the extra auxiliary parameter, which enhances the convergence and is suitable for higher-order differential equations. Moreover, the exact solution in the linear fractional-order system is obtained using the Mittag–Leffler function where the conventional solution is a special case. For nonlinear models, the proposed method gives matched responses with the homotopy analysis method (HAM) solutions for different fractional orders. The effect of fractional-order parameter on the dimensionless concentration of the reactant in a porous catalyst is analyzed graphically for different cases of order reactions and Thiele moduli. Moreover, the proposed method has been applied numerically for different cases to predict and calculate the dual solutions of a nonlinear fractional model when the reaction order n?=??1.     

Unsteady Natural Convective Boiling in a Narrow Vertical Channel

The purpose of this work is to describe the two-phase flow structure and heat transfer of unsteady natural convective boiling in a narrow vertical channel. The experiments are performed with saturated n-pentane at a pressure of 1 bar. An unheated plate is placed parallel to the heating surface and lateral sides are closed. The distance between the heated surface and the confinement plate is 800 μm. Void fraction measurements are performed using capacitive sensors. The void fraction increases with heat flux and reaches a maximum of 0.80 in the mid-height of the channel when the heat flux is equal to 90% of the critical heat flux. Flow observations using a high-speed video camera show an unsteady thermo-hydraulic behavior. The frequency of the cycles increases with the wall temperature during nucleate and transient boiling. Local velocities of the bubble meniscus developing within the confined space are determined during the boiling cycles. The time-averaged liquid flow rate increases significantly with heat flux and reaches a maximum for heat flux close to the critical heat flux.     

Entropy generation in Poiseuille–Benard channel flow

The issue of entropy generation in Poiseuille–Benard channel flow is analyzed by solving numerically the mass, momentum and energy equations with the use of the classic Boussinesq incompressible approximation. The numerical scheme is based on Control Volume Finite Element Method with the SIMPLER algorithm for pressure–velocity coupling. Results are obtained for Rayleigh numbers Ra and irreversibility φ ranging from 10³ to 5×10⁴ and from 10⁻⁴ to 10 respectively. Variations of entropy generation and the Bejan number as a function of Ra and φ are studied. The limit value φ_l for which entropy generation due to heat transfer is equal to entropy due to fluid friction is evaluated. It has been found that φ_l is a decreasing function of the Rayleigh number Ra. φ_l varies from 0.0015 to 0.096 when Ra decrease from 5×10⁴ to 10³. Stream lines and entropy generation maps are plotted at six times over one period at Ra =10⁴ and φ=10⁻³. It has been found that the maximum entropy generation is localized at areas where heat exchanged between the walls and the flow is maximum. No significant entropy production is seen in the main flow.     

Design-for-testability for embedded delay-locked loops

This paper introduces a new approach to testing a basic analog-only delay-locked loop (DLL) that is embedded in a field-programmable gate array, an application specific integrated circuit, or a system-on-chip (SoC). Part of the DLL circuitry is duplicated and then connected to the DLL in a way that produces a replica of the control voltage. This shadow of the control voltage is used to measure the loop's response to a step in phase. The concept of test construct (TC) gain is introduced as a means of improving detectability. The benefit of the testing approach is demonstrated by injecting defects into the DLL and detecting them through the TC at the observation point.