全文获取类型
收费全文 | 335篇 |
免费 | 19篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 5篇 |
综合类 | 1篇 |
化学工业 | 89篇 |
金属工艺 | 9篇 |
机械仪表 | 9篇 |
建筑科学 | 14篇 |
矿业工程 | 1篇 |
能源动力 | 21篇 |
轻工业 | 17篇 |
水利工程 | 8篇 |
石油天然气 | 2篇 |
无线电 | 34篇 |
一般工业技术 | 47篇 |
冶金工业 | 17篇 |
原子能技术 | 7篇 |
自动化技术 | 75篇 |
出版年
2024年 | 1篇 |
2023年 | 4篇 |
2022年 | 9篇 |
2021年 | 28篇 |
2020年 | 19篇 |
2019年 | 21篇 |
2018年 | 19篇 |
2017年 | 26篇 |
2016年 | 20篇 |
2015年 | 8篇 |
2014年 | 31篇 |
2013年 | 41篇 |
2012年 | 21篇 |
2011年 | 17篇 |
2010年 | 23篇 |
2009年 | 11篇 |
2008年 | 15篇 |
2007年 | 10篇 |
2006年 | 4篇 |
2005年 | 7篇 |
2004年 | 5篇 |
2003年 | 1篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1995年 | 1篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1989年 | 1篇 |
1986年 | 1篇 |
1982年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有356条查询结果,搜索用时 31 毫秒
41.
The spun tapes of synthesized PAN, its copolymer with 1 wt% itaconic acid, and doped version with 1 wt% sodium dodecyl sulfate (SDS) all showed stripy, even, and compact cross-sections as the hallmark of gel forming products. PAN doping with SDS and acrylonitrile copolymerization with itaconic acid reduced its dimethylformamide (DMF) solution structural viscosity index (Δη) by 50% and 30%, respectively, at 675 s??1. In addition, the modification of synthesized PAN through doping and acrylonitrile copolymerization with itaconic acid led to severe and mild gelation temperature decrease, respectively. The stabilization peak of the synthesized PAN tape was enhanced as much as 25 °C by 900% hot drawing, decreased by about 10 °C through copolymerization, while experienced small temperature changes through doping. The second derivative of Fourier transform infrared and Gaussian fitting was used to analyze the tapes cyclization due to stabilization treatment through introducing Isd index. 10 min Isd index was raised as much as 430% and 800% in comparison with the synthesized PAN through its doping or acrylonitrile copolymerization with itaconic acid, respectively. Further 180 min of Isd index, however, showed the same proportional increase as toughness of the drawn tapes versus their heat of stabilization through their physical and chemical modifications. 相似文献
42.
Polyacrylonitrile (PAN) in dimethylformamide solution containing 0.25 or 1 wt% graphene oxide (GO) was gel spun to tapes. Scanning electron microscopy of tapes showed compact staircase cross-sections hallmarking the gel spun products. Low shear rate rheometry of the tape precursors revealed a viscosity increase, while the structural viscosity indexes of dispersions dropped to 40 and 70% at high shear rates by 0.25 and 1 wt% GO inclusion, respectively. Furthermore, the sol–gel transition temperature of PAN solution was enhanced by about 2.5 and 10 °C with 0.25 and 1 wt% GO inclusion, respectively. Strain sweep test implied a gel-to-sol transition from 9 to 28% by 1 wt% GO inclusion. The experimental reinforcement coefficient corresponded the aligned Halpin–Tsai model confirming the suitable dispersion preparation route namely master batch dilution implementing strong interphase formation among the PAN chains and GO platelets. Molecular evolution analysis during air stabilization through a combined second derivative of FTIR spectra, Gaussian peak fitting represented by Isd index, indicated the initial cyclization at 290 °C followed by its enhanced rate. Final Isd was noticed to be 48% higher for the tapes containing GO nanosheets. GO inclusion not only enhanced the tape heat of stabilizations but also differentiated its proportional Isd and toughness dependency based on the heat of stabilization. 相似文献
43.
The safety of hydrogen generation process is a major concern. This paper discusses the quantitative analyzes of the risk imposed on neighborhood from the operation of a hydrogen generator using natural gas reforming process. For this purpose, after hazard identification, the frequency of scenarios was estimated using generic data. Quantitative risk assessment was applied for consequence modeling and risk estimation. The results revealed that, jet fire caused by a full bore rupture in Desulphurization reactor has the highest fatality (26person) and affects the largest area of 5102 m2. The lethality radius, maximum radiation and safe distance of this incident were 140 m, 370 kW/m2 and 225 m respectively. A full bore rupture in Reformer can lead to the most dangerous flash fire. In this incident the concentration of released material in LFL zone (area of 1483.17 m2) and ½ LEL zone (area of 1970.74 m2) were 61,125 ppm and 40,000 ppm respectively. QRA is a credible method to assess the risks of hydrogen generation process. 相似文献
44.
Effective delayed neutron fraction βeff and neutron generation time Λ are important factors in reactor physics calculation and transient analysis. In the first stage of this research, these kinetics parameters have been calculated for two states of Tehran Research Reactor (TRR), i.e. cold (fuel, clad and coolant temperature 20 °C) and hot (fuel, clad and coolant temperature 65, 49 and 44 °C, respectively) states using MTR_PC computer code. The ratio of (βeff)i/(βeff)core plays an important role in reactivity accident analysis codes. This parameter and its contribution to effective delayed neutron fraction from each nucleus have been calculated in cold and hot reactor states. Uncertainty of effective delayed neutron fraction is evaluated in terms of following four quantities; basic delayed neutron constants, delayed neutron spectra, energy dependence of delayed neutron yield (νd) and fission cross-section of 235U and 238U. In the second stage, these parameters have been measured with an experimental method based on Inhour equation. The calculated and measured values are in good agreement. Relative Percent Errors (RPEs) are 2.8% for βeff and 5.7% for Λ in the cold state. 相似文献
45.
In this paper, the development of a neutron noise simulator for hexagonal-structured reactor cores using both the forward and the adjoint methods is reported. The spatial discretisation of both 2-D 2-group static and dynamic equations is based on a developed box-scheme finite difference method for hexagonal mesh boxes. Using the power iteration method for the static calculations, the 2-group neutron flux and its adjoint with the corresponding eigenvalues are obtained by the developed static simulator. The results are then benchmarked against the well-known CITATION computer code. The dynamic calculations are performed in the frequency domain which leads to discarding of the time discretisation. Then, the developed 2-D 2-group neutron noise simulator calculates both the discretised forward and the adjoint reactor transfer function between a point source and its induced neutron noise, by assuming the neutron noise source as an “absorber of variable strength” type. The neutron noise induced by a “vibrating absorber” type of noise source may also be modeled using the calculated transfer function. The viability of the simulator is verified for different benchmark cases. 相似文献
46.
Mahmoud Moslehi-Fard Naser Alinejad Chapar Rasouli Asghar Sadigzadeh 《Journal of Fusion Energy》2012,31(4):346-351
Toroidal and Poloidal magnetic fields have an important effect on the tokomak topology. Damavand Tokomak is a small size tokomak characterized with k?=?1.2, B t?=?1T, R 0?=?36?cm, maximum plasma current is about 35?KA with a discharge time of 21?ms. In this experimental work, the variation of poloidal magnetic field on the torodial cross section is measured and analyzed. In order to measure the polodial magnetic field, 18 probes were installed on the edge of tokomak plasma with ?θ?=?18°, while a limiter was installed inside the torus. Plasma current, I p, induces a polodial magnetic field, B p, smaller than the torodial magnetic field B t. Magnetic lines B produced as a combination of B t and B p, are localized on the nested toroidal magnetic surfaces. The presence of polodial magnetic field is necessary for particles confinement. Mirnov oscillations are the fluctuations of polodial magnetic field, detected by magnetic probes. Disrupted instability in Tokomak typically starts with mirnov oscillations which appear as fluctuations of polodial magnetic field and is detected by magnetic probes. Minor disruptions inside the plasma can contain principal magnetic islands and their satellites can cause the annihilation of plasma confinement. Production of thin layer of turbulent magnetic field lines cause minor disruption. Magnetic limiter may cause the deformation of symmetric equilibrium configuration and chaotic magnetic islands reveal in plasma occurring in thin region of chaotic field lines close to their separatrix. The width of this chaotic layer in the right side of poloidal profile of Damavand Tokomak is smaller than the width in the left side profile because of Shafranov displacement. Ergodic region in the left side of profile develops a perturbation on the magnetic polodial field lines, B p, that are greater in magnitude than that in the right side, although the values of B p on the left side are smaller than that on the right side of the profile. The Left side of profile is close to the principal magnetic axis and the right side is away from Z axis of Tokamak. 相似文献
47.
Biomass should be considered as one of the promising sources of energy for mitigating greenhouse gas (GHG) emissions. Co-firing biomass with coal has become a solution for meeting the power crisis as well as to reduce the pollutant emissions. The biomass fuels typically found from woody to grassy and solid recovered fuels depending on its origin and properties. It is suggested that co-firing coal with biomass has a substantial effect on SOx and NOx emission level. The ashing process, fly ash quality depends on the conversion technology, capture technology and the properties of the biomass. In order to control the furnace efficiency and production, burnout, optimum injection of biomass sharing with specific information of particle ignition properties are also important. A number of small/laboratory scale and industrial scale experiments have been conducted by different researchers. Different experimental studies performed are reviewed, grouped and summarized based on the fuel processing technology, burnout performance, emission level, environmental aspect, ash information and deposit characteristics, effect of co-firing ratios and adoption of oxy-fuel co-firing. Overall, this paper will highlight existing technologies and emerging trends in co-firing of different types of biomass which will be helpful for future investigations. 相似文献
48.
Using the hyperbolic heat conduction model, thermal stresses generated within a rapidly heated thin metal plate are investigated numerically. The effects of different parameters such as the form, duration, amplitude, and penetration depth of the heating source on the temperature, thermal moment, deflection, and thermal stresses are studied. It is found that under ultra-fast heating of very thin plates, the hyperbolic heat conduction model must be adopted to model the thermal behavior. 相似文献
49.
There is considerable interest in the use of ruthenium as an ultrathin trench liner in damascene copper plating used to fabricate
on-chip interconnects. The problem is that when freshly deposited ruthenium films are exposed to air, their surfaces tend
to undergo spontaneous oxidation, and such deposits (as demonstrated here) are reluctant to undergo reduction. Copper deposition
in an acid plating bath occurs readily on the oxidized ruthenium, but the presence of oxide is known to have a detrimental
effect both on the copper superfilling process and copper adhesion at the Ru/Cu interface. 相似文献
50.
Virgin olive oil (VOO) based polyetheramide (PEtA) was developed from N-N′-bis(2-hydroxyl ethyl) olive fatty amide (HEOA) and orcinol through condensation polymerization. PEtA was further treated with toluylene 2,4-diisocynate (TDI) with different percentages (20–30 wt%) via addition polymerization to obtain poly(ether amide urethane) (PEtAU). The structural elucidation of HEOA, PEtA and PEtAU were carried out by FT-IR, 1H NMR and 13C NMR spectroscopic techniques. Physico-chemical and physico-mechanical properties of the material were investigated by standard methods. Thermal stability and curing behavior of virgin olive oil, HEOA, and PEtAU were assessed by thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The corrosion behavior was investigated by potentiodynamic polarization measurements in different corrosive environments (3.5 wt% HCl, 5 wt% NaCl, 3.5 wt% NaOH, tap water) at room temperature. The results showed that UPEtA coatings exhibit good physico-mechanical as well as corrosion resistance performance and can be safely used up to 200 °C. The work is an attempt for alternate utilization of olive oil. 相似文献