Activities of MFI-Supported Rhenium Catalysts for the Aromatization of Methane: Effect of Cationic Form of the Inorganic Carrier

MFI type inorganic carrier was used in two different cationic forms, hydrogen and calcium respectively. MFI-supported molybdenum and rhenium catalysts were prepared. The activities of the catalysts were compared for the aromatization reaction of methane. Higher activity values were attained with the catalysts supported on HZSM-5. Aromatics were also observed with the catalysts supported on CaZSM-5, despite their deficiency in acid sites. Highly dispersed rhenium is expected to be formed with the use of the inorganic carrier in calcium form. On the other hand, lower reaction rates were observed with rhenium supported on CaZSM-5, in spite of the improved dispersion of the active rhenium species on this catalyst. This was interpreted in terms of the critical role of the acid sites in the conversion of methane to aromatics, compared to the improved dispersion of the active metal.     

CFD SIMULATION OF THE GAS-SOLID FLOW IN THE RISER OF A CIRCULATING FLUIDIZED BED WITH SECONDARY AIR INJECTION

A comprehensive investigation was carried out to study hydrodynamics aspects of secondary air injection in circulating fluidized beds. This article presents modeling and results of computational fluid dynamics simulations of gas-solid flow in the riser section of a laboratory-scale (ID = 0.23 m, height = 7.6 m) circulating fluidized bed with a radial secondary air injector. The gas-solid flow model is based on the two-fluid (Eulerian-Eulerian) approach, where both gas and solids phases are treated as interpenetrating continua. A granular kinetic theory model is used to describe the solids phase stresses. The simulation results are compared with measured pressure drop and axial particle velocity profiles; reasonable agreement is obtained. Qualitatively, excellent agreement is obtained in predicting the increase in solids volume fraction below secondary air ports, the accumulation of solids around the center of the riser due to momentum of secondary air jets, and the absence of the solids down-flow near the wall above the secondary air injection ports, which are the prominent features of secondary air injection observed in the experiments.     

AHP and multichoice goal programming integration for course planning

Course planning is one of the important problems in the education systems of universities. The processes cannot continue efficiently without planning, and various interruptions can appear in the system. This way decisions concerning which courses, when, how, and for what purposes should be answered by considering the available resources and stakeholders’ preferences. Besides, universities aiming to be in the European Higher Education Area (EHEA) have to adapt their systems to the Bologna process in order to create a lifelong student‐centered, learning‐oriented area based on quality assurance. In this study, an integrated approach based on the analytic hierarchy process (AHP) and multichoice goal programming (MCGP) model was proposed to construct an efficient course plan following the Bologna process. The proposed approach was applied in an industrial engineering department.     

HYDRODYNAMIC STUDIES IN A HALF SLOT-RECTANGULAR SPOUTED BED COLUMN

Experiments were carried out in a half slot-rectangular spouted bed to investigate the effects of slot width and lower section basal angle on column hydrodynamics. Flow regimes, minimum spouting velocity, spouting and maximum pressure drops, and maximum spoutable bed height were determined for 4 mm diameter polyethylene particles. The results are compared with those for conventional cylindrical and rectangular spouted beds. Correlations for each hydrodynamic parameter are developed and compared with equations available in the literature.     

Kinetics of non-congruent dissolution of E-glass fiber in saturated calcium hydroxide solution

The kinetics of non-congruent dissolution of long E-glass fiber in saturated calcium hydroxide solution has been investigated at 25°C in a closed reactor adopting the rotating disc method for the sample holder. The fiber dissolution rate (), measured from the relative loss weight of the fiber after selective dissolution of the attack layer in acetic acid, is a linear function of time, what implies an interfacial dissolution process. However, the kinetics does not stay regular for a long time due to local detachment of the attack layer. The comparison between = f (t) and ′ = f (t) curves, where ′ is the formation rate of the attack layer, shows that the formation of the layer does not only imply the deposit of a bad-crystalline hydrated calcium silicate but the nucleation and growth of solid calcium hydroxide and calcium carbonate resulting from the transfert, to the interface, of ions coming from the liquid phase. This phenomenon was precedently observed by some other authors in the case of glass-fiber reinforced cement matrix.     

Fusion of smartphone sensor data for classification of daily user activities

Multimedia Tools and Applications - New mobile applications need to estimate user activities by using sensor data provided by smart wearable devices and deliver context-aware solutions to users...     

Exploring the Belief Systems of Software Development Professionals

It is commonly accepted that an individual's beliefs and actions are based on his or her assessment and perceptions of the world. In order to determine what practices an individual is likely to follow at any given time, it is necessary to understand the individual's behavioral intention in a given circumstance. From an Information Technology perspective, a software development professional's belief systems are potentially the basis for the adoption and implementation of new and innovative work practices and processes. In this article, we explore the belief systems of software development professionals in order to understand the beliefs underlying intention and practice, and we seek answers about how they adopt or reject new and innovative software development processes and practices. The results point out a strong influence of past experiences, personality types, and repeated behavior on current software development processes and practices in industrial settings.     

A greedy gradient-simulated annealing selection hyper-heuristic

Educational timetabling problem is a challenging real world problem which has been of interest to many researchers and practitioners. There are many variants of this problem which mainly require scheduling of events and resources under various constraints. In this study, a curriculum based course timetabling problem at Yeditepe University is described and an iterative selection hyper-heuristic is presented as a solution method. A selection hyper-heuristic as a high level methodology operates on the space formed by a fixed set of low level heuristics which operate directly on the space of solutions. The move acceptance and heuristic selection methods are the main components of a selection hyper-heuristic. The proposed hyper-heuristic in this study combines a simulated annealing move acceptance method with a learning heuristic selection method and manages a set of low level constraint oriented heuristics. A key goal in hyper-heuristic research is to build low cost methods which are general and can be reused on unseen problem instances as well as other problem domains desirably with no additional human expert intervention. Hence, the proposed method is additionally applied to a high school timetabling problem, as well as six other problem domains from a hyper-heuristic benchmark to test its level of generality. The empirical results show that our easy-to-implement hyper-heuristic is effective in solving the Yeditepe course timetabling problem. Moreover, being sufficiently general, it delivers a reasonable performance across different problem domains.