Synthesis,characterization, thermal,electrical and electrochemical studies of oligo nitrobenzimidazoles and their p–n diode applications

Three novel nitro oligobenzimidazoles, oligo-2-(6-nitro-1H-benzo[d]imidazol-2-yl)phenol (OBINP2), oligo-3-(6-nitro-1H-benzo[d]imidazol-2-yl)phenol (OBINP3) and oligo-4-(6-nitro-1H-benzo[d]imidazol-2-yl)phenol (OBINP4) were synthesized by oxidative polycondensation of benzimidazole monomers with NaOCl in aqueous alkaline medium. The structure of the monomers and oligomers were confirmed by FT-IR, UV–Vis, ¹H and ¹³C NMR spectroscopic techniques. The monomer BINP2 and its oligomer are showing dual emission through excited state intramolecular proton transfer process. The band gap values of monomers and oligomers were calculated from both UV–Vis spectroscopic and cyclic voltammetric data. Theoretical band gap values of monomers obtained from DFT were compared with experimentally calculated band gap values. The electrical conductivity of I₂ doped and undoped oligomers were measured using two point probe technique and are showing good correlation with the charge densities on imidazole nitrogen obtained from Huckel method. The conductivity of oligomers increases with increase in iodine vapour contact time up to 144 h. The variation of dielectric properties of oligomers has been investigated at different frequency and temperature. Among the oligomers, OBINP3 is having greater thermal stability as evidenced by its high carbine residue of around 65% at 600 °C in thermogravimetric analysis.     

Optimal Confidential Mechanisms in Smart City Healthcare

Smart City Healthcare (SHC²) system is applied in monitoring the patient at home while it is also expected to react to their needs in a timely manner. The system also concedes the freedom of a patient. IoT is a part of this system and it helps in providing care to the patients. IoT-based healthcare devices are trustworthy since it almost certainly recognizes the potential intensifications at very early stage and alerts the patients and medical experts to such an extent that they are provided with immediate care. Existing methodologies exhibit few shortcomings in terms of computational complexity, cost and data security. Hence, the current research article examines SHC² security through Light Weight Cipher (LWC) with Optimal S-Box model in PRESENT cipher. This procedure aims at changing the sub bytes in which a single function is connected with several bytes’ information to upgrade the security level through Swam optimization. The key contribution of this research article is the development of a secure healthcare model for smart city using SHC² security via LWC and Optimal S-Box models. The study used a nonlinear layer and single 4-bit S box for round configuration after verifying SHC² information, constrained by Mutual Authentication (MA). The security challenges, in healthcare information systems, emphasize the need for a methodology that immovably concretes the establishments. The methodology should act practically, be an effective healthcare framework that depends on solidarity and adapts to the developing threats. Healthcare service providers integrated the IoT applications and medical services to offer individuals, a seamless technology-supported healthcare service. The proposed SHC² was implemented to demonstrate its security levels in terms of time and access policies. The model was tested under different parameters such as encryption time, decryption time, access time and response time in minimum range. Then, the level of the model and throughput were analyzed by maximum value i.e., 50 Mbps/sec and 95.56% for PRESENT-Authorization cipher to achieve smart city security. The proposed model achieved better results than the existing methodologies.     

Robust tracking control for uncertain fuzzy systems with time delay and external disturbances

In this article, robust tracking and disturbance rejection problem for Takagi–Sugeno fuzzy systems with time delay and external disturbances are discussed. Specifically, proportional-integral controller with an enhanced equivalent-input-disturbance technique is constructed to force the output trajectories to track the bounded reference input signal even in the presence of external disturbances. Further, the resulting fuzzy control system can be represented as an augmented system with state delay and uncertainties and the output tracking problem is transformed into stabilization problem of the augmented system. In the stabilization analysis, the considered fuzzy system does not share the same membership functions with the proposed control. Moreover, the delay-dependent stabilization criteria for the addressed fuzzy system are presented in the form of linear matrix inequalities by the virtue of augmented Lyapunov–Krasovskii functional. To be specific, the symmetric matrices involved in the Lyapunov–Krasovskii functional need not be positive definite. Ultimately, three numerical examples are offered to support the validity of the established theoretical results.     

Self-consistent 3-D numerical modeling of a uniformly doped nanoscale FinFET using interpolating wavelets

A three-dimensional numerical modeling of a uniformly doped nanoscale FinFET including quantum-mechanical effects has been developed. A self-consistent solution of 3D Poisson-Schr?dinger equation has been obtained using multiresolution approach to achieve adaptively refined mesh that can be used to get a solution with the same level of accuracy of a reference, but with a considerable lower number of points. To the best of our knowledge, this is the first approach for the self-consistent solution to surface potential computations of nanoscale FinFET device using interpolating wavelets. It performs an efficient computation by dynamically adjusting the computational mesh in order to obtain surface potential variations during simulation. This method allows non-uniform grids and scales the CPU time linearly with the number of mesh points. The exact potential profile, subthreshold swing (S) and threshold voltage (V _th) rolloff are estimated. The accuracy of the model has been verified with finite difference, finite element and experimental results. This method provides more accurate results than other existing methods.     

Low Latency,Area and Optimal Power Hybrid Lightweight Cryptography Authentication Scheme for Internet of Things Applications

The Internet of Things (IoT) is proved as technologically competent connecting many devices via the internet. Now in networks transmitting a large quantity of data in a secure manner is of vital concern as communication is on the increase. Hence an efficient cryptographic methodology is essential to transmit securely. However, conventional encryption algorithms are having high computational complexity, more power consumption and high memory occupation. In this paper, low latency, area and optimal power Hybrid Lightweight Cryptography Authentication Scheme which is utilizing the 8-bit manipulation principle (HLCAS) is proposed and implemented. For such a method verification is done and validated for speech signal utilizing MATLAB. The correlation and histogram attributes have been computed to validate the security level. The complexity of the hardware is validated utilizing devices of FPGA of Spartan3E XC3S500E. From the implementation result, it has been found that the proposed HLCAS method has 5.4 ns latency, 0.9 K bytes RAM and consumes 202 mW power. From the comparison with a few reported methods it has been observed that the proposed HLCAS method outperform other methods.

     

Synthesis and characterization of poly (amide-imide-imide)s based on diacids with bulky m-chloro phenyl moiety and rigid pyridine moiety

A series of novel aromatic diamines containing kinked m-chloro phenyl moiety was synthesized by the reaction of m-chloro benzaldehyde with 2,6-dimethyl aniline. The tetraimide diacid was synthesized by using the prepared diamine with benzophenone tetracarboxylic acid dianhydride (BPTDA) and p-amino benzoic acid. The polymers were prepared by treating the tetraimide diacid with different aromatic diamines. The structures of the monomers and polymers were identified by ¹H-NMR, FTIR,¹³C-NMR and elemental analysis. The polymers showed excellent thermal stability, solubility and mechanical properties. Their structure–property relationship was studied by comparing these m-chloro polymers with polymers containing rigid Pyridine moiety.     

Compact fractal based UWB mimo antenna with dual band dispensation

Analog Integrated Circuits and Signal Processing - In this study, a fractal-based ultra-wideband multiple-input-multiple-output antenna with a compact structure is proposed. By using monopole...     

UVB-Stimulated TNFα Release from Human Melanocyte and Melanoma Cells Is Mediated by p38 MAPK

Ultraviolet (UV) radiation activates cell signaling pathways in melanocytes. As a result of altered signaling pathways and UV-induced cellular damage, melanocytes can undergo oncogenesis and develop into melanomas. In this study, we investigated the effect of UV-radiation on p38 MAPK (mitogen-activated protein kinase), JNK and NFκB pathways to determine which plays a major role in stimulating TNFα secretion in human HEM (melanocytes) and MM96L (melanoma) cells. MM96L cells exhibited 3.5-fold higher p38 activity than HEM cells at 5 min following UVA + B radiation and 1.6-fold higher JNK activity at 15–30 min following UVB+A radiation, while NFκB was minimally activated in both cells. Irradiated HEM cells had the greatest fold of TNFα secretion (UVB: 109-fold, UVA + B: 103-fold & UVB+A: 130-fold) when co-exposed to IL1α. The p38 inhibitor, SB202190, inhibited TNFα release by 93% from UVB-irradiated HEM cells. In the UVB-irradiated MM96L cells, both SB202190 and sulfasalazine (NFκB inhibitor) inhibited TNFα release by 52%. Although, anisomycin was a p38 MAPK activator, it inhibited TNFα release in UV-irradiated cells. This suggests that UV-mediated TNFα release may occur via different p38 pathway intermediates compared to those stimulated by anisomycin. As such, further studies into the functional role p38 MAPK plays in regulating TNFα release in UV-irradiated melanocyte-derived cells are warranted.     

Wimax (IEEE 802.16 m) system based on space time block code and discrete multiwavelet transform and implementation in FPGA

MIMO (Multiple Input Multiple Output) scheme uses transmit diversity technique which results in high throughput with increased channel capacity. The complexity of MIMO system increases the area and power requirements of the system. The proposed work is to achieve good spectral efficiency and reduction of interference by introducing multiwavelet with MIMO technology. The improvements directly results in reduction of BER (Bit Error Rate) for a given SNR (Signal to Noise Ratio). Implementation of the proposed scheme in FPGA (Field Programmable Gate Array)—virtex5 (xcvlx30t-1f665) shows a considerable improvement in speed and area when compared with the existing methods.     

Factors Affecting Quality of Dried Low-Rank Coals

The chemical and physical properties of coal are strongly affected by the upgrading process employed. For high-moisture coals, upgrading involves thermal dehydration to improve the calorific value of the coal on mass basis. This study evaluates the feasibility of upgrading a low-rank/grade coal using the oven drying method. The objective of this research work is to study the drying characteristics of low-rank coals and to understand the factors affecting the quality of dried low-rank coals. This article describes laboratory experiments conducted on the characterization of the low-rank coals before and after the drying process. The results on drying kinetics, re-absorption of coal samples, and proximate analysis of coal samples before and after drying are discussed. It was found that the upgrading process produced coal with better heating value and combustion characteristics than those of the raw coal samples.