基于自组织映射的改进 BP 神经网络短期光伏出力预测研究

针对光伏发电出力随机波动给电网调度造成困难这一问题,提出了一种基于SOM-PSO-BP的模型对光伏有功功率进行短期预测,用于提高电网对可再生能源的调度能力。首先采用自组织映射对原始数据组进行聚类降维;接着使用粒子群算法对BP神经网络的权重和偏置矩阵进行寻优;然后利用训练集构造SOM-PSO-BP预测模型;最后在对比仿真中验证了所提方法的有效性。     

Sonochemical preparation and photocatalytic properties of CdS QDs /Bi2WO6 3D heterojunction

Hierarchical CdS quantum dots (QDs)/ Bi₂WO₆ three-dimensional (3D) heterojunction photocatalyst was successfully synthesized by a facile green ultrasonic method for the first time. Photocatalytic activities under visible light irradiation were tested by the degradation of Rhodamine B (RhB) and tetracycline hydrochloride (TC), and the reduction of Cr(VI) in aqueous solution. As compared to pure CdS and Bi₂WO₆, CdS QDs/ Bi₂WO₆ heterojunctions manifested a significantly enhanced photocatalytic activity for these treatments. When the effect of the mass ratio of CdS QDs to Bi₂WO₆ was investigated, 3% CdS QDs/ Bi₂WO₆ heterojunction showed the highest photocatalytic efficiency: the efficiency for RhB degradation was 94.5% for 30?min and this value was about 6 times and 1.5 times higher than those of pure Bi₂WO₆ and CdS QDs. This enhancement was majorly accredited to the synergetic effect between Bi₂WO₆ and CdS QDs, which included intimate contact and matched band gap potentials between 0D CdS QDs and 3D Bi₂WO₆, which contributed to the efficient electron-hole separation and fast transfer of charge carriers between CdS QDs and Bi₂WO₆. A possible Z-scheme photocatalytic mechanism was proposed, in which the sample was provided with the efficient charge transfer pathway and was endowed with excellent oxidation and reduction ability.     

Synthesis and characterization of poly(o‐toluidine) doped with organic sulfonic acid by solid‐state polymerization

Poly (o‐toluidine) (POT) salts doped with organic sulfonic acids (β‐naphthalene sulfonic acid, camphor sulfonic acid, and p‐toluene sulfonic acid) were directly synthesized by using a new solid‐state polymerization method. The FTIR spectra, ultraviolet visibility (UV–vis) absorption spectra, and X‐ray diffraction patterns were used to characterize the molecular structures of the POT salts. Voltammetric study was done to investigate the electrochemical behaviors of all these POT salts. The FTIR and UV–vis absorption spectra revealed that the POT salts were composed of mixed oxidation state phases. All POT salts contained the conducting emeraldine salt (half‐oxidized and protonated form) phase; the pernigraniline (fully oxidized form) phase is predominant in POT doped with β‐naphthalene sulfonic acid, and POT doped with p‐toluene sulfonic acid had the highest doping level. The X‐ray diffraction patterns showed that the obtained POT doped with organic sulfonic acids were lower at crystallinity. The conductivity of the POT salts were found to be of the order 10^?3‐10^?4 S/cm. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1630–1634, 2005     

改性蒙脱土对新疆和丰煤热解行为的影响

采用机械球磨法制得不同Zr含量的改性蒙脱土催化剂,通过X射线衍射仪(XRD)、物理吸附仪(BET)和化学吸附仪(NH₃-TPD)表征其结构特征,在固定床中考察催化剂对煤热解产物分布和焦油品质的影响规律,基于模型化合物苄基苯基醚(BPE)、联苄和联苯的热解行为分析,探讨了催化剂对煤中共价键断裂规律的作用机制。结果表明：酸洗可增加蒙脱土的比表面积,添加Zr后该值先减小后增加,酸性与之相反,当Zr含量为24%(质量)(24ZrAM)时,催化剂的酸量与强酸强度达最高。在xZrAM的作用下,热解焦油产率和沥青含量均下降,特别是24ZrAM对焦油的提质活性最好,轻油组分分率最高,为53.2%(质量),长链烃含量降低了22.1%,酚类化合物增加了22.5%。BPE、联苄和联苯的转化率分别比无催化剂时提高了87.2%、63.2%和31.3%,说明24ZrAM可促进长链烃裂解和C_al—O、C_al—C_al和C_ar—C_ar键的断裂。     

改善高磷蠕墨铸铁机械性能的探讨

本文研究分析了含磷量对利用新疆地方生铁制取蠕铁的磷共晶数量、分布及机械性能的影响，并通过强化孕育和热处理方式进一步提高了该铸铁的机械性能指标．     

维吾尔语拼接式语音合成方法研究

首先简要介绍语音合成技术的总体概念及研究状况,然后提出用不同长度的单元进行拼接的维吾尔语语音合成方法。该方法能更好地利用自然语流的原始信息,提高合成语音的自然度,同时也能提高系统的灵活性。     

Effect of β‐cyclodextrin on the solid‐state synthesized polyaniline doped with hydrochloric acid

Polyaniline (PANI) salts doped with hydrochloric acid were prepared by using solid‐state polymerization in the presence of β‐cyclodextrin (β‐CD) at room temperature. The fourier transform infrared (FTIR) spectra, ultraviolet‐visible absorption spectra, X‐ray diffraction patterns were used to characterize the molecular structures of these polymers. Cyclic voltammetry study and conductivity measurements were done to investigate their electrochemical behaviors. The morphology of polymers was studied by the scanning electron microscopy and transmission electron microscopy. The results showed that PANI salts prepared in the presence of β‐CD had different physicochemical characteristics compared with PANI salt prepared in the absence of β‐CD. When the molar ratio of aniline to β‐CD was 80/20, the obtained PANI salt displayed higher crystallinity, conductivity and electrochemical properties. However, these properties were opposite on condition that the molar ratio of aniline to β‐CD was 50/50. The results also revealed that the morphology of PANI salt was affected by β‐CD, especially at aniline/β‐CD molar ratio in the feed of 50/50, in which PANI salt displayed rodlike structure morphology with a diameter of near 80–100 nm. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Acidochromicity of a low‐molecular‐weight pyrimidine‐based copolymer

A new type of low‐molecular‐weight polypyrimidine in a π‐conjugated main chain was prepared by a Grignard reaction between 2‐amino‐4,6‐dichloropyrimidine and 1,4‐dibromo‐2,5‐didodecyloxybenzene in the presence of [1,2‐Bis(diphenylphosphino) ethane]dichloronickel(II). The structure of the copolymer was fully elucidated by Fourier transform infrared spectroscopy, ¹H‐NMR, and elemental analysis. The copolymer had good solubility in common organic solvents. The copolymer displayed a bathochromic shift when protonated with an organic or inorganic acid in chloroform or tetrahydrofuran. The copolymer depicted facile p‐doping and good electron‐transporting electrochemical properties in a 1M H₂SO₄ aqueous solution. The copolymer showed a narrow polydispersity of 1.04. Thermogravimetric analysis showed that the copolymer had a certain thermal stability with no decomposition at a temperature of 250°C under N₂. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41174.     

Doping effect of organic sulphonic acids on the solid‐state synthesized polyaniline

Polyaniline (PANI) salts doped with organic sulfonic acids (methanesulfonicacid, p‐toluenesulphonic acid, and dodecylbenzenesulphonic acid) were first synthesized by using solid‐state polymerization method. The polymers were characterized by Fourier transform infrared (FTIR) spectra, ultraviolet‐visible spectrometry, X‐ray diffraction, cyclic voltammetry, scanning electron microscopy, transmission electron microscopy, and conductivity measurements. It was found that PANI doped with p‐toluenesulphonic acid is formed in conductive emeraldine oxidation state, and displayed higher doping level and cyrstallinity. On the contrary, PANI doped with dodecylbenzenesulphonic acid was lower at doping level and highly amorphous. In accordance with these results, the conductivity and electrochemical acitivity was also found to be higher in p‐toluenesulphonic acid‐doped PANI, and these properties were opposite in the case of dodecylbenzenesulphonic acid. The results also revealed that the morphology of dodecylbenzenesulphonic acid‐doped PANI was remarkably different from other PANI salts. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

我国水库大坝老化现状初步分析

一般来说,大坝进入老龄阶段以后,其几何学、物理力学、水利学、热力学、化学等综合特性将随着坝龄的增加而逐渐恶化,直接影响大坝的使用寿命和健康安全运行。本文首先从大坝综合特性随坝龄的变化规律人手,解释了大坝老化的概念,然后对我国现有大坝运行年龄结构进行了统计分析,总结出了大坝老化主要的问题及其带来的后果,提出了系统研究大坝老化的必要性和重要性。