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21.
The interface behaviour in the facilitated co-transport of Ag(I), Cu(II) and Zn(II) ions through supported liquid membranes (SLMs) made of a flat-sheet polypropylene membrane support containing cryptands (2.2.2 or 2.2.1) as carriers was studied. The liquid-liquid extraction tests showed a maximum distribution coefficient when the carrier concentration was greaterthan 10−4M. In transport experiments the transmembrane flux increased with increasing carrier concentration reaching a limiting value at greater than 10−3M concentration. The calculation ofthe diffusion coefficients in membranes showed ahigherdiffusivityof2.2.2-metal complexes with respect to 2.2.1-metal complexes for silver ions. A sequence of diffusivity D(Ag+)>D(Cu2+)>D(Zn2+) was obtained, but carrier 2.2.1 showed a higher selectivity through copper ions. A sequence of diffusivity D(Cu2+)>D(Zn2+)>D(Ag+) was obtained. The diffusivity was significantly higher when using Celgard 2500 support compared to Celgard 2400 or 2402. Variable metal ion concentrations in the feed phase fluxes almost zero, at less than 10−2 M concentration, were obtained. In the transient state of the transport through the SLM, different molar flow rates at the feed-membrane and membrane-strip interfaces were observed. The selectivity of the interfaces containing 2.2.2 in the separation binary mixtures of ions showed the following separation factors: SFAgZn = 2.50, SFAgCu = 1.64, SFcuZn = 1.42. 相似文献
22.
Abdallah Chahadih Hicham El Hamzaoui Rémy Bernard Luc Boussekey Laurence Bois Odile Cristini Marc Le Parquier Bruno Capoen Mohamed Bouazaoui 《Nanoscale research letters》2011,6(1):542
Pulsed femtosecond laser irradiation at low repetition rate, without any annealing, has been used to localize the growth of PbS nanoparticles, for the first time, inside a transparent porous silica matrix prepared by a sol-gel route. Before the irradiation, the porous silica host has been soaked within a solution containing PbS precursors. The effect of the incident laser power on the particle size was studied. X-ray diffraction was used to identify the PbS crystallites inside the irradiated areas and to estimate the average particle size. The localized laser irradiation led to PbS crystallite size ranging between 4 and 8 nm, depending on the incident femtosecond laser power. The optical properties of the obtained PbS-silica nanocomposites have been investigated using absorption and photoluminescence spectroscopies. Finally, the stability of PbS nanoparticles embedded inside the host matrices has been followed as a function of time, and it has been shown that this stability depends on the nanoparticle mean size. 相似文献
23.
Ben Ammar Nour Elhouda Essid Rym Saied Taieb en Murat Elkahoui Salem Hamzaoui Ahmed Hichem 《Polymer Bulletin》2020,77(3):1343-1357
Polymer Bulletin - The aim of this study was to elaborate a suitable hydrogel to be used as drug carrier for antileishmanial treatment. Therefore, a PVP hydrogel was synthesized using gamma... 相似文献
24.
M. Abdelaziz 《应用聚合物科学杂志》2004,94(5):2178-2186
Poly(vinyl alcohol) (PVA) films filled with (x)CsBr(15 ? x)MnCl2, where 0.0 ≤ x ≤ 15%, were prepared by a casting technique. The crystal structure properties of the prepared films were examined by XRD, DTA, and FTIR. A correlation between XRD, DTA, and FTIR of the filled polymer was discussed. Optical absorption measurements revealed two optical band gaps (Eg1 and Eg2). The electrical properties were studied using dc electrical conductivity. The filling level (FL) dependency of Eg1 and Eg2, thermal activation energy (ΔE), and hopping distance (R0) are given to illustrate the behavior of the filled polymers. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 2178–2186, 2004 相似文献
25.
The corrosion mechanisms of T24, T92, VM12, and AISI 304 steels are studied under the influence of NaCl–KCl, NaCl–Na2SO4, and KCl–K2SO4 salt mixtures in a dry air atmosphere at 650°C for 15 days. NaCl–KCl was the most aggressive deposit and AISI 304 stainless steel exhibited the highest corrosion resistance. There was no relation between the Cr content of the ferritic steels and their corrosion resistance in NaCl–KCl. In contrast, the resistance of high-Cr steels was better when exposed to NaCl–Na2SO4 and KCl–K2SO4. The high-Cr and the low-Cr steels were more susceptible to NaCl–Na2SO4 and to KCl–K2SO4, respectively. 相似文献
26.
José Antonio Cayuela Mirela Rada María del Carmen Pérez‐Camino Mohamed Benaissa Elamrani Abdelaziz Ángeles Guinda 《European Journal of Lipid Science and Technology》2008,110(12):1159-1166
The present study was conducted to know the possible influence of the seed treatment, method of extraction and geographical origin on the quality and chemical composition of argan oil. Artisanally and semiautomatically extracted argan oils, from roasted and unroasted seeds, from interior and coast areas, were studied. The quality parameters analyzed were acid value, peroxide value, K232 and K270, triacylglycerols and fatty acid composition, polar compounds, total phenols, tocopherol content and oil stability index (OSI). Seed treatment and extraction method showed a higher influence on quality parameters than geographical area; the quality parameters of the different oils were discussed. The total phenolic content in all analyzed samples was lower than 10 ppm. γ‐Tocopherol was the major tocopherol (84.4–86.4%) with a high contribution to the total tocopherol content (383–485 ppm). The OSI of the argan oil samples were well correlated (R = 0.97) with the tocopherol contents. The argan oil samples obtained from roasted seeds presented higher stability (26–38 h) than the oils from unroasted seeds (16–32 h). 相似文献
27.
Omar Azouani Mourad Keddam Omar Allaoui Abdelaziz Sehisseh 《Protection of Metals and Physical Chemistry of Surfaces》2017,53(2):306-311
In this work, the EN-GJS-400-15 cast iron was pack-borided in a powder mixture composed of 5% B4C, 5% NaBF4 and 90% SiC at the three temperatures: 900, 950 and 1000°C for 2, 4 and 6 h, respectively. The pack-borided EN-GJS-400-15 cast iron was characterized by the following experimental techniques: optical microscopy, XRD analysis and Microhardness Vickers tester. The growth kinetics of boride layers was also investigated. As a consequence, the boron activation energy was found to be 212.28 kJ mol–1 for the EN-GJS-400-15 cast iron. Based on a regression model, a useful equation was derived to estimate the boride layer thickness as a function of the boriding parameters (time and temperature). A good agreement was then obtained between the predicted values of boride layers thicknesses and those measured experimentally. In addition, an iso-thickness diagram was proposed to be used as a simple tool to select the boride layers thicknesses according to the potential applications of EN-GJS-400-15 cast iron in industry. 相似文献
28.
Fadi Al-Badour Nesar Merah Abdelrahman Shuaib Abdelaziz Bazoune 《Journal of Materials Processing Technology》2013,213(8):1433-1439
A 3-dimensional localized finite element model (FEM) is developed to predict likely conditions that result in defect generation during friction stir welding (FSW). The workpiece is modeled using Eulerian formulation, while the tool is modeled using Lagrangian. Coulomb's frictional contact model is adopted to define the tool workpiece interaction, while the welding speed is defined by material inflow and outflow velocities. The numerical results show that the coefficient of friction has a major effect on void formation; the lower the friction coefficient is applied, the larger the void is formed. Furthermore, welding using force control (FC) at lower welding speed results in smaller void size and wider plastic zone, leading to higher quality weld. 相似文献
29.
Julien Orlans Carole Vincent-Monegat Isabelle Rahioui Catherine Sivignon Agata Butryn Laurent Soulre Anna Zaidman-Remy Allen M. Orville Abdelaziz Heddi Pierre Aller Pedro Da Silva 《International journal of molecular sciences》2021,22(9)
Peptidoglycan recognition proteins (PGRPs) are ubiquitous among animals and play pivotal functions in insect immunity. Non-catalytic PGRPs are involved in the activation of immune pathways by binding to the peptidoglycan (PGN), whereas amidase PGRPs are capable of cleaving the PGN into non-immunogenic compounds. Drosophila PGRP-LB belongs to the amidase PGRPs and downregulates the immune deficiency (IMD) pathway by cleaving meso-2,6-diaminopimelic (meso-DAP or DAP)-type PGN. While the recognition process is well analyzed for the non-catalytic PGRPs, little is known about the enzymatic mechanism for the amidase PGRPs, despite their essential function in immune homeostasis. Here, we analyzed the specific activity of different isoforms of Drosophila PGRP-LB towards various PGN substrates to understand their specificity and role in Drosophila immunity. We show that these isoforms have similar activity towards the different compounds. To analyze the mechanism of the amidase activity, we performed site directed mutagenesis and solved the X-ray structures of wild-type Drosophila PGRP-LB and its mutants, with one of these structures presenting a protein complexed with the tracheal cytotoxin (TCT), a muropeptide derived from the PGN. Only the Y78F mutation abolished the PGN cleavage while other mutations reduced the activity solely. Together, our findings suggest the dynamic role of the residue Y78 in the amidase mechanism by nucleophilic attack through a water molecule to the carbonyl group of the amide function destabilized by Zn2+. 相似文献
30.
Elbasuney Sherif Hamed Abdelaziz Yehia M. Ramzy Hesham Abdelgawad Ahmed Gobara Mohamed Mokhtar Mohamed 《Journal of Inorganic and Organometallic Polymers and Materials》2021,31(9):3665-3676
Journal of Inorganic and Organometallic Polymers and Materials - Surface oxygen of oxide catalyst has low coordination number; they are negatively charged. Surface oxygen can act active site for... 相似文献