Accelerating SPARQL queries by exploiting hash-based locality and adaptive partitioning

State-of-the-art distributed RDF systems partition data across multiple computer nodes (workers). Some systems perform cheap hash partitioning, which may result in expensive query evaluation. Others try to minimize inter-node communication, which requires an expensive data preprocessing phase, leading to a high startup cost. Apriori knowledge of the query workload has also been used to create partitions, which, however, are static and do not adapt to workload changes. In this paper, we propose AdPart, a distributed RDF system, which addresses the shortcomings of previous work. First, AdPart applies lightweight partitioning on the initial data, which distributes triples by hashing on their subjects; this renders its startup overhead low. At the same time, the locality-aware query optimizer of AdPart takes full advantage of the partitioning to (1) support the fully parallel processing of join patterns on subjects and (2) minimize data communication for general queries by applying hash distribution of intermediate results instead of broadcasting, wherever possible. Second, AdPart monitors the data access patterns and dynamically redistributes and replicates the instances of the most frequent ones among workers. As a result, the communication cost for future queries is drastically reduced or even eliminated. To control replication, AdPart implements an eviction policy for the redistributed patterns. Our experiments with synthetic and real data verify that AdPart: (1) starts faster than all existing systems; (2) processes thousands of queries before other systems become online; and (3) gracefully adapts to the query load, being able to evaluate queries on billion-scale RDF data in subseconds.     

钢筋与钢纤维混凝土的黏结滑移性能及其关系模型

基于内贴应变片的钢筋与钢纤维混凝土局部黏结试件的拉拔试验,研究钢筋与不同强度钢纤维混凝土的黏结性能。通过对实测钢筋应变的分析,建立了以三次多项式表达的黏结应力分布函数,得到了各级荷载作用下钢筋与钢纤维混凝土黏结应力和相对滑移沿黏结区段的分布,进一步分析了钢纤维和混凝土强度对黏结性能的影响。结果表明,随钢纤维的体积率和混凝土强度的增大,黏结试件加载端附近的黏结应力提高,黏结应力极值总体向加载端靠拢;同时,加载端与自由端的滑移减小。最后,提出了能够较好反映钢筋与钢纤维混凝土受力过程的黏结-滑移关系模型。     

Numerical study of evaporation by mixed convection of a binary liquid film

This paper deals with a numerical analysis of the evaporation of binary liquid film. The film is falling down on one plate of a vertical channel under mixed convection channel. The first plate of a vertical channel is externally submitted to a uniform heated flux q₁ while the second one (y = d) is dry and isothermal. The liquid mixture consists of water (the more volatile component) and ethylene glycol while the gas mixture has three components: dry air, water vapour and ethylene-glycol vapour. The results concern the effects of the inlet parameters in the gas and in the liquid film on the interfacial pressure, temperature and concentration profiles. The evolutions of the heat fluxes and of the water and mixture evaporation rates have been analysed. Results obtained show, in particular, that it is possible to increase the accumulated evaporation rate of water and of the liquid mixture when the inlet liquid concentration of ethylene glycol (the less volatile component) is less than 40%. This result has been explained by the fact that an increase of the inlet liquid concentration of ethylene glycol has two antagonistic effects on the accumulated evaporation rates of water and of liquid mixture.     

Deposition and characterization of cold sprayed nanocrystalline NiTi

Binary 50Ni-50Ti mixture was prepared by mechanical alloying from elemental powders. After 48 h of milling, the nanocrystalline B2-NiTi powder was produced. Then, this as-milled powder was deposited by cold spraying in order to produce a target which can be used to create thin films by magnetron sputtering technique. The objective is to improve the electrical characterizations of the NiTi/SiO₂/Si M.O.S structures. The morphology evolution of the powder particles, the phase identification and the alloying evolution process as function of milling time were studied using scanning electron microscopy, X-ray diffraction and transmission electron microscopy. In addition, the target was also characterized using X-ray diffraction, Scanning electron microscopy, and microhardness measurements. The milling of powders leads to the formation of disordered nanocrystalline B2-NiTi with a crystallite size of about 12 nm and a microstrain of level 2.10%, after 48 h of milling. The microstructure, the composition and grain size of the milled powders for 24 h and 48 h characterized by TEM are heterogeneous. The as-deposited intermetallic NiTi can be retained in the coating with a lattice parameter of 0.3 nm, crystallite size of 14 nm, microstrain and high microhardness of 2% and 694 Hv_0.25, respectively.     

A novel analytical solution of mixed convection about an inclined flat plate embedded in a porous medium using the DTM-Padé

In this study, the problem of mixed convection about an inclined flat plate embedded in a porous medium is performed. The similarity transformations are applied to reduce governing partial differential equations (PDEs) to a set of nonlinear coupled ordinary differential equations (ODEs) in dimensionless form. An efficient mathematical technique, called the differential transform method (DTM), is used to solve the nonlinear differential equations governing the problem in the form of series with easily computable terms. Then, Padé approximant is applied to the solutions to increase the convergence of given series. It has been attempted to show the reliability and performance of the DTM in comparison with the numerical method (fourth-order Runge–Kutta) in solving this problem. The obtained solutions, in comparison with the numerical solutions admit a remarkable accuracy.     

Water mapping in hydrated soft materials

We present a method based on spatially resolved electron energy-loss spectroscopy in the cryo-STEM to map the spatial distribution of water in frozen-hydrated polymers. The spatial resolution is limited by the dose constraints imposed by radiation damage, and to stay within these constraints, the use of fine electron-probe sizes comes at the cost of reduced counts in the energy-loss spectra. Thus, at the resolution limit, the detection of isolated water-rich pixels or the identification of minor variations in water content across the specimen is complicated because one must distinguish significant fluctuations from noise. Here we develop a criterion with which to guide such a distinction. We characterize the intrinsic noise associated with spectral measurements under given illumination and acquisition conditions. We then use that noise in combination with scatter diagrams to threshold spectrum images and objectively identify statistically significant compositional fluctuations. We illustrate these ideas using a simulated spectrum dataset for a hypothetical blend of hydrophilic and hydrophobic homopolymers. We show that while a direct inspection of the water map may not allow any meaningful conclusions to be drawn, after applying the thresholding approach we can clearly identify the regions of the specimen that are rich in water. We also experimentally study a model blend system comprised of hydrophilic poly(vinyl pyrrolidone) (PVP) dispersed in a hydrophobic matrix of poly(styrene) (PS). By MLS fitting using damaged and undamaged PVP reference spectra, we determine that the critical dose characteristic of dry PVP is approximately 8000 e/nm2 using 200 keV incident electrons. Irradiating frozen-hydrated PVP gives rise to noticeable hydrogen evolution at doses of approximately 1500 e/nm2. To stay within this constraint we use doses of 400 e/nm2 and a pixel spacing in the spectrum imaging of 100 nm. In order to quantitatively map the water, PVP, and PS compositions, we measure their total inelastic scattering cross-sections. Direct inspection of the composition maps reveals the presence of large water-rich domains of the order of approximately 1 microm and the scatter-diagram thresholding approach identifies small water-rich domains one pixel in size.     

Stability and calibration of platinum/palladium thermocouples following heat treatment

In this paper we describe the changes in the thermo EMF of Pt/Pd thermocouples in the temperature range from 0 to 1100 °C following a series of heat treatment at 960 °C. The magnitudes of the changes in EMF, the short and long term stability of the thermocouple were estimated, experimental results are presented. For the calibration of the thermocouple we have employed a reference polynomial function given in the literature [Metrologia 35 (1998) 761] for Pt/Pd thermocouples based on the International Temperature Scale of 1990 (ITS-90).     

The effect of nanographite addition on the physical properties of poly(vinylidene fluoride)/hydroxypropyl cellulose blend

In this study, polymeric films of poly(vinylidene fluoride) (PVDF)/hydroxypropyl cellulose (HPC) blend filled with various graphite-nanoparticles (GNP) contents were prepared via solvent-mixing technique. The compatibility between PVDF and HPC polymers was studied. The variations in structure, dielectric and thermal properties were investigated over the frequency range (20 Hz–3 MHz) and temperature range (20–110 °C). The X-ray diffraction and differential scanning calorimetry results reveal that the crystallinity of PVDF was affected by the presence of HPC and GNP. The dielectric results reveal that the great enhancement of dielectric constant ( \(\upvarepsilon^{{\prime }}\) ) and ac conductivity (σ_ac) were observed. The dielectric properties were explained in terms of the dielectric polarization mechanism. Both HPC and GNP additions enhance the \(\upvarepsilon^{{\prime }}\) of PVDF due to the formation of β-phase polymorph and the interface effect between the GNP and blend matrix. The improvement of the thermal stability was observed due to the regular arrangement of the side chains. The easy processing, high dielectric constant, low tangent loss and high thermal stability of the composites make the composites attractive for practical applications in embedded capacitors.     

Co-crystallization for enhanced dissolution rate of bicalutamide: preparation and evaluation of rapidly disintegrating tablets

Objectives: Enhance the dissolution rate of bicalutamide via co-crystallization with sucralose (sweetener), with the aim to develop rapidly disintegrating tablets with subsequent prompt dissolution.

Significance: Bicalutamide is antiandrogenic agent for the treatment of prostate cancer but has low and variable oral bioavailability, mainly attributed to poor dissolution. Co-crystallization with benign excipients is promising for dissolution enhancement with the additive serving dual functions. The benefit will become greater if dissolution enhancement is associated with the development of orodispersible tablets which is suitable for elderly patients who are the most vulnerable for prostate cancer.

Methods: Bicalutamide was dissolved in acetone in the presence of increasing molar ratios of sucralose. The solvent was evaporated while mixing to deposit crystals that were subjected to wet co-grinding until drying. The developed solids were characterized using Fourier transform infrared spectroscopy, differential thermal analysis and X-ray diffraction in addition to monitoring bicalutamide dissolution.

Results: Instrumental analysis provided evidences for co-crystallization which was initiated at 1:1 molar ratio of bicalutamide to sucralose with complete co-crystallization at 1:4 molar ratio. The co-crystals provided faster bicalutamide dissolution compared with the unprocessed drug and that recrystalized from acetone in the absence of sucralose. The formulation containing bicalutamide with sucralose at 1:4 molar ratio was selected for tablet formulation into which superdisintegrants were included. The developed tablets exhibited flash disintegration with subsequent fast dissolution of bicalutamide.

Conclusions: The study introduced co-crystallization of bicalutamide with sucralose as an efficient tool to enhance the dissolution rate and to develop rapidly dissolving tablets for intraoral administration.