Solution Property and Irradiation Effect of Random Copolypeptides Composed of Ala and Pro Residues

Summary Poly(proline) and random copolypeptide composed of Pro and Ala residues were synthesized, and their solution properties and molecular conformation were investigated. Aqueous solutions of the polypeptide were irradiated with γ-rays above the transition temperature. It was shown that the transition temperature of the aqueous solution of the copolypeptide is influenced by Ala-residue content and γ-ray irradiation.     

250 kHz spectral linewidth operation of 1.5 μm multiple quantumwell DFB-LDs

The spectral linewidth observed in a 1.5 μm multiple-quantum-well distributed-feedback laser diode (MQW-DFB-LD) with 1500 μm cavity length is discussed. The spectral linewidth was drastically reduced in long-cavity MQW-DFB0-LDs through a reduction in threshold carrier density. A spectral linewidth of 250 kHz, the narrowest ever achieved, was obtained     

An undulator with a composite magnetic field

A new type of undulator greatly improved in tunability as compared with a usual undulator, is proposed. The undulator has a composite magnetic field which is a linear superposition of two sinusoidally varying fields with different spatial periods. The wavelength can be changed by varying the field strength of the longer-period component while keeping that of the shorter-period component at the highest possible value. Numerical calculations of the spectral brightness were carried out. The proper ratios between the two spatial periods were found to be 3:1, 5:1 and 7:1.     

Cholelithiasis in hamsters: Effects of cholic acid and calcium on gallstone formation

Dietary cholic acid (0.1%) and/or calcium (2.6% as calcium carbonate) were added to a semipurified diet containing cholesterol and ethynyl estradiol to determine whether the incidence of pigment and/or cholesterol gallstones would be changed. Male golden Syrian hamsters were fed the experimental diets for 96 days (Group 1, control; Group 3, cholic acid plus calcium) or only an average of 60 days (Group 2, 0.1% cholic acid). Animals in Group 2 became ill (weight loss, low food intake, diarrhea) possibly due to cholic acid (or deoxycholic acid) toxicity. Cholesterol gallstones and crystals were absent in all experimental groups. The incidence of pigment gallstones was: control, Group 1, 12/16; 0.1% cholic acid, Group 2, 3/13; and 0.1% cholic acid plus calcium, Group 3, 11/22. Cholic acid with or without calcium produced an elevation of both liver and plasma cholesterol: Group 2, 80.1 mg/g and 501 mg/dl; Group 3, 103.7 mg/g and 475 mg/dl vs Group 1, 65 mg/g and 209 mg/dl, respectively. The lithogenic indices of the bile were lower in Groups 2 and 3 compared to Group 1, controls, 0.45 and 0.58 vs 1.16, respectively. The extent of the portal tract pathology could not be correlated with the presence or absence of pigment gallstones or with the levels of lithocholic acid in the hamster bile. In summary, when semipurified diets were supplemented with ethynyl estradiol and cholic acid, with and without calcium supplementation, no cholesterol gallstones formed and the incidence of pigment gallstones was not altered.     

Dependence of property, cathode characteristics, thermodynamic stability, and average and local structures on heat-treatment condition for LiNi0.5Mn0.5O2 as a cathode active material for Li-ion battery

LiNi_0.5Mn_0.5O₂ was heat-treated under high oxygen-pressure and Ar-reducing conditions, and then the cathode properties, thermodynamic stability and average and local structures were investigated. From X-ray diffraction and ICP measurements, it was found that the pristine LiNi_0.5Mn_0.5O₂ had a single phase of the layered rock-salt structure although the Ni content was slightly rich compared with the nominal one. These characteristics were kept even after the heat-treatments. Charge–discharge cycle tests clarified that the cycle performance of LiNi_0.5Mn_0.5O₂ was improved by both the reducing and oxidizing treatments. From neutron diffraction and X-ray absorption fine structure measurements, the local distortion around the transition metal, especially Ni, was supposed to be one of the important factors to determine the cathode properties. It was also found that the sample with higher thermodynamic stability exhibited better capacity retention in the discharge–charge cycle tests.     

Transmission electron microscopic observations of the decomposition process of lithium alanate

The thermal decomposition process of lithium alanate (LiAlH₄) was investigated by TEM, TG-DTA and XRD. It was shown that LiAlH₄ decomposes through a two-step reaction: a liquid-to-solid phase transition in the first step of the decomposition and a solid-to-solid reaction in the second step of the decomposition, both steps accompanied by hydrogen release. The particle size of the aluminum (Al), which formed in the first decomposition step, was much larger than that in the second decomposition step. In addition, Al particles formed in the liquid phase of LiAlH₄ in the first decomposition step, while, they form in solid phase of Li₃AlH₆ in the second decomposition step, resulting in the kinetics of the first decomposition step being faster than that of the second decomposition step. The investigation clearly demonstrated the reaction model of the decomposition of LiAlH₄ in the nano-scale, showing different diffusion processes of Al in each of the decomposition steps.     

Particle morphology, electrical conductivity, crystal and electronic structures of hydrothermally synthesized (Ce,Sr)PO4

We focused on Sr-substituted CePO₄—i. e., (Ce,Sr)PO₄—with the monazite structure and synthesized the orthophosphates hydrothermally. As for the obtained products, we investigated the particle morphologies by SEM and electrical conduction properties by conductivity measurements. In order to estimate the crystal and electronic structures, neutron and synchrotron X-ray diffraction measurements were also carried out. As a result, it was found that (Ce,Sr)PO₄ with a single phase of the monazite structure was successfully prepared by the hydrothermal method and the substitution amount of Sr was almost equal to the nominal one. It was also demonstrated that a powder morphology of the (Ce,Sr)PO₄ depended on the synthetic conditions; i.e, concentrations of cation sources and pH of aqueous solution in the hydrothermal process. The Sr-substituted sample showed much higher conductivities than the unsubstituted one, in the same way as the (Ce,Sr)PO₄ synthesized by other methods reported previously.     

Characterization of endotoxic indicative organic matter (2-keto-3deoxyoctulosonic acid) in raw and biologically treated domestic wastewater

The aim of this research is to characterize the organic matter showing endotoxicity in domestic wastewater. It is assumed that endotoxicity is caused by lipo-polysaccharide (LPS), particularly large and hydrophobic molecules. In this study, a batch experiment (decay test for 12 h) was conducted to confirm whether LPS is the cause of endotoxicity or not. 2-keto-3deoxyoctulosonic acid (KDO) was used as an indicator of presence of LPS.A size and structural characterization of several samples from raw and domestic wastewater was also carried out in order know which fractions are causing endotoxicity. Endotoxin and KDO patterns were found to be similar, peaking at the same time. Thus, organic matter showing endotoxicity, such as LPS was released in the decay test. Moreover, the organic matter released from bacteria during decay test was partly biodegradable. Results from size characterization (Molecular Weight Distribution) showed that the majority of endotoxin (up to 82%), in domestic sewage and secondary effluents,is composed of molecules larger than 100 kDa and less than 0.1 μm. Similarly, structural characterization (hydrophobic and hydrophilic) showed that the majority of endotoxin, ranging from 59% to 83% of the total endotoxicity, is hydrophobic fractions. Therefore, removing large and hydrophobic molecules from wastewater can be an effective way to achieve a significant decrease in its endotoxicity.