Swelling properties of copolymeric hydrogels prepared by gamma irradiation

Crosslinked xerogels in the form of rods have been prepared to > 99.9% conversion by the γ-ray initiated copolymerization in vacuo ob n-butyl acrylate (BA) with N-vinyl-2-pyrrolidone (VP) in the presence and absence of a crosslinking agent. Thin (about 0.5 mm) disks were swollen in water at 21°C, the final equilibrium swelling being the true water content only for copolymers of high BA content. At low-medium BA content, swelling was accompanied by the release of a small water-soluble fraction, leading to a slightly reduced apparent value for the water content. True water contents could be obtained more rapidly by prior Soxhlet extraction with boiling water. For xerogels containing > about 75% VP by weight, the resultant hydrogels had water contents > about 80%. The influences of dose, dose rate copolymer composition, and concentration of crosslinker on the water content, sol fraction, and extension ratio were investigated. A high level of reproducibility in properties of the hydrogels was obtained by numerous replicate experiments. The feasibility of scaling up the preparation to produce long (60 cm) xerogel rods of uniform properties has been demonstrated. For these copolymers, swelling in several common organic solvents generally exceeds that in water.     

Purity of crosslinkers for polymeric hydrogel preparation

Chromatographic procedures are described for purifying and assessing the purity of two crosslinking agents commonly used in the preparation of polymeric hydrogels. Densities and refractive indices at different temperatures are reported for these materials.     

A novel double-circuit-rotor balanced induction motor for improvedslip-energy recovery drive performance. II. Experimental verificationand harmonic analysis

The merits of the new slip-energy recovery drive system that has been proposed in Part I of this paper (see ibid., vol.11, no.3, p.556-62, 1996) is demonstrated here. Experimental work is carried out to verify the simulated, models of the proposed and conventional systems. Furthermore, harmonic analysis of both systems is conducted analytically and confirmed numerically using the FFT. The main feature of the new proposed system is the significant reduction in the harmonics of the rotor flux linkage. This leads to substantial reductions in the stator current harmonics. Moreover, the pulsating components in the developed electromagnetic torque are also reduced significantly in the new proposed system     

A Spectral Mortar Element Discretization of the Poisson Equation with Mixed Boundary Conditions

In this paper, we study a spectral mortar element discretization of the Poisson equation on a square subject to mixed boundary conditions of Dirichlet and Neumann type. We carry out the numerical analysis of the method and derive error estimates. An efficient algorithm for the solution of the problem is proposed and numerical tests confirming the theoretical results are presented.     

Assessment of Landsat 7 Scan Line Corrector-off data gap-filling methods for seagrass distribution mapping

Methods to predict and fill Landsat 7 Scan Line Corrector (SLC)-off data gaps are diverse and their usability is case specific. An appropriate gap-filling method that can be used for seagrass mapping applications has not been proposed previously. This study compared gap-filling methods for filling SLC-off data gaps with images acquired from different dates at similar mean sea-level tide heights, covering the Sungai Pulai estuary area inhabited by seagrass meadows in southern Peninsular Malaysia. To assess the geometric and radiometric fidelity of the recovered pixels, three potential gap-filling methods were examined: (a) geostatistical neighbourhood similar pixel interpolator (GNSPI); (b) weighted linear regression (WLR) algorithm integrated with the Laplacian prior regularization method; and (c) the local linear histogram matching method. These three methods were applied to simulated and original SLC-off images. Statistical measures for the recovered images showed that GNSPI can predict data gaps over the seagrass, non-seagrass/water body, and mudflat site classes with greater accuracy than the other two methods. For optimal performance of the GNSPI algorithm, cloud and shadow in the primary and auxiliary images had to be removed by cloud removal methods prior to filling data gaps. The gap-filled imagery assessed in this study produced reliable seagrass distribution maps and should help with the detection of spatiotemporal changes of seagrasses from multi-temporal Landsat imagery. The proposed gap-filling method can thus improve the usefulness of Landsat 7 ETM+ SLC-off images in seagrass applications.     

Asian Mussel Watch Program: contamination status of polybrominated diphenyl ethers and organochlorines in coastal waters of Asian countries

Mussel samples were used in this study to measure the levels of polybrominated diphenyl ethers (PBDEs) and organochlorines (OCs) in the coastal waters of Asian countries like Cambodia, China, Hong Kong, India, Indonesia, Japan, Korea, Malaysia, the Philippines, and Vietnam. PBDEs were detected in all the samples analyzed, and the concentrations ranged from 0.66 to 440 ng/g lipid wt. Apparently higher concentrations of PBDEs were found in mussels from the coastal waters of Korea, Hong Kong, China, and the Philippines, which suggests that significant sources of these chemicals exist in and around this region. With regard to the composition of PBDE congeners, BDE-47, BDE-99, and BDE-100 were the dominant congeners in most of the samples. Among the OCs analyzed, concentrations of DDTs were the highest followed by PCBs > CHLs > HCHs > HCB. Total concentrations of DDTs, PCBs, CHLs, and HCHs in mussel samples ranged from 21 to 58 000, 3.8 to 2000, 0.93 to 900, and 0.90 to 230 ng/g lipid wt., respectively. High levels of DDTs were found in mussels from Hong Kong, Vietnam, and China; PCBs were found in Japan, Hong Kong, and industrialized/urbanized locations in Korea, Indonesia, the Philippines, and India; CHLs were found in Japan and Hong Kong; HCHs were found in India and China. These countries seem to play a role as probable emission sources of corresponding contaminants in Asia and, in turn, may influence their global distribution.     

Enhanced ductility and tensile properties of hybrid montmorillonite/cellulose nanowhiskers reinforced polylactic acid nanocomposites

Montmorillonite (MMT)/cellulose nanowhiskers (CNW) reinforced polylactic acid (PLA) hybrid nanocomposites were prepared by solution casting. CNW were isolated from microcrystalline cellulose using a chemical swelling method. An initial study showed that the optimum MMT content, for mechanical properties, in a PLA/MMT nanocomposite is five parts per hundred parts of polymer (phr). Various amounts of CNW were added to the optimum formulation of PLA/MMT to produce PLA/MMT/CNW hybrid nanocomposites. FT-IR analysis indicated the formation of some polar interactions, resulting in enhanced tensile properties of the hybrid nanocomposites. The highest tensile strength for the hybrid nanocomposites was obtained for a 1 phr CNW content. Young’s modulus was also found to increase with an increasing CNW content. Interestingly, the strain to failure (or ductility) of the hybrid nanocomposites increased significantly from ~10 to ~90 % with the addition of 1 phr CNW. This increase in ductility was proposed to be due to the nucleation of crazes and the formation of shear bands in the PLA.     

High‐efficiency indium gallium nitride/Si tandem photovoltaic solar cells modeling using indium gallium nitride semibulk material: monolithic integration versus 4‐terminal tandem cells

In this work, we present a double‐junction solar cell with a crystalline silicon solar cell as a bottom junction and an indium gallium nitride‐based semibulk‐structured solar cell as a top junction. Using SILVACO Atlas and taking into account polarization effects in III‐N materials, we have shown that 50% of indium is needed to ensure the current matching between the top cell and the bottom cell in 2‐terminal configuration. Such high indium composition is technologically challenging to grow. Thus, we have also modeled a 4‐terminal configuration showing the same performance (i.e. conversion efficiency close to 29%) where only 25% of indium content is needed. Copyright © 2016 John Wiley & Sons, Ltd.     

Effects of Dilute Acid Pretreatment on Chemical and Physical Properties of Kenaf Biomass

In the current research, kenaf represents an agricultural biomass that possesses enormous potential for industrial applications. Because of its complex structure, which is composed of cellulose, hemicellulose, and lignin, pretreatment process was conducted. Here, dilute acid pretreatment process was conducted, statistically using the response surface method, which included three parameters: mass of biomass (g), temperature (°C), and time (min). About 2 g of kenaf biomass was treated with 2% dilute sulphuric acid, and it was found to have higher glucose conversion (25.3%) when the process was conducted for 60 min at the temperature of 180°C. The main aim of the current research is to investigate the chemical and physical changes of kenaf biomass before and after the pretreatment. The changes could be clearly seen in the cellulose, hemicellulose, and lignin composition before and after the pretreatment, which were evaluated via TAPPI standard test methods. Morphological observation under scanning electron microscope confirmed the changes that took place on the kenaf biomass from complex to simple surface structure. Fourier transform infrared analysis confirmed the presence of cellulose, hemicellulose, and lignin contents of the kenaf biomass before and after pretreatment. Crystallinity of the treated kenaf biomass also increased from 46.6% to 70.0%, as evidenced from X-ray diffractometer analysis.