The Effect of Polar Head and Chain Length on the Physicochemical Properties of Micellization and Adsorption of Amino Alcohol-Based Surfactants

In this work, we have synthesized a series of quaternary ammonium from amino alcohols and n-bromoalkanes. The compounds are referred to as C_nEtOH, C_nPrOH, and C_niPrOH (where n = 12 and 14 carbons, EtOH = ethanol, PrOH = propanol, iPrOH = iso-propanol). Their structures were checked using the usual spectroscopic methods [¹H, ¹³C nuclear magnetic resonance (NMR) and infrared (IR)]. Their physicochemical properties in aqueous solution were studied using conductivity, surface tension, and ultra violet (UV)–visible absorption spectroscopy measurements. This study was conducted to show the effect of the linear hydrophobic chain and the location of the OH polar group with respect to the N⁺ quaternary ammonium on the physicochemical properties of the surfactants. The comparison between the physicochemical properties of the surfactants studied shows a distinct effect of the position of the OH group on the critical micelle concentration (CMC), the ionization degree (α), the area occupied at the interface (A_min), the free energy of adsorption (), and the free energy of micellization (). The intermolecular interaction between the synthetic surfactants and the methyl orange (OM) dye is related to the degree of hydration of the micelle, proven by the hypsochromic displacement of OM wavelength (λ_max) and ionization (α) of the micelles. The CMC, the degree of ionization, and the degree of hydration of the micelle follow the same trend.     

Fabrication of Polypropylene Nanofibers from Polypropylene/Polyvinyl Butyral Blend Films Using Laser-Assisted Melt-Electrospinning

Polypropylene (PP) nanofibers, a few hundred nanometers in diameter, are of immense importance in the fiber industry. This article reports the fabrication of delicate PP nanofibers. Polyvinyl butyral (PVB) was added to PP as a blend component, and a nozzle-free melt-electrospinning system with a line-like CO₂ laser melting device was used to manufacture PP nanofibers. We investigated the effect of PVB ratio on fiber diameter. The addition of PVB was found to be potentially very beneficial in PP/PVB blends, resulting in improved PP crystallinity and a steady decrease of fiber diameter with high productivity. The reduction of fiber diameter was attributed to the decline of viscosity, increase of surface adhesion properties, and polarity of blends due to the inclusion of PVB. To produce PP nanofiber, the PVB was removed from PP/PVB blend fibers with an ethanol treatment. A drastic drop of PP fiber diameter followed by fiber splitting was observed after PVB removal. We obtained PP nanofibers with a diameter as low as 181 ± 105 nm from the blend fiber with 90% PVB. Infrared spectroscopy of fibers demonstrated that PP fibers from pure polymer and blends showed the same characteristic peaks. POLYM. ENG. SCI., 60: 362–370, 2019. © 2019 Society of Plastics Engineers     

Preparation of asymmetric polysulfone/polyimide blended membranes for CO<Subscript>2</Subscript> separation

Asymmetric Flat sheet polysulfone-polyimide (PSF-PI) blended polymeric membranes (with PI content from 5–20%) have been fabricated following phase inversion technique. The membranes have been thoroughly characterized by the measurement of porosity, mechanical properties and also by SEM, FTIR and DSC analyses. With the increase in the PI content, the mechanical properties of the membranes, like Young’s modulus, tensile strength and elongation at break, increased. SEM investigations revealed that the surfaces of fabricated blended membranes possessed adequate homogeneity and their cross-sections showed non-porous top and diminutive porous substructure. From DSC analyses it has been observed that different compositions of the blended membranes exhibited single glass transition temperatures, implying proper compatibility of the polymers. The permeance of CO₂ and CH₄ through the membrane increased with the increase in PI content and it gradually decreased with the increase in the feed pressure in the range of 2–10 bar. Under the present investigation, the membrane with 20% PI content exhibited the maximum selectivity for the separation of CO₂/CH₄ gas mixes.     

Liver is not essential for solute transport during peritoneal dialysis

Based on theoretical calculations on solute exchange capacities of various peritoneal tissues, the liver has been predicted to account for up to 43% of the permeability-surface area product (PS) of the entire peritoneal "membrane" for a small solute (sucrose) during peritoneal dialysis (PD). In these calculations, the abdominal wall and the diaphragm were found to contribute only approximately 10 to 15% of the total PS. However, evisceration has in previous studies been shown to affect the PS characteristics during PD only marginally (10 to 30%). In such evisceration experiments the liver was usually not removed, and therefore it has been suggested that an intact liver might have significantly contributed to the solute exchange under these premises. We assessed the peritoneal PS of 51Cr-EDTA (constantly infused intravenously) and the plasma-to-peritoneal clearance (ClB-->P) of 125I-human serum albumin (RISA) (given as an i.v. bolus) in Wistar rats during acute PD. In one group of rats the liver surface was sealed off using Histoacrylate glue (N = 6) and in another group a 90% hepatectomy was performed, the remaining portion of the liver, usually the right lower lobe, being sealed off by glue (N = 6). A third group was sham operated to serve as control (N = 12). The PS for 51Cr-EDTA was 0.32 +/- 0.03(+/- SE) ml. min-1 (N = 12) during control, 0.32 +/- 0.04 ml.min-1 after "sealing" of the liver surface (N = 6, P > 0.1) and 0.40 +/- 0.03 after hepatectomy (N = 6, P > 0.1), that is, remained unchanged after experimental intervention. The CIB-->P of RISA during control was 5.88 +/- 1.0 microliter.min-1 (N = 10), and was not altered after hepatectomy, 6.17 +/- 0.48 microliters.min-1 (N = 5, P > 0.1), but slightly increased after liver surface sealing (9.69 +/- 1.09 microliters.min-1, N = 5, P < 0.05). In conclusion, the present experiments indicate that the liver does not play an essential role in the overall solute exchange between the plasma and the peritoneal cavity (PC) during PD.     

Void formation and morphology in NiAl

Void formation in stoichiometric NiAl was studied through controlled heat treatments and microstructural characterization through transmission electron microscopy. Voids were observed to form at temperatures as low as 400°C, but were noted to dissolve during annealing at 900°C. Two distinct void shapes, cuboidal and rhombic dodecahedral, were observed, often at the same annealing temperature. At higher temperatures (800°C) extensive dislocation climb, rather than void formation, was noted. The relative incidence of void formation and dislocation climb can be related to the mobility of vacancies at each annealing temperature. The shape of void type is described in terms of their relative surface energy and mode of nucleation.     

Prediction of scour below submerged pipeline crossing a river using ANN

The process involved in the local scour below pipelines is so complex that it makes it difficult to establish a general empirical model to provide accurate estimation for scour. This paper describes the use of artificial neural networks (ANN) to estimate the pipeline scour depth. The data sets of laboratory measurements were collected from published works and used to train the network or evolve the program. The developed networks were validated by using the observations that were not involved in training. The performance of ANN was found to be more effective when compared with the results of regression equations in predicting the scour depth around pipelines.     

\mathcal{C}oo\mathcal{PS} – Towards a method for coordinating personalized services

This paper presents oo which is a method for oordinating ersonalized Services. These services are primarily offered to mobile users. The concept of services is the object of intense investigations from both academia and industry. However, very little has been accomplished so far regarding first, personalizing services for the benefit of mobile users, and second, providing the appropriate methodological support for those (i.e., designers) who will be specifying the operations of personalization. Various obstacles still exist such as lack of techniques for modeling and specifying the integration of personalization into services, and existing approaches for service composition typically facilitate orchestration only, while neglecting contexts of users and services. ooconsists of several steps ranging from service definition and personalization to service deployment. Each step has some representation techniques, which aim at facilitating the specification and validation of the operations of coordinating personalized services. Zakaria Maamar is an associate professor in computer sciences at Zayed University, Dubai, United Arab Emirates. His research interests include Web services, software agents, and context-aware computing. Maamar has a PhD in computer sciences from Laval University. Djamal Benslimane is a full professor in computer sciences at Claude Bernard Lyon 1 University and a member of the Laboratoire d'InfoRmatique en Images et Systèmes d'information- Centre National De la Recherche Scientifique (LIRIS-CNRS), both in Lyon, France. His research interests include interoperability, Web services, and ontologies. Benslimane has a PhD in computer sciences from Blaise Pascal University. Michael Mrissa is a Ph.D. candidate in computer sciences at Claude Bernard Lyon 1 University and a member of the Laboratoire d'InfoRmatique en Images et Systèmes d'information - Centre National De la Recherche Scientifique (LIRIS-CNRS), both in Lyon, France. His research interests include semantic Web services, interoperability and peer-to-peer networks. Chirine Ghedira is an associate professor in computer sciences at Claude Bernard Lyon 1 University and a member of the Laboratoire d'InfoRmatique en Images et Systèmes d'information- Centre National De la Recherche Scientifique (LIRIS-CNRS), both in Lyon, France. Her research interests include Web services and context-aware computing. Ghedira has a PhD in computer sciences from the National Institute for Applied Sciences (INSA).     

Improvement of thermal conductivity and dielectric constant of graphene-filled epoxy nanocomposites using colloidal polymerization approach

Polymer Bulletin - The effect of the polymeric cross-link density on the thermal conductivity of an oxidized graphene (OG)-filled epoxy nanocomposite was investigated by two different fabrication...     

Robust Nonlinear H ∞ State Feedback Control of Polynomial Discrete-Time Systems: An Integrator Approach

This paper investigates the problem of designing a nonlinear H _∞ state feedback controller for polynomial discrete-time systems with norm-bounded uncertainties. In general, the problem of designing a controller for polynomial discrete-time systems is difficult, because it is a nonconvex problem. More precisely, in general, its Lyapunov function and control input are not jointly convex. Hence, it cannot be solved by semidefinite programming. In this paper, a novel approach is proposed, where an integrator is incorporated into the controller structure. In doing so, a convex formulation of the controller design problem can be rendered in a less conservative way than the available approaches. Furthermore, we establish the interconnection between robust H _∞ control of polynomial discrete-time systems with norm-bounded uncertainties and H _∞ control of scaled polynomial discrete-time systems. This establishment allows us to convert the robust H _∞ control problems to H _∞ control problems. Then, based on the sum of squares (SOS) approach, sufficient conditions for the existence of a nonlinear H _∞ state feedback controller are given in terms of solvability of polynomial matrix inequalities (PMIs), which can be solved by the recently developed SOS solvers. A tunnel diode circuit is used to demonstrate the validity of this integrator approach.