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81.
82.
The chemical looping gasification (CLG) process utilizes an iron-based oxygen carrier to convert carbonaceous fuels into hydrogen and electricity while capturing CO2. Although the process has the potential to be efficient and environmentally friendly, the activity of the iron-based oxygen carrier is relatively low, especially for solid fuel conversion. In the present study, we propose to incorporate a secondary oxygen carrying metal oxide, i.e. CuO, to the iron-based oxygen carrier. Using the “oxygen-uncoupling” characteristics of CuO, gaseous oxygen is released at a high temperature to promote the conversion of both Fe2O3 and coal. Experiments carried out using a Thermal-Gravimetric Analyzer (TGA) indicate that a bimetallic oxygen carrier consisting of a small amount (5% by weight) of CuO is more effective for coal char conversion when compared to oxygen carrier without copper addition. ASPEN Plus® simulations and mathematical modeling of the process indicate that the incorporation of a small amount of copper leads to increased hydrogen yield and process efficiency.  相似文献   
83.
Global water resources are vulnerable to depletion due to the increasing demand of an ever-increasing human population. A country’s water footprint is a measure of the total volume of water needed to produce the goods and services consumed by the country, including water originating beyond its own borders. The water footprint can be a critical indicator of global water resource use, but its practical application is hindered by a lack of comparable data across national boundaries. The purpose of this article is to test the applicability of the nighttime imagery products produced by the Defense Meteorological Satellite Program’s Operational Linescan System (DMSP-OLS) for the assessment of the global water footprint. To accomplish this purpose, the average areal extent of nighttime lighting (lit area) is calculated from 1997 to 2001. Next, lit area is regressed on the total water footprint for each country, as indicated by the Water Footprint Network (WFN), to estimate that country’s total water footprint using nighttime imagery. Model residuals are analyzed at the national scale to understand the appropriateness of nighttime imagery for assessing water consumption. Results indicate strong positive correlations between lit area and total water footprint (TWF), domestic water withdrawal (DWW), and industrial water consumption (IWC) at the national scale. Overall, the analyses reveal that the rate of agricultural water consumption to total water footprint (AWCR) and population density can affect the precision of estimates when lit area is selected as a proxy to estimate water footprints.  相似文献   
84.
Energy consumption in China is expected to double over the next 20 years. Addressing the enormous scale of China's energy need and attendant increases in greenhouse gas emissions requires dramatic and rapid rollout of renewable energy technologies. Mongolia has some of the world's best renewable energy resources but the scale of its market cannot tap them efficiently. Developing Mongolia into a significant exporter of renewable energy to China will create synergies of scale moving both countries towards their energy goals, creating jobs, and fostering growth while significantly reducing GHG emissions in the region.  相似文献   
85.
Anaerobic digestion is a well established technology for the reduction of organic matter and stabilization of wastewater. Biogas, a mixture of methane and carbon dioxide, is produced as a useful by-product of the process. Current solid waste management at the city of Prince George is focused on disposal of waste and not on energy recovery. Co-digestion of fresh fruit and vegetable waste with sewer sludge can improve biogas yield by increasing the load of biodegradable material. A six week full-scale project co-digesting almost 15,000 kg of supermarket waste was completed. Average daily biogas production was found to be significantly higher than in previous years. Digester operation remained stable over the course of the study as indicated by the consistently low volatile acids-to-alkalinity ratio. Undigested organic material was visible in centrifuged sludge suggesting that the waste should have been added to the primary digester to prevent short circuiting and to increase the hydraulic retention time of the freshly added waste.  相似文献   
86.
The Soil and Water Assessment Tool (SWAT), a physically-based watershed-scale model, holds promise as a means to predict tributary sediment and nutrient loads to the Laurentian Great Lakes. In the present study, model performance is compared across six watersheds draining into Lake Erie to determine the applicability of SWAT to watersheds of differing characteristics. After initial model parameterization, the Huron, Raisin, Maumee, Sandusky, Cuyahoga, and Grand SWAT models were calibrated (1998-2001) and confirmed, or validated (2002-2005), individually for stream water discharge, sediment loads, and nutrient loads (total P, soluble reactive P, total N, and nitrate) based on available datasets. SWAT effectively predicted hydrology and sediments across a range of watershed characteristics. SWAT estimation of nutrient loads was weaker although still satisfactory at least two-thirds of the time across all nutrient parameters and watersheds. SWAT model performance was most satisfactory in agricultural and forested watersheds, and was less so in urbanized settings. Model performance was influenced by the availability of observational data with high sampling frequency and long duration for calibration and confirmation evaluation. In some instances, it appeared that parameter adjustments that improved calibration of hydrology negatively affected subsequent sediment and nutrient calibration, suggesting trade-offs in calibrating for hydrologic vs. water quality model performance. Despite these considerations, SWAT accurately predicted average stream discharge, sediment loads, and nutrient loads for the Raisin, Maumee, Sandusky, and Grand watersheds such that future use of these SWAT models for various scenario testing is reasonable and warranted.  相似文献   
87.
The effect of heat‐moisture treatment (HMT) on the properties of pinhão starches under different moisture and heat conditions was investigated. The starches were adjusted to 15, 20 and 25% moisture levels and heated to 100, 110 and 120°C for 1 h. The X‐ray diffractograms, swelling power, solubility, gel hardness, pasting properties and thermal properties of the native and HMT pinhão starches were evaluated. Compared to native starch, there was an increase in the X‐ray intensity and gel hardness of HMT starches, with the exception of the 25% moisture‐treated and 120°C heat‐treated starch. HMT reduced the swelling power and solubility of the pinhão starches when compared to native starch. There was an increase in the pasting temperature, final viscosity and setback and a decrease in the peak viscosity and breakdown of HMT pinhão starches compared to native starch. HMT increases the gelatinisation temperature of native pinhão starch and reduces gelatinisation enthalpy.  相似文献   
88.
89.
Restoration programmes for degraded aquatic ecosystems frequently focus on flow restoration or reinstatement, including recovery targets for volumes of water to be used for environmental benefit. Australia's Murray–Darling Basin is an example of a major system undergoing substantial water reform to balance the needs of competing users, including the environment, within the constraints of an arid climate. This reform revolves around accounting for finite volumes of water that have been shared amongst water users. We argue that while recovering water will provide good outcomes, as a sole intervention, it is not enough to deliver the desired environmental benefits of the reform given the significantly altered state of the catchment. Here, we present 10 measures that could be used to complement planned water recovery actions. These “complementary measures” integrate recovery actions, which when strategically combined with water delivery would significantly enhance water reform efforts to generate environmental outcomes in a highly modified system.  相似文献   
90.
Anthropogenic influences, including climate change, are increasing river temperatures in northern and temperate regions and threatening the thermal habitats of native salmonids. When river temperatures exceed the tolerance levels of brook trout and Atlantic salmon, individuals exhibit behavioural thermoregulation by seeking out cold‐water refugia – often created by tributaries and groundwater discharge. Thermal infrared (TIR) imagery was used to map cold‐water anomalies along a 53 km reach of the Cains River, New Brunswick. Trout and salmon parr did not use all identified thermal anomalies as refugia during higher river temperature periods (>21°C). Most small‐bodied trout (8–30 cm) were observed in 80% of the thermal anomalies sampled. Large‐bodied trout (>35 cm) required a more specific set of physical habitat conditions for suitable refugia, that is, 100% of observed large trout used 30% of the anomalies sampled and required water depths >65 cm within or adjacent to the anomaly. Densities of trout were significantly higher within anomalies compared with areas of ambient river temperature. Salmon parr were less aligned with thermal anomalies at the observed temperatures, that is, 59% were found in 65% of the sampled anomalies; and densities were not significantly different within/ outside anomalies. Salmon parr appeared to aggregate at 27°C, and after several events over 27°C variability in aggregation behaviour was observed – some fish aggregated at 25°C, others did not. We stipulate this is due to variances of thermal fatigue. Habitat suitability curves were developed for velocity, temperature, depth, substrate, and deep water availability to characterize conditions preferred by fish during high‐temperature events. These findings are useful for managers as our climate warms, and can potentially be used as a tool to help conserve and enhance thermal refugia for brook trout and Atlantic salmon in similar systems.  相似文献   
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