Propane ammoxidation on bulk, diluted and supported VSb oxides

VSb oxides diluted with Mg, Al and Zr displayed substantially higher selectivity for propane ammoxidation to acrylonitrile than their bulk and supported analogues. Diluted catalysts were found to consist of oxide compounds of antimony with diluent element, such as AlSbO₄ or MgSb₂O₆, and small amounts of individual oxides of antimony and diluent element. No VSbO₄ phase was detected in their body in contrast with bulk and supported catalysts. It appears that better isolation of vanadium and antimony entities in the structure of diluted oxides was responsible for their enhanced catalytic behavior. Tungsten loaded to the surface of diluted catalysts further improved their selectivity through tuning the surface acidity.     

Low cycle fatigue of as-HIP and HIP+forged rené 95

The continuous cycling and hold time low cycle fatigue properties of the Ni base superalloy René 95 were studied at 649°C using powder products (−60 mesh) in the as-HIP and HIP + forged conditions. It was shown that cracks were initiated by pores, by ceramic particles and by a classical stage I mechanism for both materials and for both cycle characters. For the continuously cycled as-HIP material, deformation was restricted to well defined bands at low strains and became homogeneous as the strain level increased. The total energy to fracture increased abruptly in the low strain regime and this was also reflected by a break in the Coffin-Manson plot. In all cases cracks initiated at pores. The hold time specimens exhibited an extremely high dislocation density and surface connected initiation yet without a significant life reduction. The observations were essentially similar for the HIP + forged material except that deformation tended to be confined to well defined slip bands even at high strains and to some extent even for the hold time tests. This behavior was attributed to the fact that theγ′ were smaller, more coherent and more readily sheared by dislocations which were strongly paired. There was a marked tendency for crack propagation to change from transgranular to intergranular (also observed for the as-HIP material) at a unique combination of crack length and plastic strain. The transition occurred at shorter crack lengths for the HIP + forged material except when crack initiation was subsurface. In this case the transition was delayed and the life was greatly enhanced, indicating that the environment plays a major role in determining the fatigue life. PHILIPPE TAUPIN formerly Research Associate, Department of Materials Science, University of Cincinnati.     

Experimental and numerical characterization of mechanical properties of carbon/jute fabric reinforced epoxy hybrid composites

Journal of Mechanical Science and Technology - Natural fiber composites have great potential for reducing the product cost, lowering weight and enhancing renewability. Functionality and performance...     

Morphological and palynological assessment of taxonomically problematic genus Paspalum based on light and scanning electron microscopy

Present research work was carried out to clarify the variations among species of genus Paspalum morphologically and palynologically as this genus is taxonomically difficult due to having multiple similar morphologically overlapping characters which make it difficult to identify. Henceforth present research work was carried out to delimit taxa within the same genus by morphological and palynological tools through light microscopy (LM) and scanning electron microscopy (SEM). Both these tools are considered as the most useful taxonomic characters for taxonomically problematic genera. The results showed a lot of variations among morphological characters. In Paspalum dilatatum, the upper glume was ovate whereas in the other two species, the upper glume was elliptic. The upper glume apex found in P. dilatatum and Paspalum scrobiculatum was obtuse whereas in Paspalum distichum, upper glume apex was acute. Glume nerves showed variation in all three species. Paspalum distichum was 3 nerved, P. scrobiculatum was 5–7 nerved, and P. dilatatum was 5–9 nerved. All three species showed variation in lemma nerves. Paspalum scrobiculatum had 3 nerved lemma whereas in P. distichum 3–5 nerved and P. dilatatum 5–9 nerved lemma were present. In polar and equatorial view, pollen grains ranged from 25 (20–30) to 37.5 (30–45) μm. Paspalum distichum appeared to be the smallest in size whereas P. dilatatum was the largest. Exine thickness ranged from 0.75 (0.5–1) to 1.35 (1.2–1.5) μm. The higher value of pollen fertility was found in P. scrobiculatum as 87.69% and the lowest value was in P. distichum as 78.08%. Morphological keys were also given for correct identification.     

Comparison of Bougainvillea spectabilis and Bougainvillea glabra species inhibited in Pakistan based on microscopic studies: Light microscope and scanning electron microscope

The anatomical variations of two plants from the Nyctaginaceae family, Bougainvillea spectabilis and Bougainvillea glabra, were studied using light and scanning electron microscopy methods in this work. Bougainvillea is a dicotyledonous with defensive traits that can withstand extreme (hot and dry) settings; according to the findings, crystal inclusions in cells, woody spines, and an abnormal development pattern are all features that help them survive against predators and are unique to this species. The Bougainvillea plant's leaves are arranged in simple pattern, alternate to each other along stem having an undulate leaves edge and an oval form. The xylem and phloem, palisade, parenchyma midrib, spongy mesophyll, raphide crystal bundles, and trichomes were all visible when bracts and leaves were transversally sectioned and dyed with toluidine blue O (TBO). The presence of crystals was confirmed by a detailed examination of the transverse leaves by using bright-field and cross-polarizing microscopy. Dissecting microscopic examination showed that all the leaves revealed leaves venation pattern that had midvein, lateral veins areoles, and trichomes. Although trichomes have been identified on both sides, a closer look at a cleaned leaf dyed with TBO showed multicellular abundant trichomes on adaxial surface. Stomata complexes were typically found on the abaxial surface of the leaf according to epidermal peels. Present studies also showed that on adaxial side, stomata were lesser in number or were absent and also showed that the morphologies of the pavement cells on the adaxial and abaxial sides of the leaf differed.     

基于制造资源能力的装夹工艺分层设计技术

为发展创成式的计算机辅助工艺设计,研究了计算机辅助工艺设计系统中工件装夹规划的自动生成算法.基于扩展有向图,建立了零件的公差信息和基准-加工特征关系的数学表示模型,基于公差分析和制造资源能力模型,建立了从单件层到多件层的工件装夹工艺生产算法.该数学模型和算法可自动识别工件的加工特征、装夹基准,并根据制造资源能力和公差分析对装夹进行优化分组,实现装夹分组对工件加工精度的影响最小化,进而生成装夹规程.最后以实例证明了该方法的可行性.     

Engineering characteristics of a glacio-lacustrine clay deposit in a semi-arid climate

Parent material composition, particle disintegration by glaciers and lacustrine environment govern the geological development and engineering characteristics of clay deposits in southern Saskatchewan. The pre-existing expansive clay minerals were preserved due to the restrained leaching in the Regina Lake and the prevalent aridity in the area. The main objective of this paper was to develop a fundamental understanding of the clay deposit for the use in the design and construction of civil infrastructure. The results indicated the presence of expansive clay minerals in the deposit, with smectite accounting for 35% of the material. The major exchangeable cation was found to be Ca²⁺ which accounted for more than half of the total measured cation exchange capacity of 40 (cmol(+)/kg). The most likely exchange complex governing water adsorption of the clay was determined to be Ca²⁺-smectite. Alongside a high initial saturation (86%), this complex resulted in moderate volume changes in the clay. The swelling pressure was fully developed within the first hour of the constant volume test. The corrected swelling pressure was determined to be 120 kPa leading to an estimated heave of 36 mm in the surface layer of the deposit. The compression index and the swelling index were found to be 0.25 and 0.08, respectively.