Proton Conductivity of SPEEK Membranes

Novel sulfonated poly(ether ether ketone) (PEEK) copolymers were prepared using a low-viscosity grade PEEK powder. The TGA studies indicated that SPEEK membranes with up to 75% DS have enough thermal stability. The highest conductivity of 2.176 × 10^?2 S cm^?1 has been observed at 100°C for SP96 (DS = 72%). Compared to Nafion-15, SP72 exhibits much higher conductivity at all the temperatures considered. The water sorption experiments indicated that the maximum water uptake was 3.92% for SP24 and it was 60% for SP120. It was observed that the increase in the water content in a membrane caused a decrease in the diffusion coefficient.     

Effect of Iron Ore Pellet Size on its Properties and Microstructure

The properties of the pellets and their microstructure mainly depend on the raw material mix proportion, raw material chemical composition and the physicochemical conditions like the temperature and oxygen partial pressure within the induration machine. The pelletising plant products are in the size range of 8 to 16 mm. With increasing pellet size, the sintering intensity, thermo‐chemical conditions and formation of different phases vary across its cross section. The time required for varies reactions within the pellet is directly proportional to the pellet size. Because of differences in pellet size, the reduction and oxidation process takes place under different conditions resulting in different phases and microstructures. In this work, detailed studies were carried out on pellets of different size (8 to 16 mm) produced from a 4.2 Mtpa pellet plant for their physical, metallurgical and microstructural properties. It was observed that the pellets in the size range of +8 to ‐12 mm showed good strength and lower RDI. It was observed that the amount of hematite, magnetite, porosity, pore density, pore size and slag phase play a significant role on pellet strength and RDI.     

Hydraulic Conductivity of MSW in Landfills

This paper presents a laboratory investigation of hydraulic conductivity of municipal solid waste (MSW) in landfills and provides a comparative assessment of measured hydraulic conductivity values with those reported in the literature based on laboratory and field studies. A series of laboratory tests was conducted using shredded fresh and landfilled MSW from the Orchard Hills landfill (Illinois, United States) using two different small-scale and large-scale rigid-wall permeameters and a small-scale triaxial permeameter. Fresh waste was collected from the working phase, while the landfilled waste was exhumed from a borehole in a landfill cell subjected to leachate recirculation for approximately 1.5 years. The hydraulic conductivity tests conducted on fresh MSW using small-scale rigid-wall permeameter resulted in a range of hydraulic conductivity 2.8×10?3–11.8×10?3?cm/s with dry unit weight varied in a narrow range between 3.9–5.1?kN/m3. The landfilled MSW tested using the same permeameter produced results between 0.6×10?3–3.0×10?3?cm/s for 4.5–5.5?kN/m3 dry unit weights. The hydraulic conductivity obtained from large-scale rigid-wall permeameter tests decreased with the increase in normal stress for both fresh and landfilled waste. The hydraulic conductivity for fresh MSW ranged from 0.2 cm/s for 4.1?kN/m3 dry unit weight (under zero vertical stress) and then decreased to 4.9×10?5?cm/s for 13.3?kN/m3 dry unit weight (under the maximum applied normal stress of 276 kPa). The hydraulic conductivity of the landfilled MSW decreased from 0.2 cm/s to 7.8×10?5?cm/s when the dry unit weight increased from 3.2 to 9.6?kN/m3. The results clearly demonstrated that the hydraulic conductivity of MSW can be significantly influenced by vertical stress and it is mainly attributed to the increase in density leading to low void ratio. In small-scale triaxial permeameter, when the confining pressure was increased from 69 to 276 kPa the hydraulic conductivity decreased from approximately 10?4?to?10?6?cm/s, which is much lower than those determined from rigid-wall permeameter tests. The published field MSW hydraulic conductivities are found to be higher than the laboratory results. Landfilled MSW possesses lower hydraulic conductivity than fresh MSW due to increased finer particles resulting from degradation. The decreasing hydraulic conductivity with increasing dry unit weight is expressed by an exponential decay function.     

A series of novel double perovskite oxides NaMTi<Subscript>2</Subscript>O<Subscript>6</Subscript> (M = Eu,Sm, and Gd): preparation,characterization and photocatalytic studies under visible and solarlight irradiation

The photocatalytic activity of sol–gel synthesized double perovskite type oxides NaEuTi₂O₆(NETO), NaSmTi₂O₆ (NSTO), and NaGdTi₂O₆ (NGTO) powders on degradation of methylene blue (MB) dye was demonstrated for the first time under visible light as well as sunlight irradiation. The obtained samples were characterized by X-ray diffraction, UV–Visible diffuse reflectance spectroscopy and scanning electron microscopy equipped with X-ray energy-dispersion spectrometry. All the three samples have shown photocatalytic activity for degradation of MB under sunlight and visible light irradiation and their photocatalytic activity followed the order of NGTO > NETO > NSTO. The superior activity of NGTO is ascribed to the higher amount of hydroxyl radicals generated in the photocatalytic reaction.     

Geometric Representation of Graphs in Low Dimension Using Axis Parallel Boxes

An axis-parallel k-dimensional box is a Cartesian product R ₁×R ₂×???×R _k where R _i (for 1≤i≤k) is a closed interval of the form [a _i ,b _i ] on the real line. For a graph G, its boxicity box?(G) is the minimum dimension k, such that G is representable as the intersection graph of (axis-parallel) boxes in k-dimensional space. The concept of boxicity finds applications in various areas such as ecology, operations research etc. A number of NP-hard problems are either polynomial time solvable or have much better approximation ratio on low boxicity graphs. For example, the max-clique problem is polynomial time solvable on bounded boxicity graphs and the maximum independent set problem for boxicity d graphs, given a box representation, has a $\lfloor 1+\frac{1}{c}\log n\rfloor^{d-1}An axis-parallel k-dimensional box is a Cartesian product R ₁×R ₂×⋅⋅⋅×R _k where R _i (for 1≤i≤k) is a closed interval of the form [a _i ,b _i ] on the real line. For a graph G, its boxicity box (G) is the minimum dimension k, such that G is representable as the intersection graph of (axis-parallel) boxes in k-dimensional space. The concept of boxicity finds applications in various areas such as ecology, operations research etc. A number of NP-hard problems are either polynomial time solvable or have much better approximation ratio on low boxicity graphs. For example, the max-clique problem is polynomial time solvable on bounded boxicity graphs and the maximum independent set problem for boxicity d graphs, given a box representation, has a ?1+\frac1clogn?^d-1\lfloor 1+\frac{1}{c}\log n\rfloor^{d-1} approximation ratio for any constant c≥1 when d≥2. In most cases, the first step usually is computing a low dimensional box representation of the given graph. Deciding whether the boxicity of a graph is at most 2 itself is NP-hard.     

A two stage neural network for choosing optimal ejection parameters in low altitude seat ejection based on novel injury parameter

Optimization and Engineering - Aircraft ejection systems are lifesaving devices used, in case of emergencies for military pilots. As per current literature the success rate of ejections happening...     

Optimization of sensitizer concentration for upconversion photoluminescence of Yb3+/Er3+: La10W22O81 nanophosphor rods

Yb³⁺/Er³⁺codoped La₁₀W₂₂O₈₁ (LWO) nanophosphor rods have been successfully synthesized by a facile hydrothermal assisted solid state reaction method, and their upconversion photoluminescence properties were systematically studied. X-ray diffraction patterns revealed that the nanophosphors have an orthorhombic structure with space group Pbcn (60). A microflowers-like morphology with irregular hexagonal nanorods was observed using field emission scanning electron microscopy for the Yb³⁺(2 mol%)/Er³⁺(2 mol%):LWO nanophosphor. The shape and size of the nanophosphor and the elements along with their ionic states in the material were confirmed by TEM and XPS studies, respectively. A green upconversion emission was observed in the Er³⁺: LWO nanophosphors under 980 nm laser excitation. A significant improvement in upconversion emission has been observed in the Er³⁺: LWO nanophosphors by increasing the Er³⁺ ion concentration. A decrease in the upconversion emission occurred due to concentration quenching when the doping concentration of Er³⁺ ions was greater than 2 mol%. An optimized Er³⁺(2 mol%): LWO nanophosphor exhibited a strong near infrared emission at 1.53 μm by 980 nm excitation. The green upconversion emission of Er³⁺(2 mol%): LWO was remarkably enhanced by co-doping with Yb³⁺ ions under 980 nm excitation because of energy transfer from Yb³⁺ to Er³⁺. The naked eye observed this upconversion emission when co-doping with 2 mol% Yb³⁺. In order to obtain the high upconversion green emission, the optimized sensitizer concentration of Yb³⁺ ions was found to be 2 mol%. The upconversion emission trends were studied as a function of stimulating laser power for an optimized sample. Moreover, the NIR emission intensity has also been enhanced by co-doping with Yb³⁺ ions due to energy transfer from Yb³⁺ to Er³⁺. The energy transfer dynamics were systematically elucidated by energy level scheme. Colorimetric coordinates were determined for Er³⁺ and Yb³⁺/Er³⁺: LWO nanophosphors. The energy transfer mechanism was well explained and substantiated by several fluorescence dynamics of upconversion emission spectra and CIE coordinates. The results demonstrated that the co-doped Yb³⁺(2 mol%)/Er³⁺(2 mol%): LWO nanophosphor material is found to be a suitable candidate for the novel upconversion photonic devices.     

Storage and permeation of hydrogen molecule,atom and ions (H+ and H−) through silicon carbide nanotube; a DFT approach

The barriers for the encapsulation and decapsulation of hydrogen ions (cationic hydrogen and hydride), atom, and molecule through silicon carbide nanotube are thoroughly studied. DFT method is selected to measure the kinetic barriers for the passage of hydrogen atom, ions and molecule through nanotube via scanning potential energy surface. The kinetic barriers for the passage (encapsulation and decapsulation) of hydrogen are very important to understand the mechanism of hydrogen storage and release. The barriers for the permeation of H, H⁺ and H^? across SiC nanosheet are lower compared to hydrogen molecule (H₂). The exohedral and endohedral adsorption of hydrogen ions (cation and anion), atom and exohedral hydrogen molecule on silicon carbide are exothermic in nature. Whereas the encapsulation of hydrogen molecule in silicon carbide is endothermic. Electronic properties are analyzed through measurement of energy gap between highest occupied and lowest unoccupied molecular orbitals gap (G_H-L) and the density of state (DOS) spectra. The G_H-L analysis reveals that endohedral complexes have more pronounced effect on electronic properties compared to exohedral complexes. The SiC nanotube has highly favorable properties for storage and release of hydrogen ions, and atom.