Algebraic structures of soft sets associated with new operations

Recently new operations have been defined for soft sets. In this paper, we study some important properties associated with these new operations. A collection of all soft sets with respect to new operations give rise to four idempotent monoids. Then with the help of these monoids we can study semiring (hemiring) structures of soft sets. Some of these semirings (hemirings) are actually lattices. Finally, we show that soft sets with a fixed set of parameters are MV algebras and BCK algebras.     

Structure and Mechanical Properties of Nanocomposites Based on an Amorphous Copolyester

Nanocomposites based on an amorphous copolyester (PCTG) were obtained by melt mixing, changing the screw speed and the nature of the surfactant, which differed in polarity and molecular volume. Using Young's modulus as a measure of the dispersion level, a less‐polar nature and a higher molecular volume of the surfactant appeared as positive structural factors for dispersion of the clay in the less‐polar PCTG. The Cloisite 20A, which led to the highest modulus (widest dispersion), was mixed at different contents with PCTG at the observed optimum screw speed (200 rpm). Intercalated structures were observed by WAXD and TEM. The dispersion was wide, as observed by TEM, and led to a large (77%) modulus increase after 7% organoclay addition and to important increases in both tensile yield stress and dimensional stability in creep.

     

Particle tracking velocimetry investigations on density dependent velocity vector profiles of a swirling fluidized bed

Swirling fluidized bed (SFB) is a newer version of the well-known bubbling bed and very little know. An insight study is therefore required for complete understanding of the hydrodynamics of a SFB operation. The current study was conducted on stable regime of a SFB operated at different blade fin angles, blade inclination angles, particle densities and superficial air velocities. Roughly one quarter of the fluidized bed was photographed and its velocity vector field plots were generated using a MATLAB supported particle tracking velocimetry (PTV) technique. At lower superficial velocities, Gaussian distribution of the velocity vectors was predicted along the radius of the bed. Particles in the vicinity of the bed walls moved relatively slower than those marching in the middle of the bed. However, at higher superficial velocities, the particles closer to the cone boundary were moving with velocities comparable to the particles in the middle of the bed. Unlikely, the particles closer to the outer bed wall kept on moving with lower velocities regardless of increasing superficial air velocity. A further look into individual velocity vector profiles revealed negligible influence of smaller blade angles (9° and 12°) on particles’ motion. The overall velocity magnitude decreased by 6% with 3° increase in blade fin angle and by 9% with 5° increase in inclination angle. Contrarily, the particle velocity underwent a monotonic decrease with particle density.     

Chemical Grafting of Crosslinked Polypyrrole and Poly(vinyl Chloride) onto Modified Graphite: Fabrication,Characterization, and Material Properties

ABSTRACT

Conjugated polymer/graphite nanocomposites have been known as high performance materials owing to improve the physicochemical properties relative to conventional once. Multilayered polymer nanocomposites based on polypyrrole (PPy), polyvinylchloride (PVC) as matrices and p-phenylene diamine (PDA) as linker were prepared via chemical in situ polymerization process and subsequently investigated the physical characteristics of fabricated nanocomposites at various loadings. The structural characterization and morphology of prepared nanocomposites were inspected by Fourier transform infrared spectroscopy (FTIR), X-ray photon spectroscopy (XPS), energy dispersive X-ray spectroscope (EDX), field emission scanning electron microscope (FESEM), respectively. The composite III showed higher thermal stability at 10 wt% loading of PPy. According to differential scanning calorimetry (DSC), the glass transition temperature (T_g), melting temperature T_m, and crystallization temperature (T_c) of nanocomposites increases with PPy loading (2–10 wt%) owing to crosslinking and chain rigidity. Moreover, higher surface area was displayed by the multilayered PPy/PVC/PDA@FG nanocomposites. Remarkably, electrical conductivity of ultimate nanocomposites was also found to be a function of PPy loading.     

Synthesis of four-component acrylic-modified water-reducible alkyd resin: investigation of dilution ratio effect on film properties and thermal behaviors

This study investigated the effect of the dilution ratio on film properties of acrylic-modified water-reducible alkyd resins. First, new four-component acrylic-modified alkyd resins based on 1,3-propanediol containing 40% of the equivalent amount of acrylic copolymer to alkyd resin were synthesized using the fatty acid method. The synthesized acrylic-modified alkyd resin was then dissolved in isopropyl alcohol (IPA) at various ratios and further diluted using distilled water at various ratios to obtain by-weight percentages of 70/50, 70/60, and 80/60 of solid content to IPA and water, respectively. Films of the modified alkyd resins were prepared, and cured at 150°C for 1 h, then their physical and chemical surface coating properties and thermal behaviors were investigated. The best results were obtained for the by-weight percentages of 80/60.     

Stable and reproducible synthesis of gold nanorods for biomedical applications: a comprehensive study

Gold nanorods (GNRs) are ideal choice in biomedical research due to their amenability of synthesis, tunable plasmonic properties, less toxicity and ease of detection but their diverse biological applications necessitate stable structure. Despite two decades'' efforts made towards reproducible anisotropic structures synthesis, still the kinetic control during GNRs growth has not been achieved. This study is an attempt to apprehend thermodynamic and kinetic parameters for synthesising mono‐disperse, reproducible and highly stable GNRs with desired aspect ratios. Effects of various growth parameters and assay steps on the facile and reproducible synthesis of GNRs are analysed. GNRs'' environmental and biological colloidal stability is studied through UV–Vis spectroscopy based particle instability parameter (PIP < 0.1). The authors hereby report GNRs with tunable longitudinal surface plasmon resonance (682–906 nm) having different aspect ratios (2.5–4.6) that are stable at 28–60°C; however, prolonged high temperature ( > 60°C) and alkaline pH can trigger colloidal instability. GNRs remain stable at higher salt concentration, physiological and slightly acidic pH. GNRs can be stored in 0.001 M cetyltrimethylammonium bromide for 3 months without compromising their stability. PEGylated GNRs are quite stable in cellular media solution (PIP < 0.1). With current optimised growth conditions, no aggregation at physiological pH and stability at high temperatures make GNRs an ideal candidate in biomedical applications.Inspec keywords: gold, nanorods, nanofabrication, nanomedicine, toxicology, thermodynamics, ultraviolet spectra, visible spectra, surface plasmon resonance, pH, cellular biophysicsOther keywords: nanorod synthesis, biomedical applications, tunable plasmonic properties, toxicity, reproducible anisotropic structures synthesis, thermodynamic parameters, kinetic parameters, GNR, biological colloidal stability, UV‐Vis spectroscopy, particle instability parameter, tunable longitudinal surface plasmon resonance, aspect ratios, alkaline pH, physiological pH, slightly acidic pH, cetyltrimethylammonium bromide, cellular media solution, optimised growth conditions, aggregation, wavelength 682 nm to 906 nm, time 3 month, Au     

Study of charge injection in insulators submitted to divergingfields

Various theoretical models have been proposed to explain the behavior of insulator-electrode interfaces in the case of strongly divergent electric fields. However until recently a direct measurement of the charge transferred at these interfaces could not be performed and very indirect ways had to be used. In this paper we propose a structure which allows for direct measurements of this charge using the PWP (pressure wave propagation) method. We present evidence of charge transferred around small diameter wires, embedded in an insulator, submitted to an applied voltage     

Robust ISS of uncertain discrete-time singularly perturbed systems with disturbances

This paper is concerned with robustly input-to-state stable (ISS) and Robust ISS by feedback of uncertain discrete-time singularly perturbed systems (SPSs) with disturbances. Meanwhile, robust stability and stabilisation of uncertain discrete-time SPSs are also obtained as the particular cases of robust ISS and robust ISS by feedback. We first find a sufficient condition by using the fixed-point principle in terms of linear matrix inequalities (LMIs) to guarantee that the considered system is always standard discrete-time SPSs subject to uncertainty and disturbances. Then, the full systems could decompose into the continuous-time uncertain slow subsystem with disturbance and discrete-time uncertain fast subsystems with disturbance, respectively. Based on the two-time-scale decomposition technique, sufficient condition in terms of LMIs is given such that the full systems are uniformly standard and robust ISS simultaneously. In addition, a state feedback controller is constructed by using the LMI approach such that the resulting closed-loop systems are robust ISS. Finally, a numerical example is provided to illustrate the effectiveness of the proposed approach.     

Biometric signature authentication using machine learning techniques: Current trends,challenges and opportunities

Multimedia Tools and Applications - Biometric systems are playing a key role in the multitude of applications and placed at the center of debate in the scientific research community. Among the...