Study on the electrical conductivity and morphology of porous polypyrrole layers prepared electrochemically in the presence of pyridinium chlorochromate

The electrical conductivity and morphology of thick (up to 3 mm) porous polypyrrole (PPy) layers produced electrochemically from pyrrole in acetonitrile (ACN) solutions have been studied. The electrical conductivity of pressed porous layers ranges from 1 to 10 Scm^–1, which is about one order of magnitude less than that in films which were prepared under similar conditions but without PnClCr. Analysis of the temperature dependence of conductivity has confirmed the major role of hopping in relation to tunnelling in charge transport inside the PPy layers even at lower temperatures. Scanning electron microscopy (SEM) showed a globular structure, which is different from the usual cauliflower-like structure of PPy films prepared without any oxidizing agent. Globular particles of about 1–3 m diameter have been found under a thin smooth crust on the electrode side of the sample. Globular particles form linked chain-like or larger round formations poorly filling the space. Closely packed fibrils of about 20 nm diameter and over 100 nm in length were found inside the aggregates.     

Color effects of uniform colloidal particles of different morphologies packed into films

The experimentally determined chromaticities and reflectance spectra of films consisting of uniform ellipsoidal or spherical colloidal hematite particles are compared with calculated values and are found to be in good agreement. The theoretical treatment of the light-scattering problem involves the Mie theory for the spheres and the T-matrix method for the ellipsoids. The reflectance spectra for the pigment films are calculated through the use of the Kubelka-Munk analysis.     

Algorithm for the determination of intrinsic optical constants of metal films: application to aluminum

Optical and electron-energy-loss data for evaporated-aluminum films have been critically analyzed and used in an iterative, self-consistent algorithm that represents a combination of the Kramers-Kronig analysis and the semiquantum-model application. The novel values of the intrinsic optical functions of aluminum have been determined in a wide spectral range from 200 μm (6.2 meV) to 0.12 nm (10 keV). These functions are in accordance with recent calculations by Lee and Chang [Phys. Rev. B 49, 2362 (1994)], with dc conductivity measurements, and are in good agreement with both peak positions and line widths obtained from electron-energy-loss experiments. The results are examined for internal consistency by inertial and f-sum rules.     

The influence of adding pitch to resin as a matrix precursor on properties of carbon-carbon composites

Carbon-carbon composites were prepared with commercially available carbonized and graphitized fibres, with a mixture of pitch and phenolic resin as a binder and pitch as an impregnant. The contents of pitch in mixtures were: 0, 10, 20 and 30 wt %. The influence of pitch content in the mixture and fibre type on mass loss, shrinkage and mechanical properties of the composites was examined. With an increase of pitch content mass loss and shrinkage increased, while mechanical properties decreased. After three densification cycles, flexural strength increased with increasing pitch content in the binder, especially for composites with graphitized fibres.     

A variable-precision square root implementation for field programmable gate arrays

Applications requiring variable-precision arithmetic often rely on software implementations because custom hardware is either unavailable or too costly to build. By using the flexibility of the Xilinx XC4010 field programmable gate arrays, we present a hardware implementation of square root that is easily tailored to any desired precision. Our design consists of three types of modules: a control logic module, a data path module to extend the precision in 4-bit increments, and an interface module to span multiple chips. Our data path design avoids the common problem of large fan-out delay in the critical path. Cycle time is independent of precision, and operation latency can be independent of interchip communication delays.Notation S_j square root digit of weight 2^–j - S _j {–1, 0, 1} - S[j] computed square root value as of stepj - S _j ^s sign bit in the representation ofS _j in sign and magnitude form - S _j ^m magnitude bit in the representation ofS _j in sign and magnitude form - w[j] residual at stepj in two's complement carry-save representation - a sum vector in the carry-save representation of 2w[j] - b carry vector in the carry-save representation of 2w[j] - a _i bit of weight 2^–i in the sum vector,a - b_i bit of weight 2^–i in the carry vector,b - T[j]=–S[j – 1]s_j – s _j ² 2^–(j+1) T _i bit of weight 2^–i inT     

State of the Art of Molecular Visualization in Immersive Virtual Environments

Visualization plays a crucial role in molecular and structural biology. It has been successfully applied to a variety of tasks, including structural analysis and interactive drug design. While some of the challenges in this area can be overcome with more advanced visualization and interaction techniques, others are challenging primarily due to the limitations of the hardware devices used to interact with the visualized content. Consequently, visualization researchers are increasingly trying to take advantage of new technologies to facilitate the work of domain scientists. Some typical problems associated with classic 2D interfaces, such as regular desktop computers, are a lack of natural spatial understanding and interaction, and a limited field of view. These problems could be solved by immersive virtual environments and corresponding hardware, such as virtual reality head-mounted displays. Thus, researchers are investigating the potential of immersive virtual environments in the field of molecular visualization. There is already a body of work ranging from educational approaches to protein visualization to applications for collaborative drug design. This review focuses on molecular visualization in immersive virtual environments as a whole, aiming to cover this area comprehensively. We divide the existing papers into different groups based on their application areas, and types of tasks performed. Furthermore, we also include a list of available software tools. We conclude the report with a discussion of potential future research on molecular visualization in immersive environments.     

Selective Al-Ti reactivity in laser-processed Al/Ti multilayers

Multilayers consisting of five (Al/Ti) bilayers were deposited on (100) silicon wafers. On top was deposited the Ti layer, aimed at preventing Al from diffusing to the surface upon laser treatment. The total thickness of the thin-film structure was 200?nm. Laser irradiations with Nd:YAG picoseconds laser pulses in the defocused regime were performed in air. Laser beam energy was 4?mJ and laser spot diameter on the sample surface was 3?mm (fluence 0.057?J?cm^?2). The samples were treated with different numbers of laser pulses. Structural characterizations were performed by different analytical methods and nano-hardness was also measured. Laser processing induced layer intermixing, formation of titanium aluminides, oxidation of the surface titanium layer and enhanced surface roughness. Aluminum appears at the sample surface only for the highest density of laser irradiation. Laser processing induces increment of nano-hardness by approximately 20% and decrease of residual Young’s modulus for a few percentages from the starting value of the untreated samples. These results can be interesting toward achieving structures with a selective extent of Al-Ti reactivity in this multilayered system, within the development of biocompatible materials.     

Determination of the Optimal Fourier Number on the Dynamic Thermal Transmission

This article represents the result of experimental research on transient heat transfer in a multilayered (heterogeneous) wall. Our non-steady thermal transmission simulation is based on a finite-difference calculation method. The value of a Fourier number shows the similarity of thermal variation in conditional layers of an enclosure. Most scientists recommend using no more than a value of 0.5 for the Fourier number when performing calculations on dynamic (transient) heat transfer. The value of the Fourier number is determined in order to acquire reliable calculation results with optimal accuracy. To compare the results of simulation with experimental research, a transient heat transfer calculation spreadsheet was created. Our research has shown that a Fourier number of around 0.5 or even 0.32 is not sufficient (\({\approx }17\,\%\) of oscillation amplitude) for calculations of transient heat transfer in a multilayered wall. The least distorted calculation results were obtained when the multilayered enclosure was divided into conditional layers with almost equal Fourier number values and when the value of the Fourier number was around 1/6, i.e., approximately 0.17. Statistical deviation analysis using the Statistical Analysis System was applied to assess the accuracy of the spreadsheet calculation and was developed on the basis of our established methodology. The mean and median absolute error as well as their confidence intervals has been estimated by the two methods with optimal accuracy (\({F}_{\mathrm{oMDF}}= 0.177\) and \(F_{\mathrm{oEPS}}= 0.1633\) values).     

Defining the e-learner’s security profile: Towards awareness improvement

The paper presents an improved e-learner model that supports monitoring of user behavior related to information security. The model is built upon standardized IMS specification, according to literature research and survey conducted among e-learners. It is positioned as key part of an extended LTSA architecture in which the learner data is used to improve learner security position by continuous delivery of important information and adapting security mechanisms. The implementation is considered in Moodle LMS.