Improved modelling of the fuel cell power module within a system-level model for solid-oxide fuel cell cogeneration systems

A generic system-level model for SOFC cogeneration devices has been developed under the umbrella of an International Energy Agency/Energy Conservation in Buildings and Community Systems project known as Annex 42. This paper addresses a limitation of the Annex 42 model by developing a more refined semi-mechanistic treatment for the fuel cell power module (FCPM). The electrochemical, thermal, and reformation modelling methods as well as techniques for treating the FCPM's balance of plant are first described. The methods used to calibrate and validate the enhanced model using previously collected data from a 2.8 kW_AC prototype SOFC cogeneration device are then discussed. Excellent agreement was found between model predictions and the measurements. The new modelling capabilities are then demonstrated through a parametric study that examines the influences of fuel utilization, excess air ratio and stack temperature.     

Multi‐dimensional modeling of solar cells with electromagnetic and carrier transport calculations

We present a multi‐dimensional model for comprehensive simulations of solar cells (SCs), considering both electromagnetic and electronic properties. Typical homojunction and heterojunction gallium arsenide SCs were simulated in different spatial dimensions. When considering one‐dimensional problems, the model performs carrier transport calculations following a Beer–Lambert optical absorption approximation. We show that the results of such simulations exhibit excellent agreement with the standard PC1D one‐dimensional photovoltaic simulation. Photonic and plasmonic attempts to enhance SC efficiency demand comprehensive electromagnetic calculations to be undertaken in order to acquire accurate carrier generation profiles in two and three‐dimensional systems. Our model provides complete spectral and spatial information of typical optical and electronic behavior. Furthermore, our approach permits the detailed investigation of complex systems, including plasmonic SCs, which cannot be simulated using low‐dimensional modeling tools. We present the results of numerical simulations of an optically thin plasmonic gallium arsenide SC and observe improved device performance arising from the application of plasmonic nanostructures, which agree well with previous experimental findings. Copyright © 2012 John Wiley & Sons, Ltd.     

Transient supersonic release of hydrogen from a high pressure vessel: A computational analysis

Understanding the characteristics of a hydrogen gas jet exiting from a compressed vessel during vessel rupture or venting is crucial for determining safety requirements for distribution and use of hydrogen. Such jets can undergo several flow regimes during venting, from initial supersonic flow, to transonic, to subsonic flow regimes as the pressure in the vessel decreases. A bow shock wave is a characteristic flow structure during the initial stage of the jet development, and this paper focuses on the development of the bow shock wave and the jet structure behind it. The transient behaviour of an impulsively initiated jet is investigated using unsteady, compressible flow simulations. Both the cases of a hydrogen jet exiting into quiescent hydrogen and of a hydrogen jet exiting into air are presented. The gases are considered to be ideal, and the computational domain is axisymmetric. The jet structure, including the shock wave and flow separation due to an adverse pressure gradient at the nozzle is investigated with a focus on the differences between the single- and multi-component flow scenarios.     

Thermal-Induced Wear Mechanisms of Sheet Nacre in Dry Friction

Sheet nacre is a natural biocomposite with a multiscale structure including a mineral phase of calcium carbonate (97 wt.%) and two organic matrices (3 wt.%). The mineral phase is constituted by an arrangement of CaCO₃ biocrystal nanograins (ca 40 nm in size) drowned in an “intracrystalline” organic matrix (4 nm thick) in order to form a microsized flat organomineral aragonite platelet. These platelets are themselves surrounded by an “intercrystalline” organic matrix (40 nm thick) building up a very tough materials. This microarchitecture referred to as “bricks and mortar” nacre structure, is mainly studied for the creation of new organic/inorganic hybrid materials. Currently, only little is known about the nacre mechanical behaviour under dynamical loading and more particularly under tribological conditions which involve shocks and thermal effects simultaneously. This paper brings out the thermal-induced damage mechanisms effect on the wear of sheet nacre by the assessment of the thermal component of the friction with a scanning thermal microscope. Results reveal that the mean contact pressure is the main driving force involved in the degradation of the organic constituents. For the lowest mean contact pressure (<0.4 MPa), wear is rather weak because the friction-induced thermal component is not sufficient for degrading the organic matrices. In contrast, beyond 0.4 MPa, the friction-induced contact temperature rises up over the melting point of the organic matrices, and may even reach the temperature of the aragonite–calcite phase transformation increasing dramatically the wear of sheet nacre.     

Half-Maintainability?A Formidable Goal

A recent letter issued by HQ USAF/CV established a Double-R/Half-M policy for developing reliability and maintainability (R&M) requirements for the next generation of systems. This paper reviews the second portion of that policy, Half-M, and assesses the feasibility and implications of achieving the goal, as well as the programmatic elements considered most likely to assist in achievement of the goal. The paper discusses measures of maintainability, trends and concepts influencing maintainability, and the maintainability of current systems. The results of a survey of maintainability practitioners are presented as part of the assessment of the Half-M goal.     

Active power filters — Recent advances

Power electronic loads inject harmonic currents into the utility causing overheating of power transformers and neutral wires, the power system, unpredictable performance of protection systems etc. In addition, electric resonances in such loads can also cause other undesirable phenomena like voltage fluctuations, ratio frequency interference (RFI) etc. To mitigate these undesirable effects, a new class of power electronics equipment (Active Filters) is being considered. A review of present-day solutions in the area of active filters is conducted in this paper. Finally, this paper discusses the trends in the design of active filters and the factors influencing them.     

Affiliative vocalizations in infant rhesus macaques (Macaca mulatta).

In Exp 1, infant rhesus monkeys were separated and then reunited with mothers, united with a male, or placed into an empty cage. Infants girned more when with mothers or the male than when alone. Girns declined over time when infants were united with the male. Coo rates were high when the infant was alone or with the male. Shrieks, barks, and fear-related behavior were higher with the male. In Exp 2, the vocalizations of infants were examined during separation when alone or when mothers or a male were in the same room. Infants cooed more when mothers or a male were present. Cooing increased over time, with a greater increase in the mothers' presence. Girns were given to both mothers and males, but more were given to mothers. Coos and girns are both affiliative vocalizations but are differentially modulated as infants cease cooing when they receive contact comfort. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Corticotropin-releasing factor modulates defensive-withdrawal and exploratory behavior in rats.

The role of corticotropin-releasing factor (CRF), an endogenous neuropeptide, in modulating species-typical responses was examined in an unfamiliar open field containing a small chamber. Rats placed in this small chamber spent most of their time withdrawn in it. However, rats given an icv injection (20 μg) of α-helical CRF(9–41), a CRF receptor antagonist, emerged from the chamber and explored the unfamiliar open field. Results of additional studies with vehicle-treated rats suggest that reexposure reduces the threatening impact of an unfamiliar open field. CRF (300 ng) injected centrally, but not peripherally, before reexposure to the test environment significantly reduced exploration in the open field and increased a pattern of defensive-withdrawal into the chamber. Data suggest that whether defensive-withdrawal or exploratory behavior is exhibited may depend on CRF actions in brain systems that mediate the perception of threat in the environment. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Classification of chronic pain patients with the Brief Symptom Inventory: Patient characteristics of cluster profiles.

In this study, the psychological symptom patterns of individuals with chronic pain on the Brief Symptom Inventory (BSI) were cluster analyzed. Cluster analysis was initially performed on a sample of 1,489 people with chronic pain and then cross-validated on a smaller sample of 244 people. A 2-cluster solution was deemed most appropriate. The clusters reflected low- and high-profile elevations on all BSI subscales. As part of their clinical evaluation, participants also completed the Pain Disability Index, the adjective list from the McGill Pain Questionnaire, and a modified version of the Posttraumatic Chronic Pain Test. Among persons in the smaller sample, high-profile participants were more likely to be involved in litigation, report a higher frequency of posttraumatic stress symptoms, and display poorer psychosocial functioning. The results suggest that the BSI subgroups are associated with psychosocial characteristics that may be important in terms of treatment planning and outcome. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The free radical oxidation of polyunsaturated lecithins

Two unsymmetric polyunsaturated lecithins were allowed to air oxidize and the primary products of autoxidation were isolated and characterized. 1-Palmitic-2-linoleic-phosphatidylcholine undergoes significant oxidation after 16 hr at room temperature under air. A new phospholipid product may be isolated by reverse phase high pressure liquid chromatography (HPLC) and this HPLC fraction is shown to be made up of lipid hydroperoxides formed by free radical oxidation of the homoconjugated diene of the linoleate component of the lecithin. 1-Stearic-2-arachidonic-phosphatidylcholine undergoes a similar oxidation with the arachidonate polyunsaturated functionality being oxidized. The structure of the oxidation products was established by reduction of hydroperoxide with triphenylphosphine, snake venom hydrolysis of the C-2 ester, and HPLC analysis of the resulting hydroxy fatty acids or their methyl esters.