Segregation Effects at Grain Boundaries in Fluorite-Structured Ceramics

The atomic-scale structure, composition, and chemistry of grain boundaries in two fluorite-structured ceramic materials were characterized by a combination of Z -contrast imaging and electron energy-loss spectroscopy (EELS). In the case of a symmetric 24° [001] tilt bicrystal of yttria-stabilized-zirconia (YSZ), a shift in the zirconium M -edge onset and a change in the yttrium and zirconium M -edge ratios at the boundary indicate an increase in the number of electrons in the boundary plane. A detailed study of the structure and composition indicates that this is caused by an increase in the number of oxygen vacancies in the grain boundary core that is partially compensated by yttrium segregation. Studies of grain boundaries in an industrial Gd-doped ceria ceramic reveals similar changes in vacancy/dopant profiles indicating that these effects may be generic to grain boundaries in fluorite-structured materials.     

Relative specification and transformational re-use of functional programs

Arelative specification is a collection of laws relating the behaviour of a required new program to that of one or more existing programs. A two stage method for transforming such relative specifications into effective functional programs is described and illustrated. Theinversion stage re-arranges the specifying laws to obtain a collection ofpartial definitions for each unknown function, typically involving non-deterministic operators. The subsequentfusion stage combines each set of partial definitions into a single complete definition, thereby eliminating non-deterministic operators.Supported by Science and Engineering Research Council, Grant GR/E16571     

Urban agriculture

Conclusion  This paper has attempted to outline and account for the discrepancy between the literature and empirical findings linked to the environmental and ecological benefits of UA. Having done so, it is not calling for an empiricist approach, it does not necessarily take an anti-development stance nor is it against UA. It simply makes a plea that UA be understood in terms of those who practise it. Such an understanding would necessarily include theory and a specific view of development. It is hoped that it would also generate a discourse more in line with the practice, views and aspirations of the cultivators themselves.     

Batch basket filtration centrifuges for FGD pay their way

In the majority of the developed world, legislation has been introduced to reduce sulphur emissions from coal combustion processes through flue gas desulphurization systems. On the downside, the installation of such technology is a costly business, even with governmental financial support. However, by combining the limestone gypsum FDG system with batch basket filtration centrifuges, a saleable product, i.e. high quality gypsum, can be produced, which makes the incorporation of FGD technology a much more economically viable option. Nigel Day explains.     

Walking through CS AKTive Space: a demonstration of an integrated Semantic Web application

We describe CS AKTive Space, an integrated semantic web application and winner of the 2003 Semantic Web Challenge [http://www.challenge.semanticweb.org/]. A demonstration of the application is available at http://cs.aktivespace.org/. CS AKTive Space represents and integrates a wide range of heterogenous resources representing the computer science domain in the UK; it supports the exploration of patterns and implications inherent in the content and exploits a variety of services, visualisations and multidimensional representations to support questions like who is working with whom, where are there geographical concentrations in funding or research area, who are the most significant researchers in an area. We briefly show how this demonstration illustrates a number of substantial challenges for the Semantic Web. These include problems of referential integrity, tractable inference and interaction support. We review our approaches to these issues and discuss relevant related work.     

Development of an Electrochemical Device for Removal of Arsenic from Drinking Water

The forthcoming introduction of lower standards for arsenic in drinking water requires new technologies for arsenic removal. We report the development of an electrochemical unit for remediating domestic water supplies for homes without municipally treated water. Electrolysis in a two‐anode system provides oxidants to convert As(III) to As(V) in situ, and a sacrificial anode to deliver iron into solution. Conditioning tanks after each electrolysis step ensure completion of the chemical reactions. At the pH of domestic water, As(V) co‐precipitates with Fe(OH)₃; subsequent filtration leaves <10 ppb of inorganic arsenic in solution.     

Structural and Biochemical Studies of Actin in Complex with Synthetic Macrolide Tail Analogues

The actin filament‐binding and filament‐severing activities of the aplyronine, kabiramide, and reidispongiolide families of marine macrolides are located within the hydrophobic tail region of the molecule. Two synthetic tail analogues of aplyronine C (SF‐01 and GC‐04) are shown to bind to G‐actin with dissociation constants of (285±33) and (132±13) nM , respectively. The crystal structures of actin complexes with GC‐04, SF‐01, and kabiramide C reveal a conserved mode of tail binding within the cleft that forms between subdomains (SD) 1 and 3. Our studies support the view that filament severing is brought about by specific binding of the tail region to the SD1/SD3 cleft on the upper protomer, which displaces loop‐D from the lower protomer on the same half‐filament. With previous studies showing that the GC‐04 analogue can sever actin filaments, it is argued that the shorter complex lifetime of tail analogues with F‐actin would make them more effective at severing filaments compared with plasma gelsolin. Structure‐based analyses are used to suggest more reactive or targetable forms of GC‐04 and SF‐01, which may serve to boost the capacity of the serum actin scavenging system, to generate antibody conjugates against tumor cell antigens, and to decrease sputum viscosity in children with cystic fibrosis.     

Understanding the New Zealand non-domestic building stock

Unlike the residential building stock, most countries have poor information on their non-domestic stock. This necessitates the use of other data sources. In the mid-1980s the (then) New Zealand Department of Valuation digitized its valuation records. This permitted the first analysis of an entire country's non-domestic buildings. A very long-tail probability density function was identified, with the largest 5% of buildings containing more than 40% of the floor space. This knowledge informed the development of research for understanding non-domestic buildings as well as underpinning the 1996 revision of the NZ Building Code Clause H1 Energy Efficiency. More recently an analysis of valuation data has provided the Building Energy End-use Study (BEES) with a national sampling frame to examine energy and water end-uses in non-domestic buildings. The development of processes for collecting and analyzing data is described. Considerable changes in understanding of valuation data have occurred for documenting the non-domestic building stock. New online and geographic information sources can validate and improve building data. The use of such a database supports improved understanding of the changing nature of the building stock and potential intervention points, as well as harnessing regulatory and market forces.     

Optimising the production of energy from coblended food waste and biosolids using batch reactor studies

Energy production from a coblended mixture of biosolids and food waste was optimised for hydrogen and methane production. Four different blends were prepared by varying the carbohydrate : protein (carb : pro) ratios. The biosolids contained a low carbohydrate fraction and so was not suitable for hydrogen production when used alone. However coblending this waste with a carbohydrate‐enriched food waste produced a greater hydrogen yield, making this option viable. Batch studies showed that the optimised mix had a biosolids concentration of 25.7% (w/w). The largest hydrogen yield of 198.5 mL/gVS_removed was observed when the carb : pro was 2.78, and this was threefold higher than the other carb : pro ratios evaluated in this study. The digestate recovered after hydrogen recovery had a C : N of 17.5, which is in the ideal range for methane production. The biochemical methane potential test showed a methane yield of 239 mL/gVS_removed, and the total volatile solids destruction following two‐phase hydrogen and methane production was 93%.