Effects of mixing sequence on peroxide cured polypropylene (PP)/ethylene octene copolymer (EOC) thermoplastic vulcanizates (TPVs). Part. II. Viscoelastic characteristics

The effects of mixing sequence on the dynamic viscoelastic characteristics of peroxide cured polypropylene (PP)/ethylene octene copolymer (EOC) based TPVs were studied both in solid and melt states. When a peroxide is added to PP-EOC blends, two major competing reactions take place simultaneously: crosslinking in the EOC phase and degradation in the PP phase by ß-chain scission. Three different mixing sequences were employed. They are as follows: (a) preblending method—melt mixing of PP and EOC followed by dynamic vulcanization (b) phase mixing method—curative master batch of EOC added in molten PP and (c) split addition method—preblending procedure followed by addition of half part of PP. Solid state viscoelastic properties were studied by using dynamic mechanical thermal analysis (DMTA). Melt state viscoelastic properties were studied by dynamic strain sweep at 180 °C in Rubber Process Analyser (RPA 2000). The results indicate that both solid and melt state viscoelastic characteristics are strongly influenced by sequence of mixing. A good correlation is observed between the particle size of crosslinked EOC and the dynamic storage modulus obtained from the melt rheological experiments. Furthermore, the shortcomings of dynamic mechanical analyses in evaluating the properties of the TPVs are also critically discussed.     

Animating Volumetric Models

This paper describes a technique to animate three-dimensional sampled volumes. The technique gives the animator the ability to treat volumes as if they were standard polygonal models and to use all of the standard animation/motion capture tools on volumetric data. A volumetric skeleton is computed from a volumetric model using a multi-resolution thinning procedure. The volumetric skeleton is centered in the object and accurately represents the shape of the object. The thinning process is reversible in that the volumetric model can be reconstructed from the volumetric skeleton. The volumetric skeleton is then connected and imported into a standard graphics animation package for animation. The animated skeleton is used for reconstruction, which essentially recreates a deformed volume around the deformed skeleton. Polygons are never computed and the entire process remains in the volumetric domain. This technique is demonstrated on one of the most complex 3D datasets, the Visible Male, resulting in actual “human animation”.     

A finite element model to predict the ablation depth in pulsed laser ablation

This work presents development of a two-dimensional finite element model to predict temperature distribution and ablation depth in a laser ablation process. The model considers a number of aspects of the process, which hitherto have been considered independently in the literature. The aspects considered include: temperature dependent material properties of the target material, effect of plasma shielding on the incident laser flux, and temperature dependent absorptivity and absorption coefficient of the target. It was evident that these considerations have resulted in a significant improvement in the ability of the model to predict the ablation depth. Finally, the predicted ablation depth was found to match extremely well with experimental results at lower laser fluences, though at higher fluences there is a marginal overestimation.     

Compressive and ultrasonic properties of polyester/fly ash composites

The addition of hollow fillers having appropriate mechanical properties can decrease the density of the resulting composite, called syntactic foams, while concurrently improving its mechanical properties. In this study, hollow fly ash particles, called cenospheres, are used as fillers in polyester matrix material. Cenospheres are a waste by-product of coal combustion and, as such, are available at very low cost. In this study, the composites were synthesized by settling cenospheres in a glass tube filled with liquid polyester resin and subsequently curing the resin. This process resulted in a functionally graded structure containing a gradient in the cenosphere volume fraction along the sample height. Uniform radial sections were cut from each composite and were characterized to observe the relationship between cenosphere volume fraction and compressive properties of the composite. The composite was also tested using ultrasonic non-destructive evaluation method. Results show that the modulus of the composites increases with increasing cenosphere volume fraction. The modulus of composites containing more than 4.9 vol% cenosphere was found to be higher than the matrix resin. In general, the modulus of composites increased from 1.33 to 2.1 GPa for composites containing from 4.9–29.5 vol% cenospheres. The specific strength of the composite was found to be as high as 2.03 MPa/(kg/m³) compared to 0.96 MPa/(kg/m³) for the neat resin. Numerous defects present in fly ash particles caused a reduction in the strength of the composite. However, the reduction in the strength was found to be only up to 22%. Increase of over 110% in the specific modulus and only a slight decrease in the strength indicates the possibility of significant saving of weight in the structures using polyester/fly ash syntactic foams.     

PPSTS: Privacy Preservation in Geographical Data by Spatio-Temporal Shifting Using Elliptic Curve Cryptography

Wireless Personal Communications - The massive growth in modern wireless technologies and devices has resulted in increase in spectrum demands and energy consumption of wireless sensor network...     

A Thermoplastic Polyurethane /Nanosilica Composite via Melt Mixing Process and its Properties

Silicon - This investigation reports the preparation and properties of thermoplastic polyurethane/silica nanocomposite prepared via melt mixing process. In this case, nanosilica at different...     

Performance of a large scale packed recirculating reactor for homogeneous catalytic oxidation of car-3-ene

Autooxidation of car-3-ene was carried out in a large scale packed recirculating reactor, where the catalyst cobalt acetylacetonate and the liquid were recirculated and sprayed on top of an inert packing. Gas is introduced from the bottom. The mass transfer parameters and mixing characteristics of the reactor were determined. The effect of catalyst quantity, operating pressure on car-3-ene conversion, and selectivity for various products were studied. The reaction system was mathematically modelled, and the simulation compared with the observed behaviour. The rate constants of the elementary reaction steps had been determined separately in a laboratory reactor.