MICAST — The effect of magnetically controlled fluid flow on microstructure evolution in cast technical Al-alloys

The MICAST research program focuses on a systematic analysis of the effect of convection on the microstructure evolution in cast Al-alloys. The experiments within MICAST are carried out under well defined thermally and magnetically controlled, convective boundary conditions and analyzed using advanced diagnostics and theoretical modeling, involving phase field simulation, micro-modeling and global simulation of heat and mass transport. The MICAST team uses as a model material the Al-Si base alloys. This paper gives a brief overview on recent experimental results of the MICAST team on the effect of rotating magnetic fields on microstructure in AlSi alloys.     

Identification Facilitation for Emotionally Arousing Verbs During the Attentional Blink.

The present study aimed to examine affective modulation of the "attentional blink" effect during rapid serial visual presentation (RSVP). Pleasant, neutral, and unpleasant written verbs were used as a 2nd target (T2) in an 8.6-Hz RSVP paradigm. Pronounced effects of 1st target (T1)-T2 stimulus onset asynchrony (SOA) were found, showing reduced report accuracy for 232- and 464-ms SOAs. Affectively arousing (pleasant and unpleasant) T2s were associated with enhanced accuracy compared with neutral T2s specifically during short (232 ms) SOAs. In contrast, pleasant and unpleasant T2s rated low in terms of emotional arousal did not show this enhancement. These results suggest that affectively arousing information is selected preferentially from a temporal stream, facilitating processes such as working memory consolidation and action. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Magneto-transport Properties and Thermally Activated Flux Flow in Ba(Fe 0 . 9 1 Co 0 . 0 9 ) 2 As 2 Superconductor

Thermally assisted flux flow (TAFF) based on magneto-resistivity and ac susceptibility measurements is studied in a Ba(Fe_0.91Co_0.09)₂As₂(T _c=25.3 K) sample in magnetic fields up to 18 T. In addition to the upper critical field μ ₀ H _c2 and the coherence length ξ(0), the flux flow activation energy U(T,H) has also been determined. The resistive transition width is proportional to μ ₀ H, in contrast to Tinkham’s theoretical prediction. By applying Fisher’s model, the glass melting transition temperature T _g, which occurs in the upper TAFF state and not in the zero resistivity vortex solid regime, is calculated. The onset of TAFF temperature and the crossover temperature T _x from TAFF to flux flow are determined. By contrasting the ac susceptibility data with the resistivity data, considerable flux penetration appears even in the zero resistivity state, in addition to ac losses. The H-T phase diagram is drawn and shows weak pinning regime as the field approaches μ ₀ H _c2, and the strength of the weak pinning decreases to 0 with increasing magnetic field from 0 to 18 T.     

Efficient Total Chemical Synthesis of 13C=18O Isotopomers of Human Insulin for Isotope‐Edited FTIR

Isotope‐edited two‐dimensional Fourier transform infrared spectroscopy (2 D FTIR) can potentially provide a unique probe of protein structure and dynamics. However, general methods for the site‐specific incorporation of stable ¹³C=¹⁸O labels into the polypeptide backbone of the protein molecule have not yet been established. Here we describe, as a prototype for the incorporation of specific arrays of isotope labels, the total chemical synthesis—via a key ester insulin intermediate—of 97 % enriched [(1‐¹³C=¹⁸O)Phe^B24] human insulin: stable‐isotope labeled at a single backbone amide carbonyl. The amino acid sequence as well as the positions of the disulfide bonds and the correctly folded structure were unambiguously confirmed by the X‐ray crystal structure of the synthetic protein molecule. In vitro assays of the isotope labeled [(1‐¹³C=¹⁸O)Phe^B24] human insulin showed that it had full insulin receptor binding activity. Linear and 2 D IR spectra revealed a distinct red‐shifted amide I carbonyl band peak at 1595 cm^?1 resulting from the (1‐¹³C=¹⁸O)Phe^B24 backbone label. This work illustrates the utility of chemical synthesis to enable the application of advanced physical methods for the elucidation of the molecular basis of protein function.     

Evaluation of non-linear strain paths using Generalized Forming Limit Concept and a modification of the Time Dependent Evaluation Method

The prediction of formability is one of the most important tasks in sheet metal forming process simulation. The common criterion for ductile fracture in industrial applications is the Forming Limit Diagram (FLD). This is only applicable for linear strain paths. However, in most industrial simulation cases non-linear strain paths occur. To resolve this problem, a phenomenological approach is introduced, the so-called Generalized Forming Limit Concept (GFLC). The GFLC enables prediction of localized necking on arbitrary non-linear strain paths. Another possibility is the use of the Time Dependent Evaluation Method (TDEM) within the simulation as a failure criteria. During the Numisheet Benchmark 1 (2014) a two-stage forming process was performed with three typical sheet materials (AA5182, DP600 and TRIP 780) and three different blank shapes. The task was to determinate the point in time and space of local instability. Therefore the strain path for the point of maximum local thinning is evaluated. To predict the start of local necking the Generalized Forming Limit Concept (GFLC), the Time Dependent Evaluation Method (TDEM) and the modified TDEM were applied. The results of the simulation are compared with the results of the Benchmark experiment.     

Characterisation of CO/NO/SO2 emission and ash-forming elements from the combustion and pyrolysis process

Bioenergy is considered as a sustainable energy which can play a significant role in the future’s energy scenarios to replace fossil fuels, not only in the heat production, but also in the electricity and transportation sectors. Emission formation and release of main ash-forming elements during thermal conversion of biomass fuels at different conditions have been the scope of this study. The experiments were conducted in a quartz glass reactor where the temperature and atmosphere could be controlled. The selected fuels represent a wide range of biomass compositions. They are torrefied softwood, spruce bark, waste wood, miscanthus, and wheat straw. The fuels were first grinded and then pressed with a pellet maker into pellets of the same size and weight. For each fuel, the experiments were carried out under both oxidation and pyrolysis condition, with atmosphere of 3 % O₂ + 97 % N₂ and 100 % N₂, respectively, at four residence times. The selected temperatures under which experiments were performed are 800, 900, and 1,050 °C. The concentration of SO₂, NO, CO, and CO₂ emissions and O₂ were monitored online by three analysers, simultaneously. The residue weight was measured after each process, and the comparison with the ash content of the fresh pellet is made. Additionally, the release of several ash-forming elements (K, Zn, Na, and Mn) from the fuels has been quantified as function of temperature and residence time by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma atomic emission spectroscopy (ICP-AES). Time-dependent formation of NO and SO₂ and other emissions is presented and discussed with respect to different temperature and combustion conditions.     

Point or pointless – quality of ground data

A method for measuring continuously the inherent optical properties of water together with the salinity and the temperature values was developed and tested at the Division of Geophysics, University of Helsinki. The flow‐through system operates from a moving boat and has been used to collect parameters for optical modelling, coastal zone and inland water studies and to track the path of the fresh water spreading into sea areas. The system was also used in Lake Vänern, Sweden, to calculate the radiance reflectance, R _r, and total back‐scattering efficiency, b _{b eff}, along a transect. An example from the Gulf of Finland is presented, which shows how the spectral behaviour of light changes when moving away from a fresh water source. Data collected from the River Kymijoki estuary showed that the details in a rapidly changing environment were strongly smoothed in a Moderate Resolution Imaging Spectroradiometer (MODIS) data image. The correlation for continuously measured scattering values and MODIS channel 1 data varied between 0.70 and 0.85, n?=?126. Flow‐through measurement datasets can be used to obtain representative sites for vertical profiles or calibration measurements.