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71.
Grinding processes can be optimized by simulating the influence of individual grains on process forces and surface topographies. However, the process results are significantly influenced by tool wear. Simulating this effect allows, e.g., the prediction of necessary tool changes when manufacturing large forming tools. Therefore, a new point-based approach for modeling arbitrarily shaped grains in different states of tool wear was developed. Based on a small amount of representative wear investigations, a flexible tool model was defined, which can be used for various tool shapes without further experiments. This model can be applied for grinding processes with varying engagement situations. 相似文献
72.
Elisabeth Koch Mustafa Bagci Michael Kuhn Nicole M. Hartung Malwina Mainka Katharina M. Rund Nils Helge Schebb 《Lipids》2023,58(1):41-56
Oxysterols play a key role in many (patho)physiological processes and they are potential biomarkers for oxidative stress in several diseases. Here we developed a rapid gas chromatographic-mass spectrometry-based method for the separation and quantification of 11 biologically relevant oxysterols bearing hydroxy, epoxy, and dihydroxy groups. Efficient chromatographic separation (resolution ≥ 1.9) was achieved using a medium polarity 35%-diphenyl/65%-dimethyl polysiloxane stationary phase material (30 m × 0.25 mm inner diameter and 0.25 μm film thickness). Based on thorough analysis of the fragmentation during electron ionization we developed a strategy to deduce structural information of the oxysterols. Optimized sample preparation includes (i) extraction with a mixture of n-hexane/iso-propanol, (ii) removal of cholesterol by solid phase extraction with unmodified silica, and (iii) trimethylsilylation. The method was successfully applied on the analysis of brain samples, showing consistent results with previous studies and a good intra- and interday precision of ≤20%. Finally, we used the method for the investigation of oxysterol formation during oxidative stress in HepG2 cells. Incubation with tert-butyl hydroperoxide led to a massive increase in free radical formed oxysterols (7-keto-chol > 7β-OH-chol >> 7α-OH-chol), while 24 h incubation with the glutathione peroxidase 4 inhibitor RSL3 showed no increase in oxidative stress based on the oxysterol pattern. Overall, the new method described here enables the robust analysis of a biologically meaningful pattern of oxysterols with high sensitivity and precision allowing us to gain new insights in the biological formation and role of oxysterols. 相似文献
73.
Anaerobic degradation of cis-1,2-dichloroethene (cis-1,2-DCE) and 1,2-dichloroethane (1,2-DCA) was studied in microcosms derived from a laboratory-scale upflow treatment wetland system used to biodegrade chlorinated compounds present in groundwater from a Superfund site. Dechlorination kinetics of cis-1,2-DCE (0.94-1.57 d(-1)) and 1,2-DCA (0.15-0.71 d(-1)) were rapid, and degradation proceeded to completion with ethene or ethane as terminal dechlorination products. Hydrogen concentrations, measured simultaneously during dechlorination, were significantly different for the two compounds, approximately 2.5 nM for cis-1,2-DCE and 38 nM for 1,2-DCA. Methanogenesis proceeded during the degradation of 1,2-DCA when H2 concentrations were high but not during the dechlorination of cis-1,2-DCE when H2 concentrations were below published thresholds for methanogenesis. A 16S rRNA gene-based approach indicates that microorganisms closely related to Dehalococcoides ethenogenes were present and that they were distributed throughout the bottom, middle, and top of the upflow treatment wetland system. These results coupled with consideration of hydrogen thresholds, degradation kinetics, daughter products, and measurements of methanogenesis strongly suggest that halorespirers were responsible for dechlorination of cis-1,2-DCE and that 1,2-DCA dechlorination was co-metabolic, likely mediated by acetogens or methanogens. Rapid dechlorination potential was distributed throughout the wetland bed, both within and below the rhizosphere, indicating that reductive dechlorination pathways can be active in anaerobic environments located in close spatial proximity to aerobic environments and plants in treatment wetland systems. 相似文献
74.
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76.
Für die Prognose der Gef?hrdung der Schutzgüter Grundwasser und Boden gewinnen numerische Programmsysteme zur Simulation von Str?mungs- und Stofftransportprozessen immer mehr an Bedeutung. Im Mittelpunkt des Interesses stehen dabei komplexe geochemische Reaktionsvorg?nge, dichtebeeinflusste Str?mungs- und Stofftransportvorg?nge, komplizierte hydraulische Gegebenheiten und die Parameterbelegung gro?er Modelle. Das hier beschriebene Programmsystem MODCALIF erlaubt die dreidimensionale Simulation der dichtebeeinflussten Str?mung und des Stofftransportes. Die Verwendung neu integrierter L?sungalgorithmen erm?glicht eine grobe r?umliche Diskretisierung und damit eine deutliche Verringerung des Rechenaufwandes. Die Berücksichtigung unterschiedlicher Ans?tze zur Beschreibung der Wechselwirkungen zwischen gel?stem Stoff und Feststoff sowie die Kopplung mit dem geochemischen Gleichgewichtsprogramm PHREEQC erlauben die Simulation des Stofftransportes für vielf?ltige Problemstellungen. Aufbauend auf einer kurzen Darstellung der theoretischen Grundlagen des Programmsystems MODCALIF wird das Programm verifiziert und seine Anwendbarkeit an zwei ausgew?hlten Fallbeispielen praktisch demonstriert. 相似文献
77.
In many industries mixed-model assembly systems are increasingly supplied out of third-party consignment stock. This novel
trend gives rise to a new short-term sequencing problem which decides on the succession of models launched down the line and
aims at minimizing the cost of in-process inventory held by the manufacturer. In this work, we investigate the mathematical
structure of this part oriented mixed-model sequencing problem and prove that general instances of the problem are NP-hard
in the strong sense. Moreover, we develop a new Beam Search heuristic, which clearly outperforms existing solution procedures. 相似文献
78.
In this paper, we introduce a new approach to the method of non-parametric adaptive spectral analysis by using the Amplitude and Phase Estimation (APES) method, and taking into account the small sample errors of the sample covariance matrix. This approach is referred to as Adaptive Tuning Amplitude and Phase Estimation method (ATAPES). The main advantage of the ATAPES algorithm is its elimination of biased estimation exists with APES method, which is a biased peak location and corresponding problem of the biased amplitude estimation. The ATAPES method provides more accurate peak location and amplitude estimation with higher resolution than APES method. 相似文献
79.
High performance liquid chromatography-electrospray tandem mass spectrometry was used to elucidate the phospholipids in krill
oil extracted from Euphausia superba, an emerging source for human nutritional supplements. The study was carried out in order to map the species of the choline-containing
phospholipid classes: phosphatidylcholine and lyso-phosphatidylcholine. In addition, the prevalent phosphatidylcholine class
was quantified and the results compared with prior analysis. The qualification was performed with separation on a reverse
phase chromatography column, while the quantification was obtained with class separation on a normal phase chromatography
column. An Orbitrap system was used for the detection, and pulsed-Q dissociation fragmentation was utilized for the identification
of the species. An asymmetrical exclusion list was applied for detection of phospholipid species of lower concentration, significantly
improving the number of species observed. A total of 69 choline-containing phospholipids were detected, whereof 60 phosphatidylcholine
substances, among others seven with probable omega-3 fatty acids in both sn-1 and sn-2. The phosphatidylcholine concentration was estimated to be 34 ± 5 g/100 g oil (n = 5). These results confirm the complexity of the phospholipid composition of krill oil, and the presence of long chained,
heavily unsaturated fatty acids. 相似文献
80.