Densification Kinetics of CeO<Subscript>2</Subscript> Reinforced 8 Mol.% Y<Subscript>2</Subscript>O<Subscript>3</Subscript> Stabilized ZrO<Subscript>2</Subscript> Ceramics

The grain growth kinetics of 8YSZ ceramics processed using spark plasma sintering (SPS) has been investigated in the temperature ranging from 1100°C to 1500°C. The activation energy during SPS densification was obtained as 332 kJ/mol with grain boundary diffusion as a dominant mechanism. Further, the effect of CeO₂ on the densification kinetics of 8YSZ ceramic processed via SPS and conventional sintering (CS) has been delineated. The lower grain boundary mobility of CS-processed composites (an order of magnitude lower than SPS) is attributed to the solute drag and lattice distortion mechanism. However, no significant change in the grain boundary mobility was observed with CeO₂ addition (~?14.7–43.9?×?10^?18 m³/N/s for CS and 107.2–116.7?×?10^?18 m³/N/s for SPS) revealing that the defect concentration is nearly constant in 8YSZ. The study highlights the effect of sintering techniques (SPS and CS) and reinforcement (CeO₂) on engineering the desired microstructure of 8YSZ ceramic.     

Electric field assisted solid-state interfacial joining of TaC-HfC ceramics without filler

The application of ultra-high-temperature ceramics (UHTCs) demands effective ways of joining in overcoming the problems associated with the fabrication of complex-shaped components. In this study, we choose to investigate a new method of rapidly joining pre-sintered TaC and HfC ceramics without any filler material using the spark plasma sintering (SPS) technique. A well-bonded TaC–HfC interface was observed with no apparent cracking and porosity at the joint. The joining mechanisms were predominantly driven by solid-state diffusion and localized plastic deformation. The nanomechanical properties of the TaC-HfC joint are better than the HfC while comparable to that of the TaC. High-load indentation (up to 200 N) results suggest that the TaC–HfC interface is stronger than the parent UHTCs with no crack propagating at the interface. Upon comparison with the parent UHTCs, the damaged area and the average crack length at the interface, reduced up to ~94% and ~56%, respectively. This study shows that the SPS technique can also apply to joining other UHTCs without any filler, resulting in the new field of developing complex components for the thermal protection system (TPS).     

Noble Metal Nanocrystal‐Incorporated Fullerene‐Like Polyoxometalate Based Microspheres

Monodisperse fullerene‐like polyoxometalate‐based microspheres are synthesized using a single‐phase approach which is quick, easier to control surfactant to polyoxometalate (POM) molar ratios and result in better control over the size‐distribution range. Noble‐metal nanocrystals are successfully incorporated in the surfactant encapsulated complex multilayered spherical assemblies without any change in their layered morphology. Combining the merits of fullerene‐like POMs and monodisperse noble metal nanocrystals, these monodisperse hybrid spheres show interesting composition‐ and size‐dependent photochemical properties.     

Exact Analysis of Non-Linear Fractionalized Jeffrey Fluid. A Novel Approach of Atangana-Baleanu Fractional Model

It is a very difficult task for the researchers to find the exact solutions to mathematical problems that contain non-linear terms in the equation. Therefore, this article aims to investigate the viscous dissipation (VD) effect on the fractional model of Jeffrey fluid over a heated vertical flat plate that suddenly moves in its own plane. Based on the Atangana-Baleanu operator, the fractional model is developed from the fractional constitutive equations. VD is responsible for the non-linear behavior in the problem. Upon taking the Laplace and Fourier sine transforms, exact expressions have been obtained for momentum and energy equations. The influence of relative parameters on fluid flow and temperature distribution is shown graphically. As special cases, and for the sake of correctness, the corresponding results for second-grade fluid and Newtonian viscous fluid are also obtained. It is interesting to note that fractional parameter α provides more than one line as compared to the classical model. This effect represents the memory effect in the fluid which is not possible to elaborate by the classical model. It is also worth noting that the temperature profile of the generalized Jeffrey fluid rises for higher values of Eckert number which is due to the enthalpy difference of the boundary layer.     

Al₂O₃ and γAl₂O₃ Nanomaterials Based Nanofluid Models with Surface Diffusion: Applications for Thermal Performance in Multiple Engineering Systems and Industries

Thermal transport investigation in colloidal suspensions is taking a significant research direction. The applications of these fluids are found in various industries, engineering, aerodynamics, mechanical engineering and medical sciences etc. A huge amount of thermal transport is essential in the operation of various industrial production processes. It is a fact that conventional liquids have lower thermal transport characteristics as compared to colloidal suspensions. The colloidal suspensions have high thermal performance due to the thermophysical attributes of the nanoparticles and the host liquid. Therefore, researchers focused on the analysis of the heat transport in nanofluids under diverse circumstances. As such, the colloidal analysis of H₂O composed by γAl₂O₃ and Al₂O₃ is conducted over an elastic cylinder. The governing flow models of γAl₂O₃/H₂O and Al₂O₃/H₂O is reduced in the dimensionless form by adopting the described similarity transforms. The colloidal models are handled by implementing the suitable numerical technique and provided the results for the velocity, temperature and local thermal performance rate against the multiple flow parameters. From the presented results, it is shown that the velocity of Al₂O₃–H₂O increases promptly against a high Reynolds number and it decreases for high-volume fraction. The significant contribution of the volumetric fraction is examined for thermal enhancement of nanofluids. The temperature of Al₂O₃–H₂O and γAl₂O₃–H₂O significantly increases against a higher ϕ. Most importantly, the analysis shows that γAl₂O₃–H₂O has a high local thermal performance rate compared to Al₂O₃–H₂O. Therefore, it is concluded that γAl₂O₃–H₂O is a better heat transfer fluid and is suitable for industrial and technological uses.     

Mechanical transfer of electrochemically grown molybdenum sulfide layers to silicon wafer

Journal of Applied Electrochemistry - Large area MoS2 ultra-thin film deposition is one of the big challenges in the recent years. Electrodeposition provides an opportunity to grow such ultra-thin...     

Synthesis,Characterization and Surface Properties of Amidosulfobetaine Surfactants Bearing Odd-Number Hydrophobic Tail

Three amidosulfobetaine surfactants were synthesized namely: 3-(N-pentadecanamidopropyl-N,N-dimethyl ammonium) propanesulfonate (2a); 3-(N-heptadecanamidopropyl-N,N-dimethyl ammonium) propanesulfonate (2b), and 3-(N-nonadecanamidopropyl-N,N-dimethyl ammonium) propanesulfonate (2c). These surfactants were prepared by direct amidation of commercially available fatty acids with 3-(dimethylamino)-1-propylamine and subsequent reaction with 1,3-propanesultone to obtain quaternary ammonium salts. The synthesized surfactants were characterized by IR, NMR and mass spectrometry. Thermogravimetric analysis (TGA) results showed that the synthesized surfactants have excellent thermal stability with no major thermal degradation below 300 °C. The critical micelle concentration (CMC) values of the surfactants 2a and 2b were found to be 2.2 × 10^?4 and 1.04 × 10^?4 mol/L, and the corresponding surface tension (γ_CMC) values were 33.14 and 34.89 mN m^?1, respectively. The surfactants exhibit excellent surface properties, which are comparable with conventional surfactants. The intrinsic viscosity of surfactant (2b) was studied at various temperatures and concentrations of multi-component brine solution. The plot of natural logarithm of relative viscosity versus surfactant concentration obtained from Higiro et al. model best fit the surfactant behavior. Due to good salt resistance, excellent surface properties and thermal stability, the synthesized surfactant has potential to be used in various oil field applications such as enhanced oil recovery, fracturing, acid diversion, and well stimulation.     

Estimation of a Unique Pair of Nash Model Parameters: An Optimization Approach

Water resources planning and management requires hydrologic models to estimate runoff from a catchment. For catchments with limited data, the choice of model and identification of its parameters is very important for development of a direct runoff hydrograph. A method is presented to determine a unique pair of hydrologic parameters of the Nash Model, number of linear cascade (n) and storage coefficient (k), using optimization based on Downhill Simplex technique. In this study physical parameters of the catchment are derived from (SPOT) satellite imageries of the basin using ERDAS software. Four different objective functions of varying complexity are tested to find the best solution. Weighted root mean square error (RMSE) and Model Efficiency (Nash-Sutcliffe coefficient) are used to evaluate the model performance. Using the NASH model, a direct surface runoff hydrograph (DSRH) is developed. Kaha catchment is part of Indus river system and is located in the semi-arid region of Pakistan. This catchment is dominated by hill torrent flows and is used in this work to demonstrate the applicability of the proposed method. Ten randomly selected rainfall-runoff events are used for calibration and five events are used for validation. Model results during validation are very promising with model efficiency exceeding 93% and error in peak discharge under 8%. The sensitivity of the Nash model output in response to variation in hydrologic parameters n and k is also investigated. When evaluating the hydrologic response of large catchments, model output is more sensitive to n as compared to k indicating that the runoff diffusion phenomenon is dominant compared to translation flow effects.     

Potential of the renewable energy development in Jammu and Kashmir,India

The future economic growth for India is likely to result in rapid and accelerated surge in energy demand, with expected shortages in terms of supply. Many of its current policies and strategies are aimed at the improvement and possible maximization of energy production from the renewable sector. It is also clear that while energy conservation and energy efficiency can make an important contribution, renewable energies will be essential to the solution and are likely to play an increasingly important role for providing enhanced energy access, reducing consumption of fossil fuels, and helping India pursue its low-carbon progressive pathway. However, most of the states in India, like the northernmost state of Jammu and Kashmir, have experienced an energy crisis over a sustained period of time and the government both at center and state level has to embark upon with these pressing issues in a more sustainable manner and accordingly initiate various renewable energy projects within these states. This paper will provide a broad-spectrum view about the energy situation within Jammu and Kashmir and will highlight the current policies along with future strategies for the optimal utilization of renewable energy resources.