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排序方式: 共有192条查询结果,搜索用时 12 毫秒
11.
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Nagatoshi Nishiwaki Tomoya Konishi Shiro Tsukamoto Masahiko Shimoda 《Journal of Inorganic and Organometallic Polymers and Materials》2010,20(4):873-876
A palladium catalyst supported on a semiconductor plate underwent the Heck reaction effectively to afford a coupling product. The catalytic plate was easily recovered from the reaction mixture with tweezers and reused several times without any special treatment. Comparison of reusability, durability, and treatability of seven kinds of commercially available solid-supported palladium catalysts and the semiconductor-supported catalyst plate was studied. 相似文献
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ZnO nonlinear dielectric has a small temperature coefficient of conductivity up to about 550 C, and above 550 C the temperature coefficient of conductivity becomes substantially positive, which tends to result in thermal runaway through condensation of the current density into filaments which “melt” their way through the ceramic. Thus to obtain maximum energy absorption in a ZnO element, it is important to avoid hot spots so that the element will heat quite uniformly to its maximum stable operating temperature in the range of 550 C. The current density at the electrode edge is enhanced by spreading of the current into the ZnO at radii larger than the electrode. This causes an enhanced temperature at the electrode edge which results in the “melting punctures” commonly observed. Using transient, nonlinear finite element analysis with coupled thermal and electric fields, the authors have quantified the temperature enhancement as a function of edge margin and optimized the electrode topology 相似文献
15.
Yasuhisa Ishikawa Akihiko Iwai Susumu Nishiwaki Tadashi Koshizuka Tsuneharu Teranishi Kyouichi Uehara 《Electrical Engineering in Japan》2004,146(2):20-26
Investigations were conducted on the VFT (Very Fast Transient) surges that propagate into a 500‐kV transformer. The disconnector restriking surge and ground fault surged were discussed. It was regarded that a large part of the surge voltage was applied just at the entrance of the transformer winding for the VFT surges. Thus, an equivalent circuit that models the windings was used for the analysis. The overvoltages that appear between the first winding sections at the entrance of the transformer were computed. The following was established. (1) The overvoltage between the first winding sections becomes greater when the magnitude of the voltage change at the transformer terminal is larger. The overvoltage between the first winding sections is not affected by the magnitude of the transformer terminal voltage. (2) For the disconnectors that are not connected directly to the transformer, the voltage change at the transformer terminal is not so large. (3) In the case of a ground fault at the GIS near the transformer, the voltage change at the transformer terminal is the same as that for a disconnector directly connected to the transformer. (4) In actual GIS, the disconnector that is connected directly to the transformer is not usually used. In this situation, the overvoltages that threaten the transformer insulation will not be generated by the restriking of the disconnectors. © 2003 Wiley Periodicals, Inc. Electr Eng Jpn, 146(2): 20–26, 2004; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10225 相似文献
16.
Tsuyoshi Nishiwaki Atsushi Yokoyama Zen-ichiro Maekawa Hiroyuki Hamada 《Composite Structures》1995,32(1-4):635-640
Localized impact problems for composite structures have recently become important. In this study, some elastic wave velocities in 7-ply GFRP laminate with [02/903/02] ply orientation after low speed impact was investigated by using both experimental methods and finite element methods. For the finite element simulation, the quasi-three-dimensional model was used. Comparing the results, the validity for the application of this model to the dynamic problem was estimated. Moreover the quasi-three-dimensional model is applied to the GFRP plates with interlaminar delamination. The relationship between the elastic wave velocities and delaminated states is discussed. 相似文献
17.
N Yamamoto T Tamura Y Nishiwaki Y Kurita Y Kawakami S Abe T Nakabayashi S Suzuki T Matsuda I Hayashi T Takahashi N Saijo 《Canadian Metallurgical Quarterly》1997,3(7):1087-1092
We previously established a limited sampling model (LSM) for the area under the concentration versus time curve (AUC) of irinotecan (CPT-11). Using this LSM, we performed a pharmacokinetic-pharmacodynamic analysis of CPT-11 in a multicentric Phase II study for non-small cell lung cancer. Ten institutes participated in this study, 36 patients were registered, and 30 patients were evaluable for the pharmacokinetic-pharmacodynamic analysis. CPT-11 and etoposide were administered daily for three consecutive days, both at a dose of 60 mg/m2. Blood samples were obtained 4 and 8 h after infusion on days 1 and 3. When using the LSM, there is a significant possible source of error in the timing of these selected points. In this study, however, the sample timing error was small. Mean timing errors were 1.0-4.0 min at each point. The estimated CPT-11 AUCs were: Day 1 Day 2 Day 1 + 3 Mean +/- SD (mg.h/liter) 3.76+/-0.68 4.10+/-0.86 7.86+/-1.43 Range 2.01-5.03 2. 29-5.72 4.30-10.68 Max/min 2.50 2.45 2.48 High interpatient variability was observed in the AUC. The CPT-11 AUC correlated positively with the grade of emesis (P = 0.003) and the percent decreases in WBC count (P = 0.001) and absolute neutrophil count (P =0.0006), but it did not correlate with the grade of diarrhea or response. We concluded that the LSM was useful in estimating individual pharmacokinetic parameters in multicentric trials. 相似文献
18.
Rie Matsushima-Nishiwaki Yoshihiro Shidoji Shinji Nishiwaki Tetsuya Yamada Hisataka Moriwaki Yasutoshi Muto 《Lipids》1995,30(11):1029-1034
Microcystin-LR is a liver tumor promoter in the okadaic acid class, a group of potent inhibitors of protein phosphatases 1
and 2A. Because of inhibition of protein phosphatases, microcystin-LR induces hyperphosphorylation of cellular proteins, including
cytoskeletal proteins—cytokeratins 8 and 18—and causes morphological changes in mouse hepatocytes in primary culture. We studied
the effects of carotenoids to antagonize microcystin-LR-induced morphological changes in hepatocytes. β-Carotene (100 nM to
100 μM), suppressed the morphological changes induced by 100 nM microcystin-LR in a dose-dependent manner. Other carotenoids
tested exerted similar suppressive effects, although retinoids, such as all-trans retinol, all-trans retinoic acid, and 9-cis retinoic acid, were only weakly suppressive. The relative potency of the suppression correlated significantly with the number
of conjugated double bonds in thetrans configuration. β-Carotene strongly suppressed the hyperphosphorylation of cellular proteins induced by microcystin-LR without
significant changes in the basal phosphorylation level. Other antioxidants, such as α-tocopherol, did not protect the cells
against microcystin-LR. Taken together, the antagonistic effects of carotenoids against microcystin-LR are difficult to explain
by their antioxidant or provitamin A activities. Suppression of the hyperphosphorylation of cellular proteins may be a novel
mechanism by which carotenoids inhibit tumor promotion. 相似文献
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20.
Protein tyrosine phosphatase zeta (PTPzeta/RPTPbeta) is a receptor-like protein tyrosine phosphatase specifically expressed in the brain. Alternative splicing produces three isoforms of this molecule: PTPzeta-A, the full-length form of PTPzeta; PTPzeta-B, the short form of PTPzeta; and PTPzeta-S, an extracellular variant. Here, we identified all these isoforms, including PTPzeta-B, as chondroitin sulfate proteoglycans, and characterized their carbohydrate modification and expression profiles in the rat brain. The level of PTPzeta-A expression was maintained during the prenatal period and decreased rapidly after birth. PTPzeta-S was expressed in a similar manner, although the postnatal decrease was gradual. In contrast, relatively constant amounts of PTPzeta-B were observed from embryonic day 13 (E13) through adulthood. PTPzeta-A and -S were constantly expressed only as proteoglycans during development, but a substantial amount of PTPzeta-B was detected in a non-proteoglycan form at E13-15. Moreover, PTPzeta-B did not contain LeX, HNK-1 carbohydrate, or keratan sulfate, although PTPzeta-A and -S were generally modified with these carbohydrates. L cells transfected with PTPzeta-A and -B cDNAs expressed these proteins as enzymatically active chondroitin sulfate proteoglycans. The PTPzeta-A and -B in L cells showed essentially similar localizations in cell cortical structures on immunofluorescence microscopy, although immature or processed forms of PTPzeta-A were accumulated additively in intracellular patchy structures. These results show that the three isoforms of PTPzeta are differentially regulated during development, and that the extracellular deleted region in PTPzeta-B is important for determination of carbohydrate modification. 相似文献