Performance characteristics of novel mechanical foam breakers in a stirred tank reactor

Unlimited foam formation and insufficient foam collapse can have serious effects in an aerated system such as a fermentation process. Mechanical foam breakers are used in foam control to avoid the drawbacks associated with the use of chemical antifoams and defoaming agents. In this paper, two new foam breakers consisting of a two‐blade paddle with three slits, and a two‐blade paddle with 168 thin needles have been tested. They gave significantly reduced critical speeds and power consumption for foam control in a stirred vessel, compared with some conventional foam breakers. The effects of various parameters, namely the physical properties of the foaming solution, type of gas sparger, surfactant concentration, and foam‐breaker clearance above liquid level, have been investigated. The degree of difficulty of controlling dynamic foams generated continuously in a stirred vessel is found to be a function of the nature of the foam, ie its bubble size, its liquid holdup, and the degree of foamability of the system. © 1999 Society of Chemical Industry     

Estimation of diffusion and solubility coefficients for water and CO2 in reaction injection molded parts

The evolution of gases from Reaction Injection Molded (RIM) parts during painting causes “pinhole” surface defects, which result in scrap. The transport of gases plays a major role in this outgassing. The diffusion rates of CO₂ and water through reaction injection molded parts is measured in this work. Despite the presence of glassy hard domains and dispersed microbubbles of size <25 μm (nucleated parts), the diffusion showed Fickian characteristics, and diffusion coefficients were independent of the concentration of water and CO₂ in nucleated and non-nucleated RIM parts. The presence of microbubbles enhances diffusion, which could be predicted from the diffusion rate through the non-nucleated material by using a simplistic one-dimensional model. The diffusion coefficients of water and CO₂ follow an Arrhenius relationship. The solubility coefficients follow a van't Hoff relationship over a wide range of 20 to 150°C. Apart from predicting diffusion and solubility coefficients, for various RIM materials and processing conditions, the estimated parameters will be used to interpret the outgassing phenomenon in a subsequent paper.     

Doping Dependent In‐Plane and Cross‐Plane Thermoelectric Performance of Thin n‐Type Polymer P(NDI2OD‐T2) Films

Thermoelectric generators pose a promising approach in renewable energies as they can convert waste heat into electricity. In order to build high efficiency devices, suitable thermoelectric materials, both n‐ and p‐type, are needed. Here, the n‐type high‐mobility polymer poly[N,N′‐bis(2‐octyldodecyl)naphthalene‐1,4,5,8‐bis(dicarboximide)‐2,6‐diyl]‐alt‐5,5′‐(2,2′‐bithiophene) (P(NDI2OD‐T2)) is focused upon. Via solution doping with 4‐(1,3‐dimethyl‐2,3‐dihydro‐1H‐benzoimidazol‐2‐yl)‐N,N‐diphenylaniline (N‐DPBI), a maximum power factor of (1.84 ± 0.13) µW K^?2 m^?1 is achieved in an in‐plane geometry for 5 wt% dopant concentration. Additionally, UV–vis spectroscopy and grazing‐incidence wide‐angle X‐ray scattering are applied to elucidate the mechanisms of the doping process and to explain the discrepancy in thermoelectric performance depending on the charge carriers being either transported in‐plane or cross‐plane. Morphological changes are found such that the crystallites, built‐up by extended polymer chains interacting via lamellar and π–π stacking, re‐arrange from face‐ to edge‐on orientation upon doping. At high doping concentrations, dopant molecules disturb the crystallinity of the polymer, hindering charge transport and leading to a decreased power factor at high dopant concentrations. These observations explain why an intermediate doping concentration of N‐DPBI leads to an optimized thermoelectric performance of P(NDI2OD‐T2) in an in‐plane geometry as compared to the cross‐plane case.     

CHELM: Convex Hull based Extreme Learning Machine for salient object detection

Multimedia Tools and Applications - Machine learning based saliency detection methods have achieved better performance than traditional methods. Here, we propose a machine learning based method...     

Upconversion-based receivers for quantum hacking-resistant quantum key distribution

We propose a novel upconversion (sum frequency generation)-based quantum-optical system design that can be employed as a receiver (Bob) in practical quantum key distribution systems. The pump governing the upconversion process is produced and utilized inside the physical receiver, making its access or control unrealistic for an external adversary (Eve). This pump facilitates several properties which permit Bob to define and control the modes that can participate in the quantum measurement. Furthermore, by manipulating and monitoring the characteristics of the pump pulses, Bob can detect a wide range of quantum hacking attacks launched by Eve.     

Experimental investigation of surface topography in photochemical machining of Inconel 718

Surface topography is one of the important aspects of micro-components manufacturing. Photochemical machining (PCM) is the most commonly used method in the low-cost micro-manufacturing process. The present investigation focused on the study of the effect of process parameters on the surface topography in PCM of Inconel 718 of two different grain sizes using ferric chloride (FeCl₃). For this work, the input parameters considered are concentration, time and temperature of the etchant. The temperature of the etchant was found to be the most dominant parameter in the PCM of Inconel 718. Moreover, in this study, the effect of grain size of samples on surface roughness was considered. The average increase in surface roughness is 1.227 times due to variation in grain size from 59?µm to 42?µm.     

Angular dose variations from 320 kV rod pinch diode flash X-ray experiments on the modified Kali-1000 Pulsed Power System

This paper highlights the angular distribution of radiation dose emitted from a rod-pinch diode. The typical RP diode employed used a small diameter (1–2 mm) anode rod extended through a cathode aperture (5–8 mm). The diode chamber is maintained at 2 × 10^–5 Torr vacuum by a rotary backed diffusion pump. Experiments performed on a modified Kali-1000 Pulsed Power System (300 kV, 30 kA, 100 ns) were aimed at optimizing the source by maximizing the figure of merit (dose at 1 m in rad/spot diameter² in mm²) with minimizing of the diode impedance. The typical electron beam parameters used in the experiments are 240–320 kV, 6.5–27.5 kA, 100 ns, with a few hundreds of kA/cm² current density. The radiation emitted from a rod-pinch diode is measured using thermoluminescence dosimeters at an angular interval of 15° on either side of the rod in horizontal and vertical plane with different aspects ratio ranging from 2.5 to 10.0. Experimentally found that the radiation dose produced from the rod pinch diode configuration is maximum in the axial direction and decreases with angular variation on either side of the axis in horizontal and vertical planes, which indicates the directivity of the source. Maximum radiation dose at 1 m distance on the axial line is ranging from 42 to 307 mR.     

Numerical investigation of semiempirical relations representing the local Nusselt number magnitude of a pin fin heat sink

Heat transfer augmentation study using air jet impingement has recently attained great interest toward electronic packaging systems and material processing industries. The present study aims at developing a nondimensional semiempirical relation, which represents the cooling rate (Nu) in terms of different geometric and impinging parameters. The spacing of the fin (S/d_p) and the fin heights (H/d_p) are the geometric parameters, while the impinging Reynolds number (Re) and nozzle‐target spacing (Z/d) are the impinging parameters. During the plot of the Nusselt profile, three vital secondary peaks are observed due to local turbulence of air over the heat sink. To incorporate this nonlinear behavior of the Nusselt profile in developing nondimensional empirical relations, the Nusselt profiles are divided into different regions of secondary rise and fall. Four different sets of the semiempirical relation using regression analysis are proposed for Z/d ≤ 6, H/d_p ≤ 4.8 with S/d_p ≤ 1.58, S/d_p > 1.58 and for Z/d > 6, H/d_p > 4.8 with S/d_p ≤ 1.58, S/d_p > 1.58. These empirical relations benefit the evaluation of the cooling rate (Nu) without any experimentation or simulation.     

A diamino based resin modified silica composite for the selective recovery of tungsten from wastewater

A new adsorbent was developed by synthesizing 1,8‐diaminonaphthalene formaldehyde resin (DANFR) and coating it over the surface of silica gels. The silica composite was then treated with HCl for the activation of binding sites (?NH₃⁺Cl^?) on its surface. The structure of DANFR and its coating over the silanols were thoroughly characterized. Further, the adsorbent was applied to remove tungsten (W) from printed circuit board recycling unit wastewater that contained various co‐metal ions such as Na⁺, K⁺, Ca²⁺, Mg²⁺, Pb²⁺, NH₄⁺, Zn²⁺, Cu²⁺ and Mn²⁺. The selective removal was achieved due to the anion exchange mechanism of Cl^? with W(VI) while other cations get repelled from the surface (?NH₃⁺) of the DANFR‐silica composite. X‐ray photoelectron spectroscopy studies, Raman spectra and overlay chromatograms of ion chromatography demonstrated selective separation of WO₄^2? species from the wastewater. A removal capacity of 55.32 mg g^?1 for W(VI) was achieved from the wastewater within 45 min of reaction (pH ca 6.0). Simultaneous treatment with neat aqueous solution of W brings out 63.27 mg g^?1 of W(VI) removal. Finally, recovery of WO₄^2? ions and regeneration of the adsorbent were carried out by using alkaline solution which demonstrated successful desorption, as investigated by using ion chromatography. © 2016 Society of Chemical Industry