Wear of graphite anodes during electrolysis of add sulphate solutions

Graphite electrodes were prepared by mixing calcined coke and coal tar pitch. They were pressed under 250 kg cm^–2 and heat treated up to 2800° C. Rectangles measuring 70 mm x 40 mm x 8 mm were anodically polarized under galvanostatic and potentiostatic conditions. Electrolyses were conducted at 10–50 mA cm^–2 for periods ranging from 10–120 hours in Na₂SO₄ solutions acidified with sulphuric acid to various pH values. The wear of graphite anodes increased with decreasing bath temperature, increasing acid concentration, decreasing pH of the electrolyte and increasing current density. A model is suggested which assumes that corrosion takes place via the formation of a lamellar crystal compound with the formula (C ₈ ⁰ O)(OH)₃HSO ₄ ^– ·2H₂SO₄.The compound is unstable at higher temperatures when corrosion is effected by oxidation of graphite by atomic oxygen. The formation of the carbon ions was found to be a necessary precondition for the formation of the complex.     

Effect of scraped-surface tube cooler temperatures on the physical properties of palm oil margarine

The effects of scraped-surface tube cooler temperatures on the isothermal solid fat content (SFC) of palm oil margarine during processing and on margarine consistency (yield value, g/cm²), SFC, and polymorphic changes in storage were studied. SFC was measured in the mixing tank after leaving the tube cooler and the pin worker. The SFC at the tube cooler exit was proportional to the amount of cooling; a higher SFC was produced by more extreme cooling treatment. The SFC of all margarines were reduced in the pin worker, and the reduction was related to the initial SFC profile of palm oil. Margarine samples were stored at 28°C for 28 d and tested daily. Margarine processed at 25°C in the tube cooler had the highest consistency and the least change in SFC, but by the second week crystals had transformed into the β form. Uniform product consistency and SFC were observed in margarines processed at 20 and 15°C. These margarines retained the β′ crystal form for 3 and 4 wk, respectively. The best palm oil margarine was obtained with a tube cooler temperature of 15°C and a residence time of 1.8 min.     

Progress and challenges in sustainability,compatibility, and production of eco-composites: A state-of-art review

Owing to economic and environmental benefits, new generations of materials/commodities follow “from waste to wealth” strategy. Recently, there has been a huge upsurge in research on the development of eco-composites using recycled plastic polymers and agro-residues because the eco-composites satisfy the stringent environment regulations and are cost-effective. Herein, we present a detailed review on the potential use of several types of natural fillers as an efficient reinforcement for recycled plastic polymers. In particular, the characterization of different categories of eco-composites according to their morphological, physical, thermal, and mechanical properties is extensively reviewed and their results are analyzed, compared, and highlighted. Furthermore, a framework to produce functional eco-composites, which includes functionalization of ingredients, critical issues on microstructural parameters, processing, and fabrication methods, is outlined and supported with sufficient data from the literature. Finally, the review outlines the emerging challenges and future prospects of eco-composites to be addressed by interested researchers to bridge the gap between research and commercialization of such a class of material. Overall, the acquired knowledge will guide researchers, scientists, and manufacturers to plan, select, and develop various forms of eco-composites with enhanced properties and optimized production processes.     

What can possibly go wrong? Anticipatory work in space operations

This paper explores how different forms of anticipatory work contribute to reliability in high-risk space operations. It is based on ethnographic field work, participant observation and interviews supplemented with video recordings from a control room responsible for operating a microgravity greenhouse at the International Space Station (ISS). Drawing on examples from different stages of a biological experiment on the ISS, we demonstrate how engineers, researchers and technicians work to anticipate and proactively mitigate possible problems. Space research is expensive and risky. The experiments are planned over the course of many years by a globally distributed network of organizations. Owing to the inaccessibility of the ISS, every trivial detail that could possibly cause a problem is subject to scrutiny. We discuss what we label anticipatory work: practices constituted of an entanglement of cognitive, social and technical elements involved in anticipating and proactively mitigating everything that might go wrong. We show how the nature of anticipatory work changes between planning and the operational phases of an experiment. In the planning phase, operators inscribe their anticipation into technology and procedures. In the operational phase, we show how troubleshooting involves the ability to look ahead in the evolving temporal trajectory of the ISS operations and to juggle pre-planned fixes along these trajectories. A key objective of this paper is to illustrate how anticipation is shared between humans and different forms of technology. Moreover, it illustrates the importance of including considerations of temporality in safety and reliability research.     

Buoyancy convection in a cavity with mutually orthogonal heated plates

Buoyancy driven convection in a square cavity induced by two mutually orthogonal arbitrarily placed heated thin plates is studied numerically under isothermal and isoflux boundary conditions. The flow is assumed to be two-dimensional. The coupled governing equations were solved by the finite difference method using the Alternating Direction Implicit technique and Successive Over Relaxation method. The steady state results are depicted in terms of streamline and isotherm plots. It is found that the resulting convection pattern is stronger for the isothermal boundary condition. A better overall heat transfer can be achieved by placing one of the plates far away from the center of the cavity for isothermal boundary condition and near the center of the cavity for isoflux boundary condition.     

Thermal Investigation for Solid Rocket Motor Nozzle Inserts Material

A time-resolved numerical computational approach, involving the combustion of double-base propellant is performed on thermal protection material for SRM nozzle. An implicit Navier-Stokes Solver is selected to simulate two-dimensional axial-symmetric unsteady turbulent flow of compressible fluid. The governing equations are discredited by using the finite Volume method. S-A turbulence model is employed. CFD scheme is implemented to investigate the temperature distribution causes at nozzle throat inserts comp...     

Optimal Machine Learning Enabled Performance Monitoring for Learning Management Systems

Learning Management System (LMS) is an application software that is used in automation, delivery, administration, tracking, and reporting of courses and programs in educational sector. The LMS which exploits machine learning (ML) has the ability of accessing user data and exploit it for improving the learning experience. The recently developed artificial intelligence (AI) and ML models helps to accomplish effective performance monitoring for LMS. Among the different processes involved in ML based LMS, feature selection and classification processes find beneficial. In this motivation, this study introduces Glowworm-based Feature Selection with Machine Learning Enabled Performance Monitoring (GSO-MFWELM) technique for LMS. The key objective of the proposed GSO-MFWELM technique is to effectually monitor the performance in LMS. The proposed GSO-MFWELM technique involves GSO-based feature selection technique to select the optimal features. Besides, Weighted Extreme Learning Machine (WELM) model is applied for classification process whereas the parameters involved in WELM model are optimally fine-tuned with the help of Mayfly Optimization (MFO) algorithm. The design of GSO and MFO techniques result in reduced computation complexity and improved classification performance. The presented GSO-MFWELM technique was validated for its performance against benchmark dataset and the results were inspected under several aspects. The simulation results established the supremacy of GSO-MFWELM technique over recent approaches with the maximum classification accuracy of 0.9589.     

An efficient numerical algorithm for the study of time fractional Tricomi and Keldysh type equations

Engineering with Computers - This work addresses a hybrid scheme for the numerical solutions of time fractional Tricomi and Keldysh type equations. In proposed methodology, Haar wavelets are used...