Removal of boron from ceramic industry wastewater by adsorption-flocculation mechanism using palm oil mill boiler (POMB) bottom ash and polymer

Boron is extensively used in the ceramic industry for enhancing mechanical strength of the tiles. The discharge of boron containing wastewater to the environment causes severe pollution problems. Boron is also dangerous for human consumption and causes organisms' reproductive impediments if the safe intake level is exceeded. Current methods to remove boron include ion-exchange, membrane filtration, precipitation-coagulation, biological and chemical treatment. These methods are costly to remove boron from the wastewater and hence infeasible for industrial wastewater treatment. In the present research, adsorption-flocculation mechanism is proposed for boron removal from ceramic wastewater by using Palm Oil Mill Boiler (POMB) bottom ash and long chain polymer or flocculant. Ceramic wastewater is turbid and milky in color which contains 15 mg/L of boron and 2000 mg/L of suspended solids. The optimum operating conditions for boron adsorption on POMB bottom ash and flocculation using polymer were investigated in the present research. Adsorption isotherm of boron on bottom ash was also investigated to evaluate the adsorption capacity. Adsorption isotherm modeling was conducted based on Langmuir and Freundlich isotherms. The results show that coarse POMB bottom ash with particle size larger than 2 mm is a suitable adsorbent where boron is removed up to 80% under the optimum conditions (pH = 8.0, dosage = 40 g bottom ash/300 ml wastewater, residence time = 1 h). The results also show that KP 1200 B cationic polymer is effective in flocculating the suspended solids while AP 120 C anionic polymer is effective in flocculating the bottom ash. The combined cationic and anionic polymers are able to clarify the ceramic wastewater under the optimum conditions (dosage of KP 1200 B cationic polymer = 100 mg/L, dosage of AP 120 C anionic polymer = 50 mg/L, mixing speed = 200 rpm). Under the optimum operating conditions, the boron and suspended solids concentration of the treated wastewater were reduced to 3 mg/L and 5 mg/L respectively, satisfying the discharge requirement by Malaysia Department of Environment (DOE). The modeling study shows that the adsorption isotherm of boron onto POMB bottom ash conformed to the Freundlich Isotherm. The proposed method is suitable for boron removal in ceramic wastewater especially in regions where POMB bottom ash is abundant.     

准静态轴向和侧向挤压下对径向波纹管的分析

介绍了波纹几何形状对破坏性能、能量吸收、失效机理和玻璃纤维方格布／环氧复合材料管失效模式的影响。对承受轴向和侧向压力的3个具有不同几何形状的复合材料管进行试验研究。同时对相同受力条件下的径向波纹复合管、圆柱型复合管、圆柱管环绕的波纹管进行试验,以了解波纹几何形状的影响。结果表明,轴向挤压中波纹几何形状会显著影响管的承载能力。然而,侧向挤压中并没有发现波纹几何形状的影响。试验中绘制了荷载一位移曲线,因此可以对各种不同几何形状的构件进行清晰的对比。研究同时发现,径向波纹可以稳定并有效地吸收能量。     

Enhancement of stack ventilation in hot and humid climate using a combination of roof solar collector and vertical stack

In the hot and humid climate, stack ventilation is inefficient due to small temperature difference between the inside and outside of naturally ventilated buildings. Hence, solar induced ventilation is a feasible alternative in enhancing the stack ventilation. This paper aims to investigate the effectiveness of a proposed solar induced ventilation strategy, which combines a roof solar collector and a vertical stack, in enhancing the stack ventilation performance in the hot and humid climate. The methodology selected for the investigation is physical experimental modelling which was carried out in the actual environment. The results are presented and discussed in terms of two performance variables: air temperature and air velocity. The findings indicate that the proposed strategy is able to enhance the stack ventilation, both in semi-clear sky and overcast sky conditions. The highest air temperature difference between the air inside the stack and the ambient air (T_i−T_o) is achieved in the semi-clear sky condition, which is about 9.9 °C (45.8 °C–35.9 °C). Meanwhile, in the overcast sky condition, the highest air temperature difference (T_i−T_o) is 6.2 °C (39.3 °C–33.1 °C). The experimental results also indicate good agreement with the theoretical results for the glass temperature, the air temperature in the roof solar collector’s channel and the absorber temperature. The findings also show that wind has significant effect to the induced air velocity by the proposed strategy.     

Electronic properties of polyaniline doped with dodecylbenzenesulphonic acid (PANI-DBSA) and poly(methyl methacrylate) (PMMA) blends in the presence of hydroquinone

Films of polyaniline doped with dodecylbenzenesulphonic acid (DBSA) and poly(methyl methacrylate) (PMMA) blends were studied with and without compatibilising agent “hydroquinone”. Hydroquinone was used to maximize solubility and to make it compatible with polymethylmethacrylate (PMMA) to get uniform and homogenous films on indium tin oxide ITO coated glass. Current density measurement as a function of voltage (J–V) and capacitance voltage (C–V) measurements at different temperature were carried out. The observed J–V and C–V characteristics can be satisfactorily fitted using the modified Schottky equations. The junction parameters were strongly influenced by hydroquinone. From C–V characteristics, the built-in voltage and charge carriers concentration were also calculated and discussed.     

Voltage-controlled double-resonance quartz oscillator using variable-capacitance diode

In this work, we present a variable-frequency quartz crystal oscillator that is able to oscillate at LC resonance under frequency locking of a quartz crystal resonance, with the frequency tuning realized by variable-capacitance diodes. This circuit shows a steep transition between LC oscillation modes to quartz crystal double-resonance, which shows a characteristic change in the oscillation frequency. Control voltage of this diode is precisely adjusted from the low side to higher values and conversely in the vicinity of the oscillation mode transition. The transition of the oscillation modes is experimentally demonstrated and compared with an algebraic analysis.     

Eco‐friendly synthesis of silver nanoparticles and its larvicidal property against fourth instar larvae of Aedes aegypti

In this study, larvicidal activity of silver nanoparticles (AgNPs) synthesised using apple extract against fourth instar larvae of Aedes aegypti was determined. As a result, the AgNPs showed moderate larvicidal effects against Ae. aegypti larvae (LC₅₀  = 15.76 ppm and LC₉₀  = 27.7 ppm). In addition, comparison of larvicidal activity performance of AgNPs at high concentration prepared using two different methods showed that Ae. aegypti larvae was fully eliminated within the duration of 2.5 h. From X‐ray diffraction, the AgNP crystallites were found to exhibit face centred cubic structure. The average size of these AgNPs as estimated by particle size distribution was in the range of 50–120 nm. The absorption maxima of the synthesised Ag showed characteristic Ag surface plasmon resonance peak. This green synthesis provides an economic, eco‐friendly and clean synthesis route to Ag.Inspec keywords: silver, nanofabrication, X‐ray diffraction, zoology, particle size, nanoparticles, biomedical materials, nanomedicineOther keywords: time 2.5 h, size 50 nm to 120 nm, silver nanoparticle, larvicidal property, instar larvae, Aedes aegypti, larvicidal effect, larvicidal activity performance, X‐ray diffraction, nanoparticle particle size distribution, absorption maxima, silver surface plasmon resonance peak     

PIV investigations on particle velocity distribution in uniform swirling regime of fluidization

In this study, hydrodynamics of spherical particles in uniform swirling regime of a fluidized bed were investigated using MATLAB supported particle imaging velocimetry (PIV). A least investigated mesh-type distributor was used to fluidize the bed particles, at different air entry angles, for future applications in coating and granulation industry. A quarter of the bed was photographed using high speed imaging technique and the respective velocity fields of the swirling particles were produced using PIV technique. The Gaussian distribution of the particle velocity profiles was predicted at low superficial air velocity; particles near the border of the bed showed relatively low velocity than that swirled in the middle of the test section. However, at high superficial velocity, the particles near the central cone moved with velocity comparable to the particle velocity in the middle of the test section. Contrarily, the particles in the vicinity of the outer bed-wall maintained their steady state motion at all superficial air velocities. The average particle velocity experienced monotonic increase for more angular air intake. The magnitude of the particle velocity reduced by 6.35% for each \(3^{\circ }\) increment in the air entry angle.     

Ba-M+Y (Ba4−XCo2+XFe36O60) complex hexaferrite: structural,electrical, magnetic,and enhanced microwave absorbing properties over 8–18 GHz frequency

Journal of Materials Science: Materials in Electronics - Hexaferrites are a class of materials that have practical applications as microwave absorbing materials (MAMs) and radar absorbing materials...     

Behaviour of sand–clay mixtures for road pavement subgrade

Materials forming sand grains and colluvial soil deposits have a distinct structure, consisting of a composite matrix of coarse and fine soil grains. The influence of sand grains content on the behaviour of sand–clay mixtures was investigated by a series of intensive laboratory experiments. The California bearing ratio (CBR), unconfined compression strength (UCS) and compaction tests were carried out on various contents of sand and clay mixtures. The sand–clay mixtures were prepared with sand contents of 0, 10, 20, 30, 40, and 50% by weight. The laboratory tests on these mixtures have indicated that their behaviour will depend on the relative concentration of the sand and clay samples. The results of the tests showed a decrease in the UCS, and an increase the CBR values with an increase in the amount of sand. An increase in dry unit weight and a decrease in respective moisture content by an increase in the amount of sand were observed in the compaction tests.