WorkSim: A Calibrated Agent-Based Model of the Labor Market Accounting for Workers’ Stocks and Gross Flows

This paper presents an agent-based model of the labor market. It simulates the market in the recent period at the aggregate level and at the level of the principal categories of labor, on the basis of the decisions of heterogeneous agents, firms and individuals, who interact. These decisions rely on individual computations of profits and utilities, although rationality is bounded in such a complex environment. The theoretical structure that underlies the decisions is the search concept. We apply this framework to the case of France in 2011. The model is at a scale of 1/4700. It is fairly detailed on the institutions of the labor market that constrain the agents’ decisions. Finally it is calibrated by a powerful algorithm to reproduce a large number of variables of interest. The calibrated model presents a consistent accounting system of the gross flows of the individuals between the main states, employment, distinguishing open ended contracts and fixed duration contracts, unemployment and inactivity. The simulation of the gross flows accounts enables us to analyze the patterns of mobility in a way that the observed statistics on gross flows, which are partial, cannot do. The model then characterizes the nature of the labor market under study, reproducing the high proportion of the fixed duration contracts in the hiring flows, and it points to a dualism of the French labor market.     

High‐Temperature Creep Behavior of SiOC Glass‐Ceramics: Influence of Network Carbon Versus Segregated Carbon

Three silicon oxycarbide samples with different carbon contents are analyzed in the present study with respect to their high‐temperature creep behavior. The tests were performed in compression at 1100°C, 1200°C, and 1300°C; in this temperature range the mechanism of creep relies on viscoelastic flow within the samples and has been modeled with the Jeffreys viscoelastic model. After the release of the applied mechanical stress, a viscoelastic recovery behavior was observed in all samples. The creep behavior of the investigated samples indicates two rheological contributions in SiOC: (i) a high viscous answer, coming from the silica‐rich network, and (ii) an elastic response from the segregated carbon phase within the samples. Furthermore, two distinct effects of the carbon phase on the HT creep behavior of SiOC were identified and are discussed in the present paper: the effect of the carbon presence within the SiOC network (the “carbidic” carbon), which induces a significant increase in the viscosity and a strong decrease in the activation energy for creep, as compared to vitreous silica; and the influence of the segregated carbon phase (the “free” carbon), which has been shown to affect the viscosity and the activation energy of creep and dominates the creep behavior in phase‐separated silicon oxycarbides.     

The impact of strain-induced crystallization on strain during mechanical cycling of cross-linked natural rubber

The improvement of X-ray diffraction techniques since the last ten years allowed a renewal of the study of strain-induced crystallization in natural rubber. In particular real-time measurements are now commonplace. However, due to experimental difficulties, the exploitation of the X-ray data as far as the strain state of the remaining molten fraction is concerned has been left aside. Indeed the knowledge of the local extension of the molten chains is crucial for understanding the peculiar stress behavior observed during the crystallization process. This paper presents a systematic study of this parameter during mechanical cycling performed at various temperatures. It is shown that crystallization limits the amplitude of strain endured by the molten fraction during traction. This process of strain regulation may be one explanation for the protective effect of crystallization against tearing. A precise evaluation of the contribution of the molten fraction to the retraction force during mechanical cycling is made. The role of crystallites as nanofillers may be quantified this way.     

Interpolation of rotation and motion

In Cosserat solids such as shear deformable beams and shells, the displacement and rotation fields are independent. The finite element implementation of these structural components within the framework of flexible multibody dynamics requires the interpolation of rotation and motion fields. In general, the interpolation process does not preserve fundamental properties of the interpolated field. For instance, interpolation of an orthogonal rotation tensor does not yield an orthogonal tensor, and furthermore, does not preserve the tensorial nature of the rotation field. Consequently, many researchers have been reluctant to apply the classical interpolation tools used in finite element procedures to interpolate these fields. This paper presents a systematic study of interpolation algorithms for rotation and motion. All the algorithms presented here preserve the fundamental properties of the interpolated rotation and motion fields, and furthermore, preserve their tensorial nature. It is also shown that the interpolation of rotation and motion is as accurate as the interpolation of displacement, a widely accepted tool in the finite element method. The algorithms presented in this paper provide interpolation tools for rotation and motion that are accurate, easy to implement, and physically meaningful.     

Shape‐Memory Topographies on Nickel–Titanium Alloys Trained by Embossing and Pulse Electrochemical Machining

The two‐way shape‐memory effect (TWSME) in Nickel–titanium (NiTi) alloys is of interest for applications in aerospace, biomedicine, and microengineering due to its reversible shape recovery. In this study, the authors demonstrate two approaches to obtain switchable surface structures using the TWSME. Samples are structured using two surface geometries by either cold embossing, or pulse electrochemical machining (PECM). After planarization, a change from optically smooth to structured and vice versa is observed. The switch is induced through heating and cooling the sample above and below the phase transformation temperature. The protrusions reflect the pattern applied by the two processes. Both methods are promising for preparation of switchable metallic surfaces on larger areas.     

Solution homopolymerizations of n-butyl acrylate and styrene mediated using 2,2,5-trimethyl-4-tert-butyl-3-azahexane-3-oxyl (TITNO)

Use of Styryl-TITNO (the styrene alkoxyamine of 2,2,5-trimethyl-4-tert-butyl-3-azahexane-3-oxyl) as mediator for nitroxide-mediated polymerization (NMP) of n-butyl acrylate (BA) and styrene has been investigated at temperatures ≤110 °C. Very good control of molecular weight and molecular weight dispersity with no measurable loss of active chains, and no evidence of tails in the molecular weight distribution as conversion increases, was observed at 90 °C for BA and at 70 °C for styrene. The alkoxyamine dissociation equilibrium constant values determined for polyBA-TITNO (8.5 × 10⁻¹¹ mol L⁻¹ at 90 °C) and polystyrene-TITNO (3.1 × 10⁻⁹ mol L⁻¹ at 70 °C) are consistent with those required for control when using more established nitroxides that require higher temperatures to achieve these values. The lower optimum polymerization temperatures with Styryl-TITNO as mediator provide new opportunities for NMP and are especially significant for styrene since this appears to eliminate completely the complications from thermal initiation.     

Complementation of rational sets on scattered linear orderings of finite rank

In a preceding paper [V. Bruyère, O. Carton, Automata on linear orderings, in: J. Sgall, A. Pultr, P. Kolman (Eds.), MFCS’2001, in: Lect. Notes in Comput. Sci., vol. 2136, 2001, pp. 236–247. iGM report 2001-12], automata have been introduced for words indexed by linear orderings. These automata are a generalization of automata for finite, infinite, bi-infinite, and even transfinite words studied by Büchi. Kleene’s theorem has been generalized to these words. We show that deterministic automata do not have the same expressive power. Despite this negative result, we prove that rational sets of words of finite ranks are closed under complementation.