Pilot-scale evaluation of ozone and biological activated carbon for trace organic contaminant mitigation and disinfection

In an effort to validate the use of ozone for contaminant oxidation and disinfection in water reclamation, extensive pilot testing was performed with ozone/H₂O₂ and biological activated carbon (BAC) at the Reno-Stead Water Reclamation Facility in Reno, Nevada. Three sets of samples were collected over a five-month period of continuous operation, and these samples were analyzed for a suite of trace organic contaminants (TOrCs), total estrogenicity, and several microbial surrogates, including the bacteriophage MS2, total and fecal coliforms, and Bacillus spores. Based on the high degree of microbial inactivation and contaminant destruction, this treatment train appears to be a viable alternative to the standard indirect potable reuse (IPR) configuration (i.e., membrane filtration, reverse osmosis, UV/H₂O₂, and aquifer injection), particularly for inland applications where brine disposal is an issue. Several issues, including regrowth of coliform bacteria in the BAC process, must be addressed prior to full-scale implementation.     

The impact of roasting on the ochratoxin A content of coffee

Roasting coffee led to a drop in the ochratoxin A (OTA) concentration, as measured by the reference method, especially for dark type roasts. The way the beverage was prepared also affected the OTA content, which could paradoxically be higher than that of the initial roasted coffee. Assays on the thermal stability of pure OTA showed that it ought to be found in larger quantities in roasted coffee. This suggested that OTA was masked by reactions with the substrate during roasting. The absence of OTA in green coffee is therefore the best guarantee of safety.     

ESR studies of free radicals in photo-initiated graft polymerization reactions with cotton cellulose

Electron spin resonance (ESR) spectra of free-radical intermediates formed during photo-initiated graft polymerization reactions of acrylamide, methacrylamide, and diacetone acrylamide onto purified cotton cellulose were recorded. Purified cellulose was saturated with aqueous solutions of the vinyl monomers (0.5M) and then photolyzed under nitrogen by near-ultraviolet light (3100–4100 Å, peak near 3500 Å) at ?196° and 40°C. Other samples of cellulose were saturated with aqueous solutions of the monomers, dried, and then photolyzed at 40°C. In the absence of cellulose, either poorly resolved or no free-radical spectra were generated on photolysis of the monomers. Photolysis of dried cellulose at 40°C and wet cellulose at ?196°C initiated formation of a cellulosic radical that generated a singlet spectrum. Photolysis of wet cellulose at 40°C generated no ESR detectable radical; however, photolysis of wet cellulose that contained monomer at 40°C generated poorly resolved spectra. The ESR spectra of the propagating copolymer radicals recorded were poly(acrylamide), three lines; poly(methacrylamide), five lines; and poly(diacetone acrylamide), two lines (doublet).     

Electron spin resonance studies of interactions of ammonia,copper, and cupriammonia with cellulose

The electron spin resonance spectra (ESR) of complexes of copper with fibrous cotton cellulose under various experimental conditions were determined. Cupric ions dissolved in solutions of strong bases, such as concentrated ammonium hydroxide, sodium hydroxide, and potassium hydroxide, formed complexes with fibrous cotton cellulose. These complexes had paramagnetic resonance properties and generated characteristic ESR spectra. Cupric ions dissolved in solutions of highly ionized neutral salts, such as sodium chloride, formed complexes with cellulose. These complexes also generated the same characteristic ESR spectra as the complexes formed in solutions of strong base. The reaction between cupric ions and cellulose was evidently very rapid and reversible. When the concentration of ammonia was decreased in, or ammonia was removed from, the cupric ion–ammonium hydroxide–cellulose complexes, the paramagnetic resonance properties of the complex were decreased or lost. Similar results were received when potassium hydroxide was removed from the complexes. The compositions of the complexes evidently are variable, that is, under different experimental conditions the relative intensities of the lines of the ESR spectra of the complexes varied, although the hyperfine splittings of the lines were constant. It was concluded that reactions of cupric ions to form complexes with adjacent hydroxyl groups on the cellulose molecule depended on an optimum spatial arrangement of the hydroxyl groups, that is, distance between the groups. Evidently, wetting of cotton cellulosic fibers with solutions of strong bases or neutral salt allowed rotation about the C₂–C₃ bond to yield this optimum arrangement. When the base or salt was removed, rotation occurred to give less favorable positions of the hydroxyl groups for complexing with cupric ions.     

Molybdenum-catalyzed asymmetric allylic alkylations

The highly regio- and enantioselective molybdenum-catalyzed allylic alkylation reaction has become a powerful synthetic tool during the past few years. This Account describes the achievements gained so far in the area, with special attention directed to the different chiral ligands that have been used for inducing chirality in the products, the range of allylic substrates and nucleophiles employed, mechanistic studies, and applications of the reaction in asymmetric syntheses.     

Bilinear Control for Three-Phase Microgrids: A Proportional-Integral Passivity-Based Design

Abstract

A bilinear PI control based on passivity theory for the adequate integration of distributed energy resources (DERs) in ac microgrids is presented in this paper. DERs are integrated into the grid by voltage source converters (VSC), the most common and suitable technology for this type of application. The proposed control guarantees asymptotically stable operation for the dynamical system under closed-loop operating scenarios via Hamiltonian and Lyapunov formulations. ZP load models and π-model of the transmission lines are considered in the stability analysis of the microgrid. Conventional PI control is also implemented for comparative purposes. Simulation results in Matlab/Simulink demonstrate the effectiveness and stability of the proposed control’s performance in a radial microgrid composed of a photovoltaic generator, a supercapacitor energy storage (SCES) system and unbalanced loads.     

An online optimum voltage estimation and real‐time MPP tracking for a PV system

In this paper, a photovoltaic system topology incorporating a new maximum power point tracking (MPPT) controller method is presented. This method uses an autotuning estimator and a PI controller to make the system work in the maximum power point. The controller is formulated based on the bijectivity in the photovoltaic generator characteristic; therefore, if the optimal voltage is reached, this means that the maximum of power is obtained. The proposed MPPT algorithm is implemented on a dSpace DS1104 controller board. In order to demonstrate the efficiency of the proposed algorithm in real time, an experimental setup using a boost converter connected to a resistive load is successfully implemented and studied. The obtained experimental results prove the validity of the proposed MPPT algorithm.     

Stability of Local On‐Ramp Metering Control Laws

A framework for stability analysis of local on‐ramp metering control strategies based on the cell transmission model is presented. Within this framework, it is possible to formulate Lyapunov and input‐state stability results for on‐ramp metering control strategies in an open section of highway with on‐ramps. Using this analysis, recommendations for the design of on‐ramp metering control laws set points are derived. Two examples on the use of such analysis are presented. One deals with the stability analysis of a local on‐ramp metering control law and the other with the design of a disturbance observer that, used in combination with the local on‐ramp metering control law, provides a more robust response to traffic regulation. Simulation results are included that confirm the possibility of using this framework to test the impact of local on‐ramp metering control strategies.     

Using Scrum to guide the execution of software process improvement in small organizations

For software process improvement - SPI - there are few small organizations using models that guide the management and deployment of their improvement initiatives. This is largely because a lot of these models do not consider the special characteristics of small businesses, nor the appropriate strategies for deploying an SPI initiative in this type of organization. It should also be noted that the models which direct improvement implementation for small settings do not present an explicit process with which to organize and guide the internal work of the employees involved in the implementation of the improvement opportunities. In this paper we propose a lightweight process, which takes into account appropriate strategies for this type of organization. Our proposal, known as a “Lightweight process to incorporate improvements”, uses the philosophy of the Scrum agile method, aiming to give detailed guidelines for supporting the management and performance of the incorporation of improvement opportunities within processes and their putting into practice in small companies. We have applied the proposed process in two small companies by means of the case study research method, and from the initial results, we have observed that it is indeed suitable for small businesses.