Oxidation stability and compositional characteristics of oils from microwave roasted pumpkin seeds during thermal oxidation

The oxidative stability and compositional characteristics of the pumpkin seed oil (PSO) exposed to microwaves were studied during heating at 170°C. The oxidative indices such as free fatty acid (FFA), peroxide value (PV), p-anisidine value (p-AV), TOTOX, specific extinctions and thiobarbituric acid (TBA) value of oils were significantly increased, and the increments were found to be significantly higher (P < 0.05) in unroasted seed oil as compared to roasted seed oil. The relative contents of polyunsaturated fatty acids (PUFAs) were decreased to 84.7%, and saturated fatty acids (SFAs) were increased to 119.5% in unroasted sample, after 9 h of heating. On the other hand, in 12 min roasted samples, the relative contents of PUFAs were decreased to 97.0%, and SFAs were increased to 102.6% after 9 h of heating. The triacylglycerol species LLL and OLL levels were decreased as a consequence of increased heating time, and the reduction tended to be significantly higher in unroasted samples as compared to roasted ones. The oxidation products formed were also investigated by FTIR. The present results indicated that microwave roasting of pumpkin seeds markedly enhanced the oxidative stability of the oils during heating.     

Structural Control of NiO–YSZ/LSCF–YSZ Dual‐Layer Hollow Fiber Membrane for Potential Syngas Production

The objective of this study was to fabricate dual‐layer hollow fiber as a microreactor for potential syngas production via phase inversion‐based co‐extrusion/cosintering process. As the main challenge of phase inversion is the difficulty to obtain defect‐free fiber, this work focuses on the effect of the fabrication parameters, that is, nonsolvent content, sintering temperature and outer‐layer extrusion rate, on the macrostructure of the produced hollow fiber. SEM images confirm that the addition of nonsolvent has successfully minimized the finger‐like formation. At high sintering temperature, more dense hollow fiber was formed while outer‐layer extrusion rate affects the outer layer thickness.     

Correction to: Synthesis of Co3O4 @ Organo/Polymeric Bentonite Structures as Environmental Photocatalysts and Antibacterial Agents for Enhanced Removal of Methyl Parathion and Pathogenic Bacteria

Journal of Inorganic and Organometallic Polymers and Materials -     

A new interval diagnosis method: Application to the spacecraft rendezvous phase of the Mars sample return mission

This paper presents a new optimized interval principal component analysis applied to detect and isolate actuators faults of an autonomous spacecraft involved in the rendezvous phase of the Mars sample return mission. Based on the exploitation of various arithmetic and interval analysis properties, the new interval model is built by solving the interval eigenpairs problem via a resolution of a parametric linear programming problem. The detection and isolation phases are performed by extending the classic methods to interval-valued data. The proposed method is applied to detect and isolate actuators faults that can occur on the spacecraft's thrusters. Based on data provided by a “high fidelity” industrial simulator developed by Thales Alenia Space, the obtained results proved the effectiveness of the proposed interval fault diagnosis method on detecting and isolating thrusters' faults.     

Development of high performance amine functionalized zeolitic imidazolate framework (ZIF-8)/cellulose triacetate mixed matrix membranes for CO2/CH4 separation

High cost and complex fabrication process of inorganic membranes and lower position of pristine polymeric membranes in the Robeson upper bound curve urged the researchers to develop mixed matrix membranes (MMMs). Cellulose acetate being most commercially used polymer, dominates the market of CO₂ separation mainly because of low cost and environmental friendly resource. In the present study, MMMs consists of amine functionalized zeolitic imidazolate framework (NH₂-ZIF-8) and cellulose triacetate were fabricated for the first time. NH₂-ZIF-8 was used as a filler because the pore size of ZIF-8 is between the kinetic diameter of separating gases (CO₂ and CH₄). Moreover,  NH₂ group attached on the surface of ZIF-8 has affinity with condensable gases like CO₂. Morphology, crystallinity, tensile strength and functional groups of fabricated membranes were investigated using different analytical techniques. Results revealed that the increase of feed pressure has increased CO₂ permeability and decreased permselectivity. However, improvements in gas separation performance were observed with the addition of nanofiller. Best position in Robeson's upper bound curve at 4 bar was obtained with 10 wt% loading with CO₂ permeability and CO₂/CH₄ permselectivity of 218 barrer and 13.84, respectively. The improvement in the gas separation performance with loading is attributed to the increased diffusion coefficients as well as solubility coefficients, which was increased to 33% and 3.8%, respectively.     

Two‐sided matching framework for optimal user association in 5G multi‐RAT UDNs

Recently, academic and industrial research communities are paying more explicit attention to the 5G multiple radio access technology ultra‐dense networks (5G multi‐RAT UDNs) for boosting network capacity, especially in UD urban zones. To this aim, in this paper, we intend to tackle the user association problem in 5G multi‐RAT UDNs. By considering the decoupled uplink/downlink access (DUDA), we divide our user association problem into two distinct subproblems representing, respectively, the uplink and the downlink channels. Next, we formulated each one as a nonlinear optimization problem with binary variables. Then, to solve them, we were restricted by the hard complexity, as well as the hard feasibility of centralized user association schemes. Thus, to resolve our user association problem in a reasonable time and distributed manner, we formulated each subproblem as a many‐to‐one matching game based on matching theory. Next, we provide two fully distributed association algorithms to compute the uplink and downlink stable matching among user equipments (UEs) and base stations (BSs). Simulation results corroborate our theoretical model and show the effectiveness and improvement of our achieved results in terms of the overall network performance, quality of service (QoS), and energy efficiency (EE) of UEs.     

An Enhanced A-MSDU Frame Aggregation Scheme for 802.11n Wireless Networks

The main goal of the IEEE 802.11n standard is to achieve a minimum throughput of 100 Mbps at the MAC service access point. This high throughput has been achieved via many enhancements in both the physical and MAC layers. A key enhancement at the MAC layer is frame aggregation in which the timing and headers overheads of the legacy MAC are reduced by aggregating multiple frames into a single large frame before being transmitted. Two aggregation schemes have been defined by the 802.11n standard, aggregate MAC service data unit (A-MSDU) and aggregate MAC protocol data unit (A-MPDU). As a consequence of the aggregation, new aggregation headers are introduced and become parts of the transmitted frame. Even though these headers are small compared to the legacy headers they still have a negative impact on the network performance, especially when aggregating frames of small payload. Moreover, the A-MSDU is highly influenced by the channel condition due mainly to lack of subframes sequence control and retransmission. In this paper, we have proposed an aggregation scheme (mA-MSDU) that reduces the aggregation headers and implements a retransmission control over the individual subframes at the MSDU level. The analysis and simulations results show the significance of the proposed scheme, specifically for applications that have a small frame size such as VoIP.     

Unglazed Fiberglass Reinforced Polyester Solar Water Heater with Integrated Storage System

Theoretical and experimental investigations on an unglazed solar hot water heater with integrated storage system were conducted. The system was comprised of a collector and storage tank which was integrated into one unit. All parts of the system have been fabricated from fiberglass reinforced polyester (GFRP). The absorber plate has water tubes of semielliptical shape. The width and length of the absorber plate were 1.4 and 1.8?m, respectively. The absorber plate was fabricated from GFPR using a special resin composition that provides good thermal conductivity and absorptivity. The storage tank has a capacity of 496?L. The storage tank is of sandwich construction with a core material made of polyurethane foam that combines stiffness and lightness of the structure with very good thermal insulation properties. An average tank temperature of 53°C was achieved at an average solar radiation level of 700?W/m2 and ambient temperature of 28°C. The thermal efficiencies of the system were evaluated at 48 and 57% for cloudy and clear days, respectively. Transient performance of the system was predicted by solving the mathematical models consisting of energy balance equations of the system that have been converted to finite difference form and solved by a personal computer. The experimental results were in close agreement as has been found with the theoretical predictions.     

Ethanol and lactic acid production using sap squeezed from old oil palm trunks felled for replanting

Old oil palm trunks that had been felled for replanting were found to contain large quantities of high glucose content sap. Notably, the sap in the inner part of the trunk accounted for more than 80% of the whole trunk weight. The glucose concentration of the sap from the inner part was 85.2 g/L and decreased towards the outer part. Other sugars found in relatively low concentrations were sucrose, fructose, galactose, xylose, and rhamnose. In addition, oil palm sap was found to be rich in various kinds of amino acids, organic acids, minerals and vitamins. Based on these findings, we fermented the sap to produce ethanol using the sake brewing yeast strain, Saccharomyces cerevisiae Kyokai no.7. Ethanol was produced from the sap without the addition of nutrients, at a comparable rate and yield to the reference fermentation on YPD medium with glucose as a carbon source. Likewise, we produced lactic acid, a promising material for bio-plastics, poly-lactate, from the sap using the homolactic acid bacterium Lactobacillus lactis ATCC19435. We confirmed that sugars contained in the sap were readily converted to lactic acid with almost the same efficiency as the reference fermentation on MSR medium with glucose as a substrate. These results indicate that oil palm trunks felled for replanting are a significant resource for the production of fuel ethanol and lactic acid in palm oil-producing countries such as Malaysia and Indonesia.