Silicon nanoclusters (Si-ncs) embedded in silicon nitride films have been studied to determine the effects that deposition
and processing parameters have on their growth, luminescent properties, and electronic structure. Luminescence was observed
from Si-ncs formed in silicon-rich silicon nitride films with a broad range of compositions and grown using three different
types of chemical vapour deposition systems. Photoluminescence (PL) experiments revealed broad, tunable emissions with peaks
ranging from the near-infrared across the full visible spectrum. The emission energy was highly dependent on the film composition
and changed only slightly with annealing temperature and time, which primarily affected the emission intensity. The PL spectra
from films annealed for duration of times ranging from 2 s to 2 h at 600 and 800°C indicated a fast initial formation and
growth of nanoclusters in the first few seconds of annealing followed by a slow, but steady growth as annealing time was further
increased. X-ray absorption near edge structure at the Si K- and L3,2-edges exhibited composition-dependent phase separation and structural re-ordering of the Si-ncs and silicon nitride host
matrix under different post-deposition annealing conditions and generally supported the trends observed in the PL spectra. 相似文献
As a network-based localized mobility management protocol, Proxy Mobile IPv6 (PMIPv6) enables a Mobile Host (MH) to roam within a localized domain without MH intervention in the mobility-related signalling. However, the PMIPv6 maintains MH mobility support in a restriction domain. Therefore, whenever the MH roams away from the PMIPv6 domain, its reachability status will be broken-down causing high handover latency and inevitable traffic loss for its communication session. This article proposes a proactive mechanism to mange the MH handover and maintain its data session continually across inter-PMIPv6-domains. The proposed mechanism introduces an intermediate global mobility anchor entity, called, which is responsible to coordinate MH handover as well as redirect its traffic across inter-PMIPv6-domains. Through various simulation evaluations, via ns-2, several experiments were conducted, revealing numerous results that verify the proposed mechanism superior performance over the conventional inter-PMIPv6-domain handover schemes in terms of handover latency, achieved throughput, protocol signalling cost and end-to-end traffic delivery latency. 相似文献
Three activated carbons and two chars made from low rank coal were evaluated in terms of their ability to remove the organic compound 4-nitrophenol (4-NP) and natural organic matter (NOM) from aqueous systems. The adsorption equilibrium capacities of all adsorbents for 4-NP correlated with the micropore area of the adsorbents. Adsorption rates showed improved removal with decreasing particle size and higher carbon mass loadings. A pseudo first order model was used to fit the kinetic data, with a correlation coefficient of 0.995–0.999 for all systems.
The adsorption capacity for NOM, as measured by UV-absorbing DOC, correlated well with the pore volume and pore surface areas for pores with diameters in the range 2.7–21 nm. The trend in the adsorption capacities and removal rates of the adsorbents for NOM provided evidence that the pore size distribution is one of the most important physical characteristics of activated carbon for the adsorption of NOM.
The performance of activated low rank coal based materials was comparable to a high quality coconut-based commercial carbon in batch systems. Although the non-activated char adsorbents gave poor performance, they have potential for use in applications where poor performance can be outweighed by lower cost. 相似文献
A new series of polymers comprising four terpolymers was synthesized via Mannich polycondensation of benzene-1,4-diamine, formaldehyde and piperazine by varying the benzene-1,4-diamine and piperazine ratio. The new polyamines (labeled Dipip) were characterized using 13C solid-state NMR, FT-IR, TGA, DSC, XRD, SEM and EDX. The adsorptive performances of the synthesized polymers for Erichrome Black T (EBT) uptake from aqueous solution were investigated under batch process. Equilibrium, kinetic, and thermo-dynamic studies were conducted to determine the influence of different operational parameters of the adsorption process. The two most promising polymers among the series show an excellent EBT removal efficiency of~100%and~95%with high adsorption capacities of 775 mg·g- 1 and 917 mg·g- 1, respectively at a meager dosage of 5 mg. The sorption of EBT on the polymers was well described by Redlich-Peterson&Langmuir model while the kinetic studies indicate that pseudo-second order model was followed. For the thermodynamic studies, the negativeΔG and positiveΔH values obtained suggest a spontaneity of the sorption process which was endothermic in nature. The results of reusability test of the resins were promising even at the fourth cycle, showcasing the potentials of the new polymers in dyes contaminated water treatment. 相似文献
Wireless Personal Communications - In the last decade, daily lifestyles have been invaded by mobile networks which added a huge exchange of information. This exchange among vehicular nodes as a... 相似文献
Activated-carbon nanofibers (ACNFs) provide a relatively new, modified structure of carbon-based adsorbents that have the ability to adsorb carbon dioxide due to their high specific surface area, wide distribution of porous structures, and high volume of active sites. In this study, cost-effective agricultural waste-based graphene synthesized from rice husk ashes was used as additive to enhance the ACNF properties. ACNF/graphene (gACNF) is still a relatively unexplored adsorbent. The resultant gACNF exhibited better thermal stability properties, with higher yield, larger specific surface area, and higher micropore volume. These properties are the main factors contributing to their enhanced adsorption performance towards CO2. 相似文献