Geochemistry of some rare earth elements in groundwater,Vierlingsbeek, The Netherlands

Groundwater samples were taken from seven bore holes at depths ranging from 2 to 41m nearby drinking water pumping station Vierlingsbeek, The Netherlands and analysed for Y, La, Ce, Pr, Nd, Sm and Eu. Shale-normalized patterns were generally flat and showed that the observed rare earth elements (REE) were probably of natural origin. In the shallow groundwaters the REEs were light REE (LREE) enriched, probably caused by binding of LREEs to colloids. To improve understanding of the behaviour of the REE, two approaches were used: calculations of the speciation and a statistical approach.For the speciation calculations, complexation and precipitation reactions including inorganic and dissolved organic carbon (DOC) compounds, were taken into account. The REE speciation showed REE(3+), REE(SO(4))(+), REE(CO(3))(+) and REE(DOC) being the major species. Dissolution of pure REE precipitates and REE-enriched solid phases did not account for the observed REEs in groundwater. Regulation of REE concentrations by adsorption-desorption processes to Fe(III)(OH)(3) and Al(OH)(3) minerals, which were calculated to be present in nearly all groundwaters, is a probable explanation.The statistical approach (multiple linear regression) showed that pH is by far the most significant groundwater characteristic which contributes to the variation in REE concentrations. Also DOC, SO(4), Fe and Al contributed significantly, although to a much lesser extent, to the variation in REE concentrations. This is in line with the calculated REE-species in solution and REE-adsorption to iron and aluminium (hydr)oxides. Regression equations including only pH, were derived to predict REE concentrations in groundwater. External validation showed that these regression equations were reasonably successful to predict REE concentrations of groundwater of another drinking water pumping station in quite different region of The Netherlands.     

Stability analysis of simply-supported rectangular plates under non-uniform uniaxial compression using rigorous and approximate plane stress solutions

The non-classical problem of buckling of a simply-supported rectangular plate due to various types of non-uniform compressive edge loads is analysed here. For each case, the elasticity solution for the internal in-plane stress field is obtained rigorously using a superposition of Airy's stress functions and also approximately using extended Kantorovich method. Subsequently, the convergent buckling loads are obtained using Galerkin's method. Results are presented to highlight the dependence of the total buckling load and the corresponding buckled shape on the edge load distribution, as well as to illustrate the applicability of the approximate plane stress solutions.     

Method of Determining Strength and Deformation Characteristics of Soils from Results of Deep Impression of Rod Plates

The possibility of determining strength and deformation characteristics of soils under field conditions using rod plates is discussed. The mutual relationship between these characteristics is established from results of deep impression of these rods.     

Chloroaromatic formation in incineration processes

The high-temperature reactions of chlorinated hydrocarbons are reviewed with a primary focus on the gas-phase molecular growth chemistry and elementary reaction mechanisms leading to the formation of chlorinated benzenes and chlorinated polycyclic aromatic hydrocarbons. Recent heterogeneous mechanistic studies of the chlorination and condensation of aliphatic hydrocarbons at lower temperatures are also summarized. Copper(II) valent species play an important role as catalyst and reagent. The main thermal pathways for chlorinated dibenzodioxins and furans have been deduced by these laboratory experiments, which try to model the complex reality of the post-incineration zone of municipal and hazardous waste incinerators.     

Procedure for predicting settlements of thawing bases for engineering calculations

It was shown that in order to compute the settlement of thawing cohesive soil under a load in time it is necessary to experimentally determine the consolidation coefficient. A procedure is suggested for determining this coefficient, as well as use of the classical solution of a differential equation for seepage consolidation to describe the settlement of soil, thawing of which can occur according to any law.State All-Union Scientific Research Institute of Roads. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 4, pp. 5–7, July–August, 1993.     

Use of toxicity test results and confrontation of some toxicity test methods with fire scenarios

The enormous, world wide research activity in the field of combustion toxicology has given rise to an impressive amount of toxicity data.

The first part of this paper discusses the problems which arise when such results are used to rank materials in an order of the relative toxicity of their combustion products or in attempting to relate them to toxicological hazard evaluation.

In the second part, after introducing the notion of fire scenarios and describing two such possible situations, existing test methods are compared in relation to their relevance to the scenario parameters. It is shown that none of the evaluated methods completely fulfills the considered conditions.

It is concluded by the authors that agreement on thoroughly described scenarios is necessary for further trials towards international harmonisation and development of test methods.     

Circular footings resting on geotextile-reinforced sand bed

The note pertains to an experimental study made on circular footings resting on semi-infinite layer of sand reinforced with geotextiles. Using the concept of homogenization of such soils, both analytical and numerical analyses have also been conducted to predict the load-settlement behavior and compared with experimental observations. The study highlights the effect of the footing size, number of reinforcing layers, reinforcement placement pattern and bond length and the relative density of the soil on the load-settlement characteristics of the footings.     

Radon concentration in houses over a closed Hungarian uranium mine

High radon concentration (average 410 kBq m-3) has been measured in a tunnel of a uranium mine, located 15-55 m below the village of Kovágószolos, Hungary. The mine was closed in 1997; the artificial ventilation of the tunnel was then terminated and recultivation works begun. In this paper, a study has been made as to whether the tunnel has an influence on the radon concentration of surface dwellings over the mining tunnel. At different distances from the surface projection of the mining tunnel, radon concentration, the gamma dose, radon exhalation and radon concentration of soil gas were measured. The average radon concentration in the dwellings was 483 Bq m-3. Significantly higher radon concentrations (average 667 Bq m-3) were measured in houses within +/-150 m from the surface projection of the mining tunnel +50 m, compared with the houses further than the 300-m belt (average 291 Bq m-3). The average radon concentration of the soil gas was 88.8 kBq m-3, the average radon exhalation was 71.4 Bq m-2 s-1 and higher values were measured over the passage as well. Frequent fissures crossing the passage and running up to the surface and the high radon concentration generated in the passage (average 410 kBq m-3) may influence the radon concentration of the houses over the mining tunnel.     

Reviews

DROUGHT AND FAMINE IN ETHIOPIA Editor: Abdul Mejid Hussein. African Environment Special Report No. 2, The International African Institute, London, 1976,121 pp. £1.50.

HEDGING (A Practical conservation handbook) Alan Brooks, The British Trust for Conservation Volunteers, The Zoological Gardens, Regents Park, London, 1975. 117 pp. £2.10 inc. postage.

THREE JOURNALS Habitat: Published by : The Council for Nature, The Zoological Gardens, Regents Park, NW1 4RY. At £2.50, or £5.00 per annum.

Recreation News: Published by: The Countryside Commission , John Dower House, Crescent Place, Cheltenham, Glos., GL50 3RA.

The International Journal of Environmental Studies: Published by : Gordon Breach Science Publishers Ltd., 42 William IV Street. London, W.C.2. £17.50 for individuals, £35.00 for Libraries. Habitat

A HISTORY OF LANCASHIRE J.J. Bagley, Phillimore & Co. Ltd., London & Chichester 1976. 128 pp. £4.95.