Metoprolol abatement from wastewaters by electrochemical oxidation with boron doped diamond anodes

BACKGROUND: Metoprolol is a beta‐blocker that can be found in urban wastewaters and which is not removed efficiently by conventional wastewater treatments. In this work, the removal of this pollutant by conductive diamond electrochemical oxidation (CDEO) is studied. RESULTS: CDEO is able to degrade Metoprolol tartrate down to the 10 ppb level (detection limit of the technique used) with a current charge requirement that increases with increase in the initial concentration of pollutant, although it is many times greater than the stoichiometric current charge required. CDEO also removed very efficiently the reaction intermediates. In terms of TOC the depletion follows a first‐order kinetic, but the kinetic constant of Metoprolol decreases with concentration. NaCl increases significantly Metoprolol degradation rate, but it barely affects the TOC removal rate. CONCLUSIONS: CDEO can be used to remove Metoprolol from wastewaters, independently of the initial concentration of compound. Several reaction intermediates are formed during the electrolyses although their concentrations are very low and negligible compared with that of Metoprolol. The removal rate (in terms of TOC) does not depend on the nature of the electrolyte used. The process is under mass transfer control for the complete range of concentrations studied. Copyright © 2011 Society of Chemical Industry     

Impact of moisture and grinding on yield,physical, chemical and thermal properties of wholegrain flour obtained from hydrothermally treated sorghum grains

The present work evaluates the potential of sorghum with high content of tannins for wholegrain flour production. Two types of mills were used: a roller mill (RM) and a blade (BM) mill. The impact of moisture and grinding on yield, physical, chemical and thermal properties were evaluated. Maximum yield was obtained using a BM with 25% moisture in the grain, resulting in 60.9% versus 28% (g flour g⁻¹ of wholegrain sorghum) for the RM. Grain moisture and milling type affected flour colour and ashes. For both mills, the pasting and thermal properties of flour with grain moisture variation were significantly different from the untreated control sample. By studying the procedures for flour production and quality characteristics, it is possible to produce flour with good physical attributes, which can contribute to the development of gluten-free foods based on sorghum for the coeliac population.     

Assessment of the rice husk lean-combustion in a bubbling fluidized bed for the production of amorphous silica-rich ash

Rice husk lean-combustion in a bubbling and atmospheric fluidized bed reactor (FBR) of 0.3 m diameter with expansion to 0.4 m in the freeboard zone and 3 m height was investigated. Experiment design - response surface methodology (RSM) - is used to evaluate both excess air and normal fluidizing velocity influence (independent and controllable variables), in the combustion efficiency (carbon transformation), bed and freeboard temperature and silica content in the ashes. Hot gases emissions (CO₂, CO and NO_x), crystallographic structure and morphology of the ash are also shown. A cold fluidization study is also presented. The values implemented in the equipment operation, excess air in the range of 40-125% and normal fluidization velocities (0.13-0.15 Nm/s) show that the values near the lower limit, encourage bed temperatures around 750 °C with higher carbon transformation efficiencies around 98%. However, this condition deteriorated the amorphous potential of silica present in the ash. An opposite behavior was evidenced at the upper limit of the excess air. This thermochemical process in this type of reactor shows the technical feasibility to valorize RH producing hot gases and an amorphous siliceous raw material.     

Structural Characterization and Electrochemical Performance of Zr1−xTixCr0.7Mo0.3Ni Alloys

JOM - Three specimens were synthesized presenting the following stoichiometry: Zr1?xTixCr0.7Mo0.3Ni (x?=?0.3; 0.5; 0.7). The substitution of zirconium atoms by a lower atomic...     

Agile development of multiplatform educational video games using a Domain-Specific Language

Universal Access in the Information Society - Educational video games are becoming an increasingly popular alternative in the academic field. However, video game development is a very complex task...     

A data mining approach to guide students through the enrollment process based on academic performance

Student academic performance at universities is crucial for education management systems. Many actions and decisions are made based on it, specifically the enrollment process. During enrollment, students have to decide which courses to sign up for. This research presents the rationale behind the design of a recommender system to support the enrollment process using the students?? academic performance record. To build this system, the CRISP-DM methodology was applied to data from students of the Computer Science Department at University of Lima, Perú. One of the main contributions of this work is the use of two synthetic attributes to improve the relevance of the recommendations made. The first attribute estimates the inherent difficulty of a given course. The second attribute, named potential, is a measure of the competence of a student for a given course based on the grades obtained in related courses. Data was mined using C4.5, KNN (K-nearest neighbor), Naïve Bayes, Bagging and Boosting, and a set of experiments was developed in order to determine the best algorithm for this application domain. Results indicate that Bagging is the best method regarding predictive accuracy. Based on these results, the ??Student Performance Recommender System?? (SPRS) was developed, including a learning engine. SPRS was tested with a sample group of 39 students during the enrollment process. Results showed that the system had a very good performance under real-life conditions.     

Unitarity plus causality implies localizability

We consider a graph with a single quantum system at each node. The entire compound system evolves in discrete time steps by iterating a global evolution U. We require that this global evolution U be unitary, in accordance with quantum theory, and that this global evolution U be causal, in accordance with special relativity. By causal we mean that information can only ever be transmitted at a bounded speed, the speed bound being quite naturally that of one edge of the underlying graph per iteration of U. We show that under these conditions the operator U can be implemented locally; i.e. it can be put into the form of a quantum circuit made up with more elementary operators — each acting solely upon neighboring nodes. We take quantum cellular automata as an example application of this representation theorem: this analysis bridges the gap between the axiomatic and the constructive approaches to defining QCA.     

The effects of majority versus minority source status on persuasion: A self-validation analysis.

The present research proposes that sources in the numerical majority (vs. minority) can affect persuasion by influencing the confidence with which people hold their thoughts in response to the persuasive message. Participants received a persuasive message composed of either strong or weak arguments that was presented by a majority or a minority source. Consistent with the self-validation hypothesis, we predicted and found that the majority (vs. minority) status of the source increased the confidence with which recipients held their thoughts. As a consequence, majority (vs. minority) sources increased argument quality effects in persuasion when source status information followed message processing (Experiment 1). In contrast, when the information regarding source status preceded (rather than followed) the persuasive message, it validated the perception of the position advocated, reducing message processing. As a consequence of having more confidence in the position advocated before receiving the message, majority (vs. minority) sources reduced argument quality effects in persuasion (Experiment 2). Finally, Experiment 3 isolated the timing of the source status manipulation, revealing that sources in the numerical majority (vs. minority) can increase or decrease persuasion to strong arguments depending on whether source status is introduced before or after processing the message. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Low Consumption Communications Over Shallow Water Acoustic Channels

Acoustic or ultrasonic transmission is the preferred alternative for underwater communications. Power is not an unlimited resource in the underwater environment. Moreover the underwater acoustic channel is subject to severe slow and fast fading. High transmission power is needed so that a fair BER is achieved. A power control policy is, therefore, of paramount importance. This communication explores the benefits of using power control in underwater communications, when gamma/Ricean channels are considered. Simulation results are presented that suggest which channels are more appropriate for the power control to be applied, and estimate the amount of expected power saving.