Effective thermal conductivity of functionally graded random micro-heterogeneous materials using representative volume element and BEM

This work introduces a numerical methodology for the computation of the effective thermal conductivity (ETC) of random micro-heterogeneous materials using representative volume elements and the Fast Multipole Boundary Element Method (FMBEM). The methodology is applied to solve two-dimensional foam-like materials consisting of random distributions of circular isolated holes. The computed ETC values are successfully used to predict the temperature fields of two materials with functionally graded ETCs. Numerical and analytical results are experimentally validated. The proposed methodology is flexible and versatile, as it is capable to account for both, the geometrical and topological details of the material microstructure.     

Stand-alone operation of an alkaline water electrolyser fed by wind and photovoltaic systems

Over the last few years, hydrogen technologies have established themselves as key enablers in the medium and long-term development of a new energy model that offers greater sustainability and independence than the present-day one. In this respect, the integration of water electrolysis with renewable energy-based systems can play an important part in the large-scale production of sustainable hydrogen. This paper reports on the complete experimental characterisation of a 1 Nm³ h⁻¹ alkaline water electrolyser located in the Public University of Navarre (UPNa). Specifically, a study was made of the electrical performance, hydrogen production rate, purity of the gases generated and energy efficiency, for a range of operating currents (40–120 A), temperatures (35–65 °C) and pressures (5–25 bar). Additionally, an experimental study was conducted on the electrolyser operation under conditions that are characteristic of a stand-alone wind power and PV-based renewable energy system, installed at the UPNa. The results obtained for the wind power and PV emulations showed that the electrolyser performed correctly, with regard to balance of plant and its principal electrochemical characteristics. Furthermore, the mean energy efficiency of the electrolyser was 77.7% for the wind power emulation, and 78.6% for the PV emulation on a day with stable irradiance, and 78.1% on a day with highly variable irradiance (day with scattered clouds).     

An electrical network for the numerical solution of transient mhd couette flow of a dusty fluid: Effects of variable properties and hall current

The Network Simulation Method (NSM) has been used to study the variations with velocity of suction, hall effect, Reynolds and Hartmann number, particle concentration and Eckert number on the unsteady MHD Couette Flow and heat transfer of a dusty and electrically conducting fluid between parallel plates in the presence of an external uniform magnetic field and uniform suction and injection. The solutions are obtained with the network model proposed and the electric circuit simulation program PSpice. The fluid is acted upon by a constant pressure gradient and an external uniform magnetic field is applied perpendicular to the plates. Due to the presence of uniform suction and injection, the Hall Effect is not dismissed. The NSM is applied to solve the steady-state and transient problems of flow and heat transfer for both the fluid and dust particles. This method requires only discretization of the spatial co-ordinates, while time remains a real continuous variable. Velocity and temperature are studied for different values of the viscosity and magnetic field parameters and for different particle concentrations and upper wall velocities.     

Effect of a coalescing aid on the earliest stages of polymer diffusion in poly(butyl acrylate-co-methyl methacrylate) latex films

In this article we use fluorescence resonance energy transfer (FRET) to investigate how a classic coalescing aid, such as 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate (Texanol?) (TX), acts on the earliest stages of polymer diffusion as the latex film is still drying. In our approach, we temporarily arrest the drying process of a partially wet latex film by sealing it in an airtight chamber previously cooled to near the latex T_g. At these conditions, we are able to effectively stop the drying process and the polymer diffusion. FRET measurements at various locations on such a sample provide us information about the mechanism operating at the initial stages of polymer diffusion as the latex film is still drying. We complete our study with FRET measurements carried out at longer aging times on predried latex films. We analyze our diffusion data in terms of free volume theory and propose a mechanism that can account for the results obtained.     

Study of the Free Surface Flow on an Ogee-Crested Fish Bypass

A study of the free surface flow on an ogee-crested fish bypass is presented. The commercial computational fluid dynamics (CFD) code Fluent 6.1 was used to perform the simulations. Structured/unstructured hybrid grids were used to accommodate the complex geometry that included gate slots, flow control gates, and an aeration slot. The volume of fluid (VOF) approach was used to model the water/air interface. The fish bypass exhibits complex free surface features including free nappes and air entrainment from the air slots. Free surface elevations on both sides of the nappe, pressure along the ogee surface, and discharge rating curves were compared against 1:24 experimental data from the laboratory model for different headwater elevations and gate settings. Limited comparison against measured velocities was also performed. Once deemed reliable through validation against experimental data, the computational model was used to analyze the flow field, supplementing the areas of limited experimental data. Though the paper presents the final fish bypass design, CFD was used to guide the design process and provide insight for several variations in the geometry.     

Association of cyclists’ age and sex with risk of involvement in a crash before and after adjustment for cycling exposure

This study aimed to estimate the association of cyclists’ age and sex with the risk of being involved in a crash with and without adjustment for their amount of exposure. We used the distribution of the entire population and cyclists (total and non-responsible) involved in road crashes in Spain between 1993 and 2009 held by the Spanish National Institute of Statistics and the Spanish General Traffic Directorate to calculate rates of exposure and involvement in a crash. Males aged 45–49 years were used as the reference category to obtain exposure rate ratios (ERR) and unadjusted crash rate ratios (URR). We then used these values in decomposition analysis to calculate crash rate ratios adjusted for exposure (ARR). The pattern of ARR was substantially different from URR. In both sexes the highest values were observed in the youngest age groups, and the values decreased as age increased except for a slight increase in the oldest age groups. In males, a slight increase in the lowest and highest age categories was observed for crashes resulting in severe injury or death, and a decrease was observed for the youngest cyclists who were wearing a helmet. The large differences between age and sex groups in the risk of involvement in a cycling crash are strongly dependent on differences in their exposure rates. Taking exposure rates into account, cyclists younger than 30 years and older than 65 years of age had the highest risk of being involved in a crash.     

Is singular value decomposition useful for word similarity extraction?

In this paper, we analyze the behaviour of Singular Value Decomposition in a number of word similarity extraction tasks, namely acquisition of translation equivalents from comparable corpora. Special attention is paid to two different aspects: computational efficiency and extraction quality. The main objective of the paper is to describe several experiments comparing methods based on Singular Value Decomposition (SVD) to other strategies. The results lead us to conclude that SVD makes the extraction less computationally efficient and much less precise than other more basic models for the task of extracting translation equivalents from comparable corpora.     

The sensory optimum of chicken broths supplemented with calcium di-glutamate: A possibility for reducing sodium while maintaining taste

This study examined the effects of calcium di-glutamate (CDG) supplementation on the sensory and hedonic characteristics of chicken broth. Thirty-four normal weight men and women aged 20-35 years tasted 12 soups containing 4 different concentrations of sodium chloride (.16%, .53%, .85%, and 1.7% w/w) and three concentrations of CDG (0%, .17%, and .33% w/w). Participants tasted all the soups twice over 2 days and used computer-administered visual analog scales to record taste intensity and hedonic ratings. Soups were presented in random order, at least 3 min apart to allow for taste ratings and mouth rinsing. Data were analyzed using repeated measures analysis of variance. Response surface methodology (RSM) was used to determine the hedonic optima for sodium chloride and CDG. Results indicated that CDG could partly replace sodium chloride at constant levels of liking and pleasantness. These data provide evidence that lower sodium broths can be made more palatable with CDG supplementation.     

Enhancement of the fuel cell performance of a high temperature proton exchange membrane fuel cell running with titanium composite polybenzimidazole-based membranes

The fuel cell performance of a composite PBI-based membrane with TiO₂ has been studied. The behaviour of the membrane has been evaluated by comparison with the fuel cell performance of other PBI-based membranes, all of which were cast from the same polymer with the same molecular weight. The PBI composite membrane incorporating TiO₂ showed the best performance and reached 1000 mW cm⁻² at 175 °C. Moreover, this new titanium composite PBI-based membrane also showed the best stability during the preliminary long-term test under our operation conditions. Thus, the slope of the increase in the ohmic resistance of the composite membrane was 0.041 mΩ cm² h⁻¹ and this is five times lower than that of the standard PBI membrane. The increased stability was due to the high phosphoric acid retention capacity - as confirmed during leaching tests, in which the Ti-based composite PBI membrane retained 5 mol of H₃PO₄/PBI r.u. whereas the PBI standard membrane only retained 1 mol H₃PO₄/PBI r.u. Taking into account the results obtained in this study, the TiO₂-PBI based membranes are good candidates as electrolytes for high temperature PEMFCs.     

A Matrix Formulation of Discrete Chirp Fourier Transform Algorithms

This work presents a computational matrix framework in terms of tensor signal algebra for the formulation of discrete chirp Fourier transform algorithms.These algorithms are used in this work to estimate the point target functions(impulse response functions)of multiple-input multiple-output(MIMO)synthetic aperture radar(SAR)systems.This estimation technique is being studied as an alternative to the estimation of point target functions using the discrete cross-ambiguity function for certain types of environmental surveillance applications.The tensor signal algebra is presented as a mathematics environment composed of signal spaces,finite dimensional linear operators,and special matrices where algebraic methods are used to generate these signal transforms as computational estimators.Also,the tensor signal algebra contributes to analysis,design,and implementation of parallel algorithms.An instantiation of the framework was performed by using the MATLAB Parallel Computing Toolbox,where all the algorithms presented in this paper were implemented.