Exponentially convergent control laws for nonholonomic systems in power form

This paper introduces a method for constructing exponentially convergent control laws for n-dimensional nonholonomic systems in power form. The methodology is based on the construction of a series of nested invariant manifolds for the closed-loop system under a linear control law. A recursive algorithm is presented which uses these manifolds to construct a three-dimensional system in power form. It is shown that the feedback controller for the original system is the one for this three-dimensional system with a proper choice of the gains.     

Policies for the reconfiguration of cognitive wireless infrastructures to 3G Radio Access Technologies

The ceaseless evolution of wireless communications is reflected nowadays on the introduction of Beyond-3G (B3G) systems, characterized by the coexistence and cooperation of various Radio Access Technologies (RATs), over a common infrastructure. Major facilitator of this convergence is the advent of cognitive networks, which deploy elements (base stations and mobile terminals) that are able to proactively adapt to environmental stimuli, so that to optimize their performance. Part of the adaptation action takes place in cognitive base stations that own several reconfigurable transceivers, which are controlled by appropriate management functionality and may dynamically change their operating parameters. Each reconfiguration set includes a specific RAT, carrier frequency, as well as demand volume to be allocated per transceiver. Accordingly, proper evaluation of the various candidate reconfiguration sets appears to be of high significance. To this effect, in this paper we consider a cognitive network segment with transceivers operating at 3G RAT/carrier and we solve the DAMC problem (Demand Allocation into Multiple Carriers problem), which aims at evaluating and selecting the optimum policy to allocate the demand into the available 3G carrier frequencies. Optimality is expressed in terms of minimizing the total transmitted/received power per base station, thus deciding for the reconfigurations with the least impact on network interference. Indicative simulation scenarios and results are also presented for the validation and verification of the proposed functionality.

Photooxidation Products of Ethanol During Photoelectrochemical Operation Using a Nanocrystalline Titania Anode and a Two Compartment Chemically Biased Cell

ZnMe^IIIFeO₄ catalysts with different trivalent metal (Me^III = Fe, Al, Cr, Mn, and Co) were prepared by a co-precipitation method, and were applied to the oxidative dehydrogenation of n-butene to 1,3-butadiene. Successful formation of ZnMe^IIIFeO₄ catalysts was confirmed by XRD and ICP-AES analyses. Catalytic performance of ZnMe^IIIFeO₄ catalysts in the oxidative dehydrogenation of n-butene strongly depended on the identity of trivalent metal (Me^III). Acid properties of ZnMe^IIIFeO₄ catalysts were measured by NH₃-TPD experiments, with an aim of correlating the catalytic performance with the surface acid property of the catalysts. It was revealed that yield for 1,3-butadiene increased with increasing surface weak-acid density of ZnMe^IIIFeO₄ catalyst. Among the catalysts tested, ZnFeFeO₄ catalyst with the largest surface weak-acid density showed the best catalytic performance in the oxidative dehydrogenation of n-butene.     

Regulation of film thickness, surface roughness and porosity in thin film growth using deposition rate

This work focuses on distributed control of film thickness, surface roughness and porosity in a porous thin film deposition process using the deposition rate as the manipulated input. The deposition process includes adsorption and migration processes and it is modeled via kinetic Monte Carlo simulation on a triangular lattice with vacancies and overhangs allowed to develop inside the film. A distributed parameter (partial differential equation) dynamic model is derived to describe the evolution of the surface height profile of the thin film accounting for the effect of deposition rate. The dynamics of film porosity, evaluated as film site occupancy ratio, are described by an ordinary differential equation. The developed dynamic models are then used as the basis for the design of a model predictive control algorithm that includes penalty on the deviation of film thickness, surface roughness and film porosity from their respective set-point values. Simulation results demonstrate the applicability and effectiveness of the proposed modeling and control approach in the context of the deposition process under consideration.     

Chemical, leaching and toxicity characteristics of CFB combustion residues

Within the last years, attention has been focused on the development of clean coal technologies, based on the pulverized coal fired once-through boiler technology and the circulating fluidised bed combustion (CFBC) systems. The environmental problems provoked from those wastes due to their toxic trace element contents necessitate their detailed characterisation. Within the scope of this concept, two different coal types were used in a series of experimental trials. Fly and bottom ash samples were collected and characterised in terms of morphology, mineralogy, leaching and toxicity behaviour. According to the results, toxic trace elements are preferentially concentrated in the fly ash particles since they presented the smaller particles size. However, the chemical analysis of the ash leachates showed that are acceptable for safe disposal, since none of them exceeds the maximum EPA limits. Additionally, the Microtox toxicity test proved that fly ash leachates, which presented the higher heavy metals concentrations, caused the higher toxic effects.     

Secure message transmission in mobile ad hoc networks

The vision of nomadic computing with its ubiquitous access has stimulated much interest in the mobile ad hoc networking (MANET) technology. However, its proliferation strongly depends on the availability of security provisions, among other factors. In the open, collaborative MANET environment, practically any node can maliciously or selfishly disrupt and deny communication of other nodes. In this paper, we propose the secure message transmission (SMT) protocol to safeguard the data transmission against arbitrary malicious behavior of network nodes. SMT is a lightweight, yet very effective, protocol that can operate solely in an end-to-end manner. It exploits the redundancy of multi-path routing and adapts its operation to remain efficient and effective even in highly adverse environments. SMT is capable of delivering up to 83% more data messages than a protocol that does not secure the data transmission. Moreover, SMT achieves up to 65% lower end-to-end delays and up to 80% lower delay variability, compared with an alternative single-path protocol––a secure data forwarding protocol, which we term secure single path (SSP) protocol. Thus, SMT is better suited to support quality of service for real-time communications in the ad hoc networking environment. The security of data transmission is achieved without restrictive assumptions on the network nodes’ trust and network membership, without the use of intrusion detection schemes, and at the expense of moderate multi-path transmission overhead only.     

Querbeanspruchung von Ankergruppen in Randnähe – Stochastische Studien

Behavior of Anchor Groups Close to an Edge under Shear Loads – Stochastic Studies Fastenings in concrete with anchor groups placed close to a free edge are often met in practice. At the connection of anchors with a steel baseplate, installation tolerances are often present and the anchors are randomly placed in the clearance holes of the plate. Consequently, by shear loading of an anchorage, the anchors are not activated simultaneously and the group's shear capacity is strongly affected. By means of more precise investigations on this feature, improved design concepts will be developed. In the present article a stochastic analysis of the group's behavior under shear loads is described, where random configurations of the anchors in the clearance holes but also various geometries and mechanical parameters of a group are taken into consideration. Based on the results of this analysis an equation is finally proposed, in order to calculate the shear capacity of an anchor group where installation tolerances are involved in relation to its geometric and mechanical properties.     

Clustering‐based scheduling: A new class of scheduling algorithms for single‐hop lightwave networks

In wavelength division multiplexing (WDM) star networks, the construction of the transmission schedule is a key issue, which essentially affects the network performance. Up to now, classic scheduling techniques consider the nodes' requests in a sequential service order. However, these approaches are static and do not take into account the individual traffic pattern of each node. Owing to this major drawback, they suffer from low performance, especially when operating under asymmetric traffic. In this paper, a new class of scheduling algorithms for WDM star networks, which is based on the use of clustering techniques, is introduced. According to the proposed Clustering‐Based Scheduling Algorithm (CBSA), the network's nodes are organized into clusters, based on the number of their requests per channel. Then, their transmission priority is defined beginning from the nodes belonging to clusters with higher demands and ending to the nodes of clusters with fewer requests. The main objective of the proposed scheme is to minimize the length of the schedule by rearranging the nodes' service order. Furthermore, the proposed CBSA scheme adopts a prediction mechanism to minimize the computational complexity of the scheduling algorithm. Extensive simulation results are presented, which clearly indicate that the proposed approach leads to a significantly higher throughput‐delay performance when compared with conventional scheduling algorithms. We believe that the proposed clustering‐based approach can be the base of a new generation of high‐performance scheduling algorithms for WDM star networks. Copyright © 2008 John Wiley & Sons, Ltd.     

Peroxidase-active cell free extract from onion solid wastes: biocatalytic properties and putative pathway of ferulic acid oxidation

The exploitation of food residuals can be a major contribution in reducing the polluting load of food industry waste and in developing novel added-value products. Plant food residues including trimmings and peels might contain a range of enzymes capable of transforming bioorganic molecules, and thus they may have potential uses in several biocatalytic processes, including green organic synthesis, modification of food physicochemical properties, bioremediation, etc. Although the use of bacterial and fungal enzymes has gained attention in studies pertaining to biocatalytic applications, plant enzymes have been given less consideration or even disregarded. Therefore, we investigated the use of a crude peroxidase preparation from solid onion by-products for oxidizing ferulic acid, a widespread phenolic acid, various derivatives of which may occur in food wastes. The highest enzyme activity was observed at a pH value of 4, but considerable activity was retained up to a pH value of 6. Favorable temperatures for increased activity varied between 20-40 degrees C, 30 degrees C being the optimal. Liquid chromatography-mass spectrometry analysis of a homogenate/H(2)O(2)-treated ferulic acid solution showed the formation of a dimer as a major oxidation product.     

Characterisation of certain major polyphenolic antioxidants in grape (<Emphasis Type="Italic">Vitis vinifera</Emphasis> cv. Roditis) stems by liquid chromatography-mass spectrometry

The stem extract, which was shown to contain high amounts of phenolics and significant antioxidant potency, was further analysed employing liquid chromatography-electrospray ionisation mass spectrometry, in an effort to obtain a deeper insight into its polyphenolic composition. The compounds identified were mainly flavanols (a trimer and a galloylated dimer), flavonols (rutin and quercetin 3-O-glucuronide), stilbenes (trans-resveratrol and a resveratrol dehydrodimer) and a dihydroflavonol glycoside (astilbin).