Magnetically Controllable Silver Nanocomposite with Multifunctional Phosphotriazine Matrix and High Antimicrobial Activity

A recently developed multi‐functional phosphotriazine‐based polymer is used as a matrix for embedding γ‐Fe₂O₃ nanoparticles as well as a suitable chemical template for surface modification with silver nanoparticles. For the primary magnetic modification, maghemite nanoparticles are surface modified with oleic acid in order to render them organophilic and to prevent the aggregation of the nanoparticles. This aggregation could occur as the polymer synthesis, based on reaction of phosphonitrilic chlorine and 1,4‐phenylenediamine, takes place in toluene. The surface active amine units of the polymer structure enable the reduction of silver cations to silver nanoparticles, which are well attached and finely dispersed on its surface. The developed nanocomposite represents one of the few magnetically controllable antibacterial agents based on silver nanoparticles. Magnetic measurements reveal the completely suppressed interactions among maghemite nanoparticles because of their perfect surface coating with an organic surfactant and fine dispersion inside the polymer matrix. This magnetic nanocomposite exhibits a high antibacterial and antifungal activity as proven by tests with nine bacterial strains and four candida (yeast genus) species. For the majority of the tested species, the minimum‐inhibition concentrations are below 100 mg L^?1, which is comparable to their equivalent minimum‐inhibition concentrations in colloidal silver systems.     

Cornet‐Like Phosphotriazine/Diamine Polymers as Reductant and Matrix for the Synthesis of Silver Nanocomposites with Antimicrobial Activity

The synthesis of silver nanoparticles attached on the surface of a hollow cornet‐like polymer matrix which served as a reductant and host matrix is described. This hybrid organic/inorganic macromolecular matrix is exhibiting anion‐exchange properties, porous structure and hollow morphologies, and absorptions in the visible light region. Due to the anion‐exchange property and the 3D orientation of the macromolecular chains the material is defining a new functional organic/inorganic hybrid. For the synthesis of nanoparticles, no other reducing agents were used and silver nanoparticles with a mean diameter of less than 20 nm were attached on the surface of the polymer, thus inheriting the composite with high antibacterial activity tested in bacterial strains and yeasts.

     

Concentrations and patterns of organochlorine pesticides and PCBs in Mediterranean monk seals (Monachus monachus) from Western Sahara and Greece

Blubber from Mediterranean monk seals (Monachus monachus) from the Western Sahara coast (Atlantic), sampled during 1996-1999, and from the Greek coast (Mediterranean), sampled during 1995-1999, was analyzed for organochlorine pollutants (OCs). In both populations, no significant difference was found between sexes. In the Atlantic population, mature females presented greater percentages of higher chlorinated PCB (polychlorinated biphenyl) congeners in relation to total PCBs (sum of 25 congeners) than pups, indicating a differential transfer of PCB congeners through lactation. In the Mediterranean, the reduced sample size of adult individuals precluded proper statistical investigation of age-related variation. Significant differences in concentrations and pollutant patterns were found between populations. Thus, Mediterranean individuals presented significantly higher levels of HCB (hexachlorobenzene), tPCB, and DDTs (dichlorodiphenyltrichloroethane) concentrations and DDE/tDDT and tDDT/tPCB ratios than their counterparts from the Atlantic. Moreover, the relative proportion of different congeners in relation to the total PCB load (congener/tPCB) was also different between the two areas. The 100*tDDT/tPCB ratio in Atlantic seals was 38.46, which indicates a predominance of industrial inputs over those associated with agriculture. Conversely, in the Mediterranean seal population, the 100*tDDT/tPCB ratio was 177.1, denoting a proportionally higher contribution of pollutants of agricultural origin.     

Evaluation of the antiradical and reducing properties of selected Greek white wines: correlation with polyphenolic composition

The total hydroxycinnamate (THC) and total flavanol (TF) contents were determined in 26 selected Greek white wines of ‘Appellation of Origin of High Quality’ using well‐established spectrophotometric methodology. Furthermore, two parameters related to the antioxidant capacity of wines, the antiradical activity (A_AR) and the reducing power (P_R), were also determined using the stable DPPH· radical and a ferric reducing power assay respectively. THC content varied from 64.4 to 197.1 mg l^?1 chlorogenic acid equivalents (CGAE), whereas TF content exhibited larger variation, ranging from 3.3 to 205.3 mg l^?1 catechin equivalents (CTE). A_AR and P_R were found to range from 0.47 to 0.60 mM Trolox equivalents (TRE) and from 0.32 to 2.05 mM quercetin equivalents (QE) respectively. Regression analysis at 95% significance level indicated that reducing effects are likely to be exerted by the flavanol fraction (SF < 0.05), as opposed to antiradical efficiency which is primarily affected by the sum of THC and TF contents (SF < 0.05), suggesting that synergistic phenomena account for the overall antioxidant status of white wines. © 2002 Society of Chemical Industry     

Studies on the usability of recycled PET for food packaging applications

The need of and opportunities for recycling of plastics for food packaging have been recognized, and a lot of work to find meaningful and cost-effective solutions to this issue is in progress. The safety of recycled plastics for food contact use is largely dictated by the ability of post-consumer contaminants to absorb into recycled materials and later diffuse from recycled plastics into the food. The objective of the present study was to establish a suitable analytical approach to identifying and quantifying any chemical substances that derive from the earlier use and remain in the polyethylene terephthalate (PET). A simple gas chromatographic technique using flame ionization detection was developed to allow quantification of solvent extractable compounds in a series of recycled PET samples. Identification of the nature and extent of contaminants in the PET samples was also attempted using GC/MS analysis.     

Effects of Drying and Extraction Methods on the Quality and Antioxidant Activity of Sea Buckthorn (Hippophae rhamnoides) Berries and Leaves

Sea buckthorn is a promising source of bioactive compounds. However, there is limited information on the effect of post harvest drying and extraction of sea buckthorn on its antioxidant capacity. The effect of freeze, air, and solar dryingon the extraction yield of sea buckthorn berries and leaves was evaluated with respect to their bioactive content. Sequential extraction with solvents of different polarity and solvent-free microwave-assisted extraction were applied. Freeze-drying has better performance in the berries’ extracts, while air-drying has better performance in the leaves’ extracts. All data were analyzed by Multi Factor Analysis of Variance (ANOVA) and Duncan's post-hoc tests at a level of α = .05. Although the extraction yield in the sequential extraction of sea buckthorn berries is significantly better, the leaves’ extracts exhibit superior radical scavenging ability. Accelerated solar drying appears to preserve sea buckthorn leaves without degrading their antioxidant content. The components responsible for the high antioxidant activity of leaves’ extracts were found to be several flavonoids and polyphenols. The extract obtained by the microwave extraction of fresh berries exhibits moderate antioxidant activity compared to the polar extracts of freeze-dried berries.     

MIMO Channel Characterization for Short Range Fixed Wireless Propagation Environments

This paper reports results from wideband MIMO measurements performed in short range fixed wireless environments at 5.2 GHz. The objective is to provide MIMO channel characterization results for the measured environments and contribute to the limited available similar studies. Two kinds of propagation scenarios are investigated, rooftop to rooftop and street to rooftop, at three different sites always under LOS propagation conditions. The analysis of measurement data is performed in the context of non physical modeling, providing insight into the statistics of the measured channels. In particular, the slow time varying nature of the channel is studied and the narrow Doppler spectrum shape is approximated. Furthermore, frequency correlation results are obtained and the typical delay dispersion measures are extracted. Then, the antenna correlation is studied and the error of the Kronecker product approximation is evaluated. Finally, capacity results are provided and the channel measurements are characterized in terms of spatial multiplexing quality and multipath richness through condition number analysis. Nikolaos D. Skentos received his Diploma in Electrical and Computer Engineering from the National Technical University of Athens (NTUA), Greece in October 2000. Since January 2001 he has been a research associate at the Mobile Radio Communications Laboratory at the NTUA, and he is currently working towards the Ph.D. degree. His research interests include channel measurements, MIMO channel characterization, MIMO algorithms and space time processing. He has been active in the IST STINGRAY project, the COST 273 Action and the ACE Network of Excellence. He is also a member of the National Technical Chamber of Greece since 2001. Athanasios G. Kanatas received the Diploma in Electrical Engineering from the National Technical University of Athens, Greece, in 1991, the M.Sc. degree in Satellite Communication Engineering from the University of Surrey, Surrey, UK in 1992, and the Ph.D. degree in Mobile Satellite Communications from the National Technical University of Athens, Greece in February 1997. From 1993 to 1994 he was with National Documentation Center of National Research Institute. In 1995 he joined SPACETEC Ltd. where he was Technical Project Manager for VISA/EMEA VSAT Project in Greece. In 1996 he joined the Mobile Radio Communications Laboratory as a research associate. From 1999 to 2002 he was with the Institute of Communication & Computer Systems. In 2000 he became a member of the Board of Directors of OTESAT S.A. He is an Assistant Professor in the Department of Technology Education and Digital Systems at University of Piraeus. His current research interests include channel characterization and estimation, simulation and modeling for mobile, mobile satellite, and future wireless communication systems. He has been a Senior Member of IEEE since 2002, and is also a member of the Technical Chamber of Greece. In 1999 he was elected Chairman of the Communications Society of the Greek IEEE Section. Panagiotis I. Dallas was born 1967 in Thessaloniki, Greece. He obtained his diploma and Ph.D. degree from the Electrical and Computer Engineering Department of Aristotle University of Thessaloniki, Greece, in 1990 and 1997, respectively. Since 1998 he joined with INTRACOM where he currently is Section Manager of Advanced Communications Technologies branch of Emerging Technologies & Markets department, leading the next generation of broadband wireless access systems for internal and EU projects. He runs the relevant standardization activities (IEEE 802.16 and ETSI/BRAN HIPERMAN) in INTRACOM and he represents the company in WiMAX forum. Finally, he has over 30 publications in international journals and conferences. Philip Constantinou received the Diploma in Physics from the National University of Athens in 1972, the Master of Applied Science in Electrical Engineering from the University of Ottawa, Ontario, Canada in 1976, and the Ph.D. degree in Electrical Engineering in 1983 from Carleton University, Ottawa, Ontario, Canada. From 1976 to 1979 he was with Telesat Canada as a Communications System Engineer. In 1980 he joined the Ministry of Communications in Ottawa, Canada where he was engaged in the area of Mobile Communication. From 1984 to 1989 he was with the National Research Center Demokritos in Athens, Greece where he was involved in several research projects in the area of Mobile Communications. In 1989 he joined the National Technical University of Athens where he is currently a Professor and Director of the Mobile Radio Communications Laboratory. His current research interests include Personal Communications, Mobile Satellite Communications, and Interference Problems on Digital Communications Systems.