Synthesis and characterization of perfectly alternating polycarbonate‐polydimethylsiloxane multiblock copolymers possessing controlled block lengths

An array of perfectly alternating polycarbonate‐polydimethylsiloxane (PC‐PDMS) multiblock copolymers possessing systematic variations in block molecular weights were successfully produced by coupling preformed PC and PDMS telechelic oligomers using hydrosilylation. Based on gel permeation chromatography results, the multiblock copolymers were essentially void of the oligomeric precursors. Despite the relatively large difference in solubility parameter between PC and PDMS, the multiblock copolymers exhibited significant partial miscibility between the two phases. As expected, the degree of partial miscibility was dependent on the molecular weight of the blocks with the extent of partial miscibility increasing with decreasing block molecular weights. Morphological characterization using small angle X‐ray scattering showed that, at a given PC block molecular weight, the uniformity of the two phase morphology increased with increasing PDMS block molecular weight, which is consistent with a decrease in the extent of phase mixing with increasing PDMS block molecular weight. POLYM. ENG. SCI., 54:1648–1663, 2014. © 2013 Society of Plastics Engineers     

发动机均质压缩燃烧单区模拟模型及其应用

介绍一种基于燃料氧化反应动力学计算的单区模型,该模型由一维空间的质量守恒方程、动量守恒方程、能量守恒方程和气体状态方程等气相化学反应动力学控制方程所组成。采用该模型并利用二甲醚氧化的详细化学反应动力学机理,对二甲醚燃料在柴油机上的均质压缩燃烧HCCI进行了模拟计算和试验研究。计算结果与试验结果比较表明,该模型对HCCI燃烧的着火始点预测很好。     

On comparison of luminescence properties of La2Zr2O7 and La2Hf2O7 nanoparticles

Unveiling the underlying mechanisms of properties of functional materials, including the luminescence differences among similar pyrochlores A₂B₂O₇, opens new gateways to select proper hosts for various optoelectronic applications by scientists and engineers. For example, although La₂Zr₂O₇ (LZO) and La₂Hf₂O₇ (LHO) pyrochlores have similar chemical compositional and crystallographic structural features, they demonstrate different luminescence properties both before and after doped with Eu³⁺ ions. Based on our earlier work, LHO-based nanophosphors display higher photo- and radioluminescence intensity, higher quantum efficiency, and longer excited state lifetime compared to LZO-based nanophosphors. Moreover, under electronic O²⁻→Zr⁴⁺/Hf⁴⁺ transition excitation at 306 nm, undoped LHO nanoparticles (NPs) have only violet blue emission, whereas LZO NPs show violet blue and red emissions. In this study, we have combined experimental and density functional theory (DFT) based theoretical calculation to explain the observed results. First, we calculated the density of state (DOS) based on DFT and studied the energetics of ionized oxygen vacancies in the band gaps of LZO and LHO theoretically, which explain their underlying luminescence difference. For Eu³⁺-doped NPs, we performed emission intensity and lifetime calculations and found that the LHOE NPs have higher host to dopant energy transfer efficiency than the LZOE NPs (59.3% vs 24.6%), which accounts for the optical performance superiority of the former over the latter. Moreover, by corroborating our experimental data with the DFT calculations, we suggest that the Eu³⁺ doping states in LHO present at exact energy position (both in majority and minority spin components) where oxygen defect states are located unlike those in LZO. Lastly, both the NPs show negligible photobleaching highlighting their potential for bioimaging applications. This current report provides a deeper understanding of the advantages of LHO over LZO as an advanced host for phosphors, scintillators, and fluoroimmunoassays.     

A thermodynamically consistent framework for non-isothermal modelling of local heat generation and electromotive force in SOFC single electrodes

Mathematical models for single electrode reversible heat and non-isothermal electromotive force (EMF) of a solid oxide fuel cell (SOFC) are developed. These models estimate the volumetric reversible heat generation and EMF of electrochemical reactions, within each electrode at local conditions of temperature and pressure, based on entropy change of half reactions. The resulting equations are thermodynamically consistent. They inherently obey the conservation of energy law as the electrochemical energy released added to the heat of reactions at each electrode equate the enthalpy change of the reacted species. The equations are implemented to model electrodes in a tubular micro- solid oxide fuel cell (TμSOFC). The thermodynamic consistency of the model is numerically confirmed as the enthalpy of the reactants equates the electric energy released by the cell plus the sum of electrode heats plus electrolyte Ohmic heat. The effect of thermal gradients on the cell's overall EMF is found to be negligible. The reversible and irreversible heat generation of each electrode are distinguished. Overall, the anode is found to be endothermic, and the cathode exothermic.     

Taguchi analysis of surface modification technique using W-Cu powder metallurgy sintered tools in EDM and characterization of the deposited layer

The present study describes an experimental research on surface modification during electrical discharge machining (EDM) by depositing a hard layer over the work surface of C-40 grade plain carbon steel using specially prepared powder metallurgy compact tools. The investigated process parameters were composition, compaction pressure, sintering temperature, pulse on-time, peak?Ccurrent setting, and duty factor. Measurements of deposited layer thickness, mass transfer rate, tool wear rate, surface roughness and microhardness were undertaken on the EDM-ed specimens. Different studies like X-ray diffraction, optical microscopy, scanning electron microscopy, and energy dispersive X-ray spectroscopy were carried out to ascertain the characteristics of the deposited layer on the work surface. These analyses confirmed the presence of the tool materials in the work surface layer. At first, an L-16 orthogonal array was applied as Taguchi DOE technique and the ANOVA was done to study the effects of pertinent process parameters. An optimum condition was achieved using overall evaluation criteria. Later on, a detailed study was carried out to get a smooth and regular deposition of material. The characterization of the deposited layer is presented. The deposited layer with a wide range of average layer thickness of 3?C785???m, enriched with tool materials (W and Cu) and with the formation of tungsten carbide, and having microhardness of 9.81?C12.75?GPa at the hardest zone was successfully deposited over the work surface.     

Influence of martensite morphology on the work-hardening behavior of high strength ferrite–martensite dual-phase steel

This study concerns influence of martensite morphology on the work-hardening behavior of high-strength ferrite–martensite dual-phase (DP) steel. A low-carbon microalloyed steel was subjected to intermediate quenching (IQ), step quenching (SQ), and intercritical annealing (IA) to develop different martensite morphologies, i.e., fine and fibrous, blocky and banded, and island types, respectively. Analyses of work-hardening behavior of the DP microstructures by differential Crussard–Jaoul technique have demonstrated three stages of work-hardening for IQ and IA samples, whereas the SQ sample revealed only two stages. Similar analyses by modified Crussard–Jaoul technique showed only two stages of work-hardening for all the samples. Among different treatments, IQ route has yielded the best combination of strength and ductility due to its superior work-hardening behavior. The influence of martensite morphology on nucleation and growth of microvoids/microcracks has been correlated with the observed tensile ductility.     

Biodiesel production through hydrodynamic cavitation and performance testing

This paper presents the details of development of a biodiesel production test rig based on hydrodynamic cavitation followed by results of experimental investigation carried out on a four cylinder, direct injection water cooled diesel engine operating on diesel and biodiesel blend of Citrullus colocyntis (Thumba) oil. The experiment covers a wide range of engine rpm. Results show that biodiesel of Thumba oil produced through hydrodynamic cavitation technique can be used as an alternative fuel with better performance and lower emissions compared to diesel. The most significant conclusions are that (i) Biodiesel production through hydrodynamic cavitation technique seems to be a simple, efficient, time saving, eco-friendly and industrially viable process. (ii) 30% biodiesel blend of Thumba oil shows relatively higher brake power, brake thermal efficiency, reduced bsfc and smoke opacity with favourable p–θ diagram as compared to diesel.     

The inherent price of indulgence

An indulgent algorithm is a distributed algorithm that tolerates asynchronous periods of the network when process crash detection is unreliable. This paper presents a tight bound on the time complexity of indulgent consensus algorithms. We consider a round-based eventually synchronous model, and we show that any t-resilient consensus algorithm in this model, requires at least t+2 rounds for a global decision even in runs that are synchronous. We contrast our lower bound with the well-known t+1 round tight bound on consensus in the synchronous model. We then prove the bound to be tight by exhibiting a new t-resilient consensus algorithm in the eventually synchronous model that reaches a global decision at round t+2 in every synchronous run. Our new algorithm is in this sense significantly faster than the most efficient indulgent algorithm we know of, which requires 2t+2 rounds in synchronous runs. Our lower bound applies to round-based consensus algorithms with unreliable failure detectors such as ⋄ P and ⋄ S, and our matching algorithm can be adapted to such failure detectors. This work is partially supported by the Swiss National Science Foundation (project number 510-207).     

Two-dimensional bending and extension of cross-ply laminates with different moduli in tension and compression

Two-dimensional bending of cross-ply laminates is investigated. The basic equations for two-dimensional unsymmetric laminates are used. Simply supported rectangular plates subjected to uniform pressure are examined. Fourier series solutions are assumed for the displacements and iterative procedures are used to determine the location of the neutral axes with the maximum values occuring at large aspect ratios. At large aspect ratios, one neutral axis coincides with that obtained assuming cylindrical bending. The results show that there is significant variation of the location of the neutral axes at low aspect ratios and that the neutral axes do not coincide with each other nor with middle surface even at large aspect ratios.     

Design of Composite Surrogate Mirror Support Structure

Three multimaterial support structures were designed and built to support 200 mm (8 in.) diameter “surrogate” mirrors for the deployable optical telescope (DOT) ground experiment at the Air Force Research Laboratory (AFRL∕VS). A “spider-truss” structure was selected for its stiffness. Materials used included “Invar” alloy and AS4-epoxy composite rods manufactured by the “pultrusion” process, for their low thermal expansion coefficients, and aluminum for its machinability and low density. The composite rods were pultruded at AFRL∕VS, and their coefficients of thermal expansion (CTE) were determined by a laser interferometry method. Finite-element method (FEM) analysis of the vibration modes of the structure was conducted to determine the optimum selection of materials. FEM analyses were also used to determine the mirror surface figure errors caused by ±5°C temperature fluctuation, as a function of the materials chosen. The paper discusses the rationale for the materials selection and design issues.