Improved Performance of Molecular Bulk‐Heterojunction Photovoltaic Cells through Predictable Selection of Solvent Additives

Solvent additives provide an effective means to alter the morphology and thereby improve the performance of organic bulk‐heterojunction photovoltaics, although guidelines for selecting an appropriate solvent additive remain relatively unclear. Here, a family of solvent additives spanning a wide range of Hansen solubility parameters is applied to a molecular bulk‐heterojunction system consisting of an isoindigo and thiophene containing oligomer as the electron donor and [6,6]‐phenyl‐C₆₁‐butyric acid methyl ester (PC₆₁BM) as the electron acceptor. Hansen solubility parameters are calculated using the group contribution method and compared with the measured solubilities for use as a screening method in solvent additive selection. The additives are shown to alter the morphologies in a semipredictable manner, with the poorer solvents generally resulting in decreased domain sizes, increased hole mobilities, and improved photovoltaic performance. The additives with larger hydrogen bonding parameters, namely triethylene glycol (TEG) and N‐methyl‐2‐pyrrolidone (NMP), are demonstrated to increase the open circuit voltage by ~0.2 V. Combining a solvent additive observed to increase short circuit current, poly(dimethylsiloxane), with TEG results in an increase in power conversion efficiency from 1.4 to 3.3%.     

Ultra-Low-Power Interface Chip for Autonomous Capacitive Sensor Systems

Traditionally, most of the sensor interfaces must be tailored towards a specific application. This approach results in a high recurrent design cost and time to market. On the other hand, generic sensor interface design reduces the costs and offers a handy solution for multisensor applications. This paper presents a generic sensor interface chip (GSIC), which can read out a broad range of capacitive sensors. It contains capacitance-to-voltage converters, a switched-capacitor amplifier, an analog-to-digital converter, oscillators, clock generation circuits and a reference circuit. The system combines a very low-power design with a smart energy management, which adapts the current consumption according to the accuracy and speed requirements of the application. The GSIC is used in a pressure and an acceleration monitoring system. The pressure monitoring system achieves a current drain of 2.3 muA for a 10-Hz sample frequency and an 8-bit accuracy. In the acceleration monitoring system, we measured a current of 3.3 muA for a sample frequency of 10 Hz and an accuracy of 9 bits     

Beyond Cognitive Framing Processes: Anger Mediates the Effects of Responsibility Framing on the Preference for Punitive Measures

A new stream of research indicates that framing effects are based on emotional as well as cognitive processes. However, it is not entirely clear whether emotions mediate framing effects and what the moderators of emotional mediation processes are. To address these questions, we conducted an experiment in which the framing of responsibility for a social problem was manipulated (ambivalent vs. high‐responsibility frame). We find that the high‐responsibility frame increased the preference for punitive measures by increasing responsibility beliefs and eliciting anger. Furthermore, we find that trait anger moderates the framing effect on anger and that responsibility beliefs are positively associated with anger intensity. The significance of these findings for framing research and suggestions for future studies are discussed.     

Carbon‐Based Anodes for Lithium Sulfur Full Cells with High Cycle Stability

The lithium sulfur battery system has been studied since the late 1970s and has seen renewed interest in recent years. However, even after three decades of intensive research, prolonged cycling can only be achieved when a large excess of electrolyte and lithium is used. Here, for the first time, a balanced and stable lithium sulfur full cell is demonstrated with silicon–carbon as well as all‐carbon anodes. More than 1000 cycles, a specific capacity up to 1470 mAh g^?1 _sulfur (720 mAh g^?1 _cathode), and a high coulombic efficiency of over 99% even with a low amount of electrolyte are achieved. The alternative anodes do not suffer from electrolyte depletion, which is found to be the main cause of cell failure when using metallic lithium anodes.     

Highly Robust Indium‐Free Transparent Conductive Electrodes Based on Composites of Silver Nanowires and Conductive Metal Oxides

A hybrid approach for the realization of In‐free transparent conductive layers based on a composite of a mesh of silver nanowires (NWs) and a conductive metal‐oxide is demonstrated. As metal‐oxide room‐temperature‐processed sol–gel SnO_x or Al:ZnO prepared by low‐temperature (100 °C) atomic layer deposition is used, respectively. In this concept, the metal‐oxide is intended to fuse the wires together and also to “glue” them to the substrate. As a result, a low sheet resistance down to 5.2 Ω sq^‐1 is achieved with a concomitant average transmission of 87%. The adhesion of the NWs to the substrate is significantly improved and the resulting composites withstand adhesion tests without loss in conductivity. Owing to the low processing temperatures, this concept allows highly robust, highly conductive, and transparent coatings even on top of temperature sensitive objects, for example, polymer foils, organic devices. These Indium‐ and PEDOT:PSS‐free hybrid layers are successfully implemented as transparent top‐electrodes in efficient all‐solution‐processed semitransparent organic solar cells. It is obvious that this approach is not limited to organic solar cells but will generally be applicable in devices which require transparent electrodes.     

Single Cell Bioprinting with Ultrashort Laser Pulses

Tissue engineering requires the precise positioning of mammalian cells and biomaterials on substrate surfaces or in preprocessed scaffolds. Although the development of 2D and 3D bioprinting technologies has made substantial progress in recent years, precise, cell-friendly, easy to use, and fast technologies for selecting and positioning mammalian cells with single cell precision are still in need. A new laser-based bioprinting approach is therefore presented, which allows the selection of individual cells from complex cell mixtures based on morphology or fluorescence and their transfer onto a 2D target substrate or a preprocessed 3D scaffold with single cell precision and high cell viability (93–99% cell survival, depending on cell type and substrate). In addition to precise cell positioning, this approach can also be used for the generation of 3D structures by transferring and depositing multiple hydrogel droplets. By further automating and combining this approach with other 3D printing technologies, such as two-photon stereolithography, it has a high potential of becoming a fast and versatile technology for the 2D and 3D bioprinting of mammalian cells with single cell resolution.     

Key-Recovery Attacks on <Emphasis FontCategory="SansSerif">ASASA</Emphasis>

The \(\mathsf {ASASA}\) construction is a new design scheme introduced at Asiacrypt 2014 by Biryukov, Bouillaguet and Khovratovich. Its versatility was illustrated by building two public-key encryption schemes, a secret-key scheme, as well as super S-box subcomponents of a white-box scheme. However, one of the two public-key cryptosystems was recently broken at Crypto 2015 by Gilbert, Plût and Treger. As our main contribution, we propose a new algebraic key-recovery attack able to break at once the secret-key scheme as well as the remaining public-key scheme, in time complexity \(2^{63}\) and \(2^{39}\), respectively (the security parameter is 128 bits in both cases). Furthermore, we present a second attack of independent interest on the same public-key scheme, which heuristically reduces the problem of breaking the scheme to an \(\mathsf {LPN}\) instance with tractable parameters. This allows key recovery in time complexity \(2^{56}\). Finally, as a side result, we outline a very efficient heuristic attack on the white-box scheme, which breaks instances claiming 64 bits of security under one minute on a laptop computer.