A flexible thin-film for powering stand alone electronic devices

This paper presents a flexible thin-film (FTF) composed by a photovoltaic (PV) cell, a flexible solid-state rechargeable battery and power management electronics. A flexible printed circuit board (fPCB) was used for providing physical support to the electronics and to the battery, whereas a PDMS (polydimethylsiloxane) layer was used for providing mechanical adhesion between the PV cell and the fPCB. The high elasticity of the PDMS makes this material an excellent candidate for adapting two materials with different thermal expansions (fPCB and PV). The physical measurements showed a prototype with a thickness in the range 1.52 ± 0.10 mm, 10 g of weight and 37 × 114 mm of size. The electrical measurements showed ability to provide an output voltage of 3.8 V in a continuously form under these conditions: the PV providing DC power for solar irradiations higher than 6 W m⁻², and the battery providing DC power for solar irradiations above bellow 6 W m⁻² (value that has emerged during the twilight between sunset and dusk).     

Pollution of inland waters in Brazil: the case for goal-oriented initiatives

This article examines the use of output-based aid and payment for environmental services to reduce water pollution in Brazil. Two nationwide initiatives are reviewed. First, the output-based aid concept of the River Basin Clean-up Programme (PRODES) to tackle the problem of sanitation deficit in urban areas is presented. Second, the payment for environmental services scheme supported by Brazil’s National Water Agency (ANA) through the Water Producer Programme to promote water conservation on rural properties is discussed. Both programmes are evaluated not only as financing mechanisms for water conservation but also as strategies for implementing Brazil’s water policy.     

Development of an Autonomous Robot for Gas Storage Spheres Inspection

Inspection for corrosion of gas storage spheres at the welding seam lines must be done periodically. Until now this inspection is being done manually and has a high cost associated to it and a high risk of inspection personel injuries. The Brazilian Petroleum Company, Petrobras, is seeking cost reduction and personel safety by the use of autonomous robot technology. This paper presents the development of a robot capable of autonomously follow a welding line and transporting corrosion measurement sensors. The robot uses a pair of sensors each composed of a laser source and a video camera that allows the estimation of the center of the welding line. The mechanical robot uses four magnetic wheels to adhere to the sphere’s surface and was constructed in a way that always three wheels are in contact with the sphere’s metallic surface which guarantees enough magnetic atraction to hold the robot in the sphere’s surface all the time. Additionally, an independently actuated table for attaching the corrosion inspection sensors was included for small position corrections. Tests were conducted at the laboratory and in a real sphere showing the validity of the proposed approach and implementation.     

Integration of virtual and real environments for engineering service-oriented manufacturing systems

Engineering frameworks are currently required to support the easy, low-cost, modular and integrated development of manufacturing systems addressing the emergent requirements of re-configurability, responsiveness and robustness. This paper discusses the integration of 2D/3D digital software tools with Petri net based service-oriented frameworks to allow the design, configuration, analysis, validation, simulation, monitoring and control of manufacturing systems in a virtual environment and its posterior smooth migration into the real ??physical?? environment. An experimental case study was implemented to validate the proposed concepts, using the Continuum platform to design, compose, analyze, validate and simulate the Petri nets based service-oriented manufacturing control system, and the Delmia Automation^TM software suite to support the rapid prototyping and the easy simulation of the designed control solution. The experimental results prove several aspects of the proposed approach, notably the smooth migration between the design and the operation phases, one of the main objectives of the work.     

Acoustic evaluation and adjustment of an open-plan office through architectural design and noise control

Arranging office space into a single open room offers advantages in terms of easy exchange of information and interaction among coworkers, but reduces privacy and acoustic comfort. Thus, the purpose of this work was to evaluate the acoustic quality of a real open-plan office and to propose changes in the room to improve the acoustic conditioning of this office. The computational model of the office under study was calibrated based on RT and STI measurements. Predictions were made of the RT and STI, which generated the radius of distraction r(D), and the rate of spatial decay of sound pressure levels per distance doubling DL(2) in the real conditions of the office and after modifications of the room. The insertion of dividers between work stations and an increase in the ceiling's sound absorption improved the acoustic conditions in the office under study.     

MODEL‐REFERENCE OUTPUT‐FEEDBACK SLIDING MODE CONTROLLER FOR A CLASS OF MULTIVARIABLE NONLINEAR SYSTEMS

This paper proposes an output‐feedback sliding mode control design for a class of uncertain multivariable plants with nonlinear disturbances. The approach used here is based on the control parameterization employed in model‐reference adaptive control. The disturbances are allowed to be unmatched and to depend not only on the plant output but also on its unmeas‐urable state. A less restrictive condition on the uncertainty of the high frequency gain matrix is also obtained.     

A new approach to designing reduced scale thermal-hydraulic experiments

Reduced scale experiments are often employed in engineering because they are much cheaper than real scale testing. Unfortunately, though, it is difficult to design a thermal-hydraulic circuit or equipment in reduced scale capable of reproducing, both accurately and simultaneously, all the physical phenomena that occur in real scale and operating conditions. This paper presents a methodology to designing thermal-hydraulic experiments in reduced scale based on setting up a constrained optimization problem that is solved using genetic algorithms (GAs). In order to demonstrate the application of the methodology proposed, we performed some investigations in the design of a heater aimed to simulate the transport of heat and momentum in the core of a pressurized water reactor (PWR) at 100% of nominal power and non-accident operating conditions. The results obtained show that the proposed methodology is a promising approach for designing reduced scale experiments.     

Preparation of polypropylene‐based nanocomposites using nanosized MCM‐41 as support and in situ polymerization

MCM‐41 nanoparticles were used for preparing nanocomposites through the in situ polymerization of propylene. The performance of the catalytic system and the final properties of the materials obtained are highly dependent on the methodology used for impregnation of the catalyst onto the support particles, and therefore an optimization study for the impregnation methodology of the catalyst (Me₂Si(Ind)₂ZrCl₂) was carried out. Two different methodologies were used; the results in terms of catalytic activity and polymer molecular masses indicated that the most promising one involved the pre‐activation of the catalyst with the cocatalyst, methylaluminoxane, followed by impregnation onto the MCM‐41 nanoparticles. Thus, an optimized route for the preparation of polypropylene nanocomposites achieving significant improvements in catalyst activity was developed. The nanocomposite materials were characterized by GPC, TGA and DSC. The dispersion state and the size of the nanoparticles incorporated in the polypropylene matrix were investigated by transmission electron microcopy. Additionally, this methodology allows simultaneous control of the desired amount of support and the concentration of catalyst to be used in the in situ polymerization. © 2015 Society of Chemical Industry     

Influence of mesostasis in volcanic rocks on the alkali-aggregate reaction

Mesostasis material present in the interstices of volcanic rocks is the main cause of the alkali-aggregate reaction (AAR) in concretes made with these rock aggregates. Mesostasis often is referred to as volcanic glass, because it has amorphous features when analyzed by optical microscopy. However, this study demonstrates that mesostasis in the interstitials of volcanic rocks most often consists of micro to cryptocrystalline mineral phases of quartz, feldspars, and clays. Mesostasis has been identified as having different characteristics, and, thus, this new characterization calls for a re-evaluation of their influence on the reactivity of the volcanic rocks. The main purpose of this study is to correlate the characteristics of mesostasis with the AAR in mortar bars containing basalts and rhyolites.