Simulating the impact of kraft pulping and bleaching parameters on Eucalyptus camaldulensis pulp properties using MATLAB

In this work, Eucalyptus camaldulensis was evaluated as the raw material for chemical pulp under different pulping and bleaching conditions. The pulping was carried out at different H‐factors, and at different effective alkalis. The resulting pulps were then oxygen delignified and bleached using various dosages of bleaching chemicals in a D₀EpD₁ sequence. The effect of independent variables (pulping or bleaching variables) on dependent variables (pulp properties) was analysed based on the multivariable least square method via MATLAB software. An agreement was found between the results predicted from the models and the experimental data. To obtain a kappa number of 15, the optimum pulping conditions were a temperature of 155°C, a time of 225 min, and an EA of 23%. Also, the hexenuronic acid (HexA) content of cooked pulp was significantly decreased in the chlorine dioxide bleaching stages, and was only marginally related to the final HexA content of bleached pulps.     

Closed-Form Model and Parametric Study on Connection of Concrete-Filled FRP Tubes to Concrete Footings by Direct Embedment

Concrete-filled fiber-reinforced polymer (FRP) tubes (CFFTs) have been introduced as a new system for piles, columns, and poles. A simple moment connection based on direct embedment of the CFFT into concrete footings or pile caps, without using dowel-bar reinforcement, has been proposed by the authors. Robust analytical models to predict the critical embedment length (Xcr) were also developed and experimentally validated. In this paper, a comprehensive parametric study is carried out using the models developed earlier along with a newly developed closed-form model for the general case of axial loading, bending, and shear applied to the CFFT member. The parameters studied are the diameter (D), thickness (t), length outside the footing (L), and laminate structure of the FRP tube, as well as the tube-concrete interface bond strength (τmax?), concrete compressive strength in the CFFT (fct′) and footing (fc′), and the magnitude and eccentricity of axial compressive or tensile loads. It was shown that increasing D, L/D, τmax?, and fc′ of the footing, or the axial compression load, reduces (X/D)cr, whereas increasing t and fct′ of the CFFT, the fraction of longitudinal fibers in the tube, or the axial tension load, increases Xcr. As the axial load eccentricity increases, Xcr reduces for tension loads and increases for compression loads until both cases converge asymptotically to the same Xcr value, essentially that of pure bending.     

Effects of increased milking frequency for the first 21 days post partum on selected measures of mammary gland health, milk yield and milk composition

Somatic cell count (SCC) is a widely used marker of udder health and a predictor of inflammation caused by an immune response. The objective of this study was to determine whether selected measures of mammary gland health as well as milk fatty acid profile were altered by an increase in milking frequency using a unilateral frequent milking (UFM) model. Holstein cows at parturition were assigned to UFM, in which the left udder half of each cow was milked four-times daily (4X) and the right udder half was milked twice daily (2X) for the first 21 days in milk (DIM). Milk yields from each udder half were measured from 1-21 DIM and samples were collected on days 3, 7, 10, 14 and 21 for determination of SCC and milk composition. Flow cytometric analysis with bovine monoclonal antibodies was used to identify milk immune cell populations and milk fatty acid (FA) composition was determined using gas chromatography. Gene expression analysis was used to determine whether there was an alteration in mRNA expression of genes involved in milk fat production including lipoprotein lipase (LPL) and FA-binding protein 3 (FABP3) with ribosomal protein S9 (RPS9) as a house-keeping gene. No difference was detected for milk SCC or cell populations between the udder halves milked 4X as compared with the udder halves milked 2X. In addition, no difference was detected for any FA in milk from the udder half milked 4X as compared with the udder half milked 2X. Overall, using a UFM model, increased milking frequency for the first 21 DIM did not affect selected measures of mammary gland health or milk FA, but was associated with greater milk yield, milk fat percent and yield, and milk protein and lactose yields.     

Evaluation of multi-tone signal in the presence of the pre-distortion lineariser

In this article, analysis of a linearised travelling tube amplifier (TWT) using multi-tone signal under the digital modulation schemes is presented. The pre-distortion lineariser circuit based on the Schottky diodes is used to compensate for the nonlinear behaviour of the TWT amplifier in the noisy channel. The stability of the TWTA in combination with the lineariser has also been investigated through simulations. The 4-QAM and QPSK modulators are utilised and applied before linearised TWTA and capture results. The data passing through the linearised TWTA is analysed by using advanced design system (ADS). Constellation and eye diagrams are obtained from different modulation schemes and compared with each other in the same environment. Finally, the bit-error-rate (BER) performance of the system is evaluated using Monte Carlo estimation for three different values of input-back-off (IBO). It is shown that the performance is improved by applying the proposed signal pre-distortion lineariser.     

Determination of Proper Austenitization Temperatures for Hot Stamping of AISI 4140 Steel

High strength steels are desirable materials for use in automobile bodies in order to reduce vehicle weight and increase the safety of car passengers, but steel grades with high strength commonly show poor formability. Recently, steels with controlled microstructures and compositions are used to gain adequate strength after hot stamping while maintaining good formability during processing. In this study, microstructure evolutions and changes in mechanical properties of AISI 4140 steel sheets resulting from the hot stamping process at different austenitization temperatures were investigated. To determine the proper austenitization temperatures, the results were compared with those of the cold-worked and cold-worked plus quench-tempered specimens. Comparisons showed that the austenitization temperatures of 1000 and 1100 °C are proper for hot stamping of 3-mm-thick AISI 4140 steel sheets due to the resultant martensitic microstructure which led to the yield and ultimate tensile strength of 1.3 and 2.1 GPa, respectively. Such conditions resulted in more favorable simultaneous strength and elongation than those of hot-stamped conventional boron steels.     

Generalized uncertainty principle and the Ramsauer-Townsend effect

The scattering cross-section of electrons in noble gas atoms exhibits a minimum value at electron energies of approximately 1 eV. This is the Ramsauer-Townsend effect. In this letter, we study the Ramsauer-Townsend effect in the framework of the Generalized Uncertainty Principle.     

Effect of Preheating Inlet Air and Acid Gas on the Performance of Sulfur Recovery Unit—CFD Simulation and Validation

Forschung im Ingenieurwesen - Combustion temperature is a key factor that directly influences the performance of a sulfur recovery unit (SRU); the prevalent low temperatures in...     

Use of Functionalized Metallocene Copolymers from Ethylene and Polar Olefins as Compatibilizers for Low‐Density‐Polyethylene/Starch and Low‐Density‐Polyethylene/Dextran Blends

Summary: Functionalized metallocene copolymers synthesized from ethylene with 5‐hexen‐1‐ol and ethylene with 10‐undecen‐1‐ol were used as compatibilizers in LDPE/starch and LDPE/dextran blends in order to improve the interfacial adhesion between hydrophobic LDPE and hydrophilic natural polymers. An increase in tensile modulus and a slight decrease in tensile strength was observed when poly[ethylene‐co‐(10‐undecen‐1‐ol)] was added to a 70:30 wt.‐% LDPE/dextran blend, whereas the addition of poly[ethylene‐co‐(5‐hexen‐1‐ol)] as compatibilizer resulted in obtaining a more rigid material with a slightly higher modulus. Scanning electron microscopy of modified dextran blends containing 3 wt.‐% of both compatibilizers showed some degree of phase cocontinuity. Enhanced interfacial adhesion and decrease in particle size of starch was observed when 5 wt.‐% of poly [ethylene‐co‐(5‐hexen‐1‐ol)] copolymer was used as the compatibilizer in starch blends. The crystallization temperature of LDPE, determined by DSC, was shifted to a slightly higher temperature as a consequence of the addition of the compatibilizers. The existence of phase segregation was also revealed by thermal analysis when 5 wt.‐% of the copolymers were used as blend modifiers.

SEM micrograph of 70:30 wt.‐% LDPE/dextran blend with added poly[ethylene‐co‐(5‐hexen‐1‐ol)] compatibilizer.     

Lignin for polymer and nanoparticle production: Current status and challenges

In pulp production processes, lignin is generated in large quantities as a by‐product. It is often burned to generate heat and electricity. Despite the large‐scale production of lignin, its utilization in high‐value applications has remained a challenge. Recently, the production of lignin nanoparticles (LNP) and lignin polymers has gathered attention. The potential to use LNPs as reinforcement filler, UV absorbent, antioxidant, and drug carrier has been reported, while lignin polymers might be suitable for the production of composites, hydrogels, flocculants, and coagulants. This review paper provides insights into the production and application of LNP and lignin polymers. In addition, the challenges associated with the characterization and use of these products are comprehensively reviewed.