新型碳质催化剂用于NH3选择性催化还原NOx的研究

以城市污水处理厂剩余污泥为原料制备了一种新型碳质催化剂。通过试验考察了催化剂在NH₃选择催化还原NO中的应用效果。结果表明,催化性能较好，最佳的制备和催化反应条件为：锌铁物质的量比1∶0.5，热解温度750 ℃，反应温度400 ℃，O₂浓度15%。在此条件下，NOx的最大转化率达98.3%。通过考察证明催化剂自身具有一定的还原性能。对催化剂进行了FTIR、TG、SEM和BET分析，结果表明，催化剂具有很丰富的孔结构、活性粒子和表面官能团，比表面积较大，最大可达307 m²·g^-1，分析结果显示具有良好的催化条件。     

Industrial TiO2 based nacreous pigments as functional building materials: Photocatalytic removal of NO

In this paper, the photocatalytic activity of industrial titanium dioxide (TiO₂) based nacreous pigments was researched as functional building materials for photocatalytic NO remove. Three industrial TiO₂ based nacreous pigments were selected to estimate the photocatalytic activity for NO remove. This study is a good proof that pearlescent pigments can eliminate NO, and its performance is positively correlated with its titanium dioxide content. And this research will widen the application of nacreous pigments in functional building materials, and provide a new way to eliminate in door nitric oxide pollution.     

联苯型双醚二酐的合成及其表征

以4,4′二羟基联苯(联苯二酚)和N甲基4硝基邻苯二甲酰亚胺为主要原料,在非质子性溶剂中,经缩合得到联苯双醚二酞酰亚胺,再经水解、酸化、脱水等工艺制得联苯型双醚二酐(BPEDA)。通过红外光谱对产品进行了表征,结果符合要求。该单体与4,4′二氨基二苯醚(ODA)在N,N二甲基乙酰胺(DMAc)中缩聚所得聚酰胺酸特性粘度为0.72dL/g。将PI制成薄膜,室温下拉伸强度为98.5MPa,成膜性能良好。     

Effect of Pretreatment Atmosphere on CuO/TiO2 Activities in NO + CO Reaction

Using TiO₂ as carrier, CuO/TiO₂ catalysts with different CuO loading were prepared by the impregnation method. The catalytic activities in NO+CO reaction were examined with a micro-reactor gas chromatography reaction system and the methods of TPR, XPS and NO-TPD. It was found that the catalytic activities were affected by pretreatment atmosphere, i.e. H₂ atmosphere > reduction–reoxidation > 10%CO/He > reaction gas (fresh sample). NO decomposition was better by low-valence Cu species than by high-valence Cu species, i.e. Cu⁰>Cu⁺>Cu²⁺. The XPS results indicated that Cu species on CuO/TiO₂ were Cu⁰, Cu⁺, normal Cu²⁺(Cu²⁺(I)) and chain-structured Cu²⁺(Cu²⁺(II)) as –Cu–O–Ti–O–. The activities of Cu²⁺(II) were much higher than that of Cu²⁺(I), but both species were very unstable in the reaction atmosphere and easily reduced by CO, which accounted for the variable activities of fresh catalysts with increasing reaction temperature. In NO+CO reaction, the redox process was a cycle of Cu⁺–Cu²⁺(I) at low reaction temperature but was a cycle of Cu⁰–Cu⁺ at high reaction temperature. As shown by NO-TPD, high catalytic activities could be attributed to the following factors, e.g. oxygen caves on the catalyst’s surface after pretreatment with H₂ and reduction–reoxidation, formation of Cu⁰ after pretreatment with H₂, and increment of Cu species dispersion and formation of Cu²⁺(II) after pretreatment with reduction–reoxidation.     

基于仿真卡的通用1553B总线测试软件设计

1553B总线通信是航天器终端设备的重要功能,在研制各阶段,对设备的总线通信功能进行测试是必不可少的。基于总线仿真卡进行二次开发,提出一种通用1553B总线测试软件设计方法,采用总线消息描述文件和设备参数描述文件分别描述总线消息和设备参数,设计通用程序模块,使软件代码不依赖总线消息或设备参数的具体定义。所述方法已在某航天器多个分系统测试中得以应用。     

细胞固定化催化生产精细化学品的研究进展Q

摘要：细胞固定化技术具有流程简单、生物相容、操作稳定等优点，可有效保证细胞活性，实现高效的细胞催化生产精细化学品。本文介绍了表面附着、凝胶包埋、聚电解质层层自组装膜等多细胞固定化方法，及其在二元醇、生物乙醇、乳酸、酯、多糖等精细化学品生产中的研究现状和进展，并分析讨论了各种方法存在的问题。同时，总结了近年来新发展的单细胞纳米涂层固定化方法的机理、趋势及应用于精细化学品生产的可能性。最后对细胞固定化催化生产精细化学品面临的技术挑战及研究方向做出展望，以期为精细化学品生产提供一定的技术支持。     

垂直筛板塔流体力学与传质研究状况

对我国在新型垂直筛板塔的流体力学性能 ,诸如塔板干板压降与湿板压降、板孔漏液、塔板过量雾沫夹带、板上帽罩单元的液体提升能力与液体循环程度的研究及其传质性能 ,诸如塔板传质效率模型、塔板空间气相中液体大小与分布、板间空间立体传质作用的研究等进行了综合 ,并予以分析论述 ,从中看出我国对新型垂直筛板塔已进行了较全面深入的研究工作 ,并取得了新进展。     

等离子硅刻蚀及其工艺参数的多尺度优化

用CFD-ACE+和CFD-TOPO分别对容性耦合等离子体反应腔室放电和等离子硅刻蚀过程进行仿真,讨论不同射频电压和腔室条件对等离子体特性的影响.结果表明:随着射频电压的升高,离子的通量增大;在低射频电压时,离子通量随腔室压强的升高而减小,而在高射频电压时趋势则相反.用Kriging模型对影响刻蚀形貌的参数(腔室压强和射频电压)进行优化,结果表明该优化方法可以为工艺条件相近的刻蚀机设备的设计提供参考.     

模数对无机富锌涂料和涂层性能的影响

硅酸钾富锌涂料是目前广泛使用的钢铁防腐蚀涂料。作为涂料粘结剂的高模数硅酸钾溶液对涂料和涂层的性能有重要影响。本研究考察了硅酸钾粘结剂的模数变化对涂料及涂层性能产生的影响。实验结果表明：粘结剂模数的提高可以提高固化后涂层的耐水性能，当粘结剂模数在5.0左右时，所得富锌涂层具有最佳的耐磨性能，但当粘结剂模数超过5.5时会造成涂料施工性能和贮存稳定性下降，涂层柔韧性降低，从而降低涂层的耐磨性能。     

聚天冬氨酸的合成与表征

以L-天冬氨酸为原料,热缩合成聚天冬氨酸酐,水解得到聚天冬氨酸。采用凝胶色谱法(GPC)测定了聚天冬氨酸的分子量,并用核磁共振(NMR)对其进行了表征。