固体超强酸S_2O_8~(2-)/SnO_2-SiO_2催化合成环己酮1,2-丙二醇缩酮

采用沉淀-浸渍法制备了固体超强酸S2O28-/SnO2-SiO2,以它为催化剂催化环己酮和1,2-丙二醇合成了环己酮1,2-丙二醇缩酮;考察了带水剂种类及用量、酮醇摩尔比、催化剂用量、反应时间对产品收率的影响,并用正交实验对反应条件进行了优化。实验结果表明,适宜的反应条件为:n(环己酮)∶n(1,2-丙二醇)=1∶1.6、催化剂用量为反应物料总质量的2.0%、带水剂环己烷用量5.0mL、反应时间50min。在此条件下,环己酮1,2-丙二醇缩酮收率达到91.47%;催化剂的稳定性良好,在重复使用5次后环己酮1,2-丙二醇缩酮收率为82.20%,活性下降的主要原因为催化剂表面积碳和吸附了有机物;经傅里叶变换红外光谱和气相色谱质谱分析表明,产物为环己酮1,2-丙二醇缩酮,纯度为100%。     

Electron microscopic observations and DNA chain fragmentation studies on apoptosis in bone tumor cells induced by ~(153)Sm-EDTMP

ＥｌｅｃｔｒｏｎｍｉｃｒｏｓｃｏｐｉｃｏｂｓｅｒｖａｔｉｏｎｓａｎｄＤＮＡｃｈａｉｎｆｒａｇｍｅｎｔａｔｉｏｎｓｔｕｄｉｅｓｏｎａｐｏｐｔｏｓｉｓｉｎｂｏｎｅｔｕｍｏｒｃｅｌｓｉｎｄｕｃｅｄｂｙ１５３ＳｍＥＤＴＭＰＺｈｕＳｈｏｕＰｅｎｇ，Ｘｉａ...     

Study on phase behavior–impact strength relationship of unsaturated polyester/polyurethane hybrid polymer network

The phase behavior of a hybrid polymer network (HPN) composed of poly[(propylene glycol maleate)-co-(propylene glycol phthalate)] crosslinked with styrene and polyester–urethane crosslinked with methylene-bis-ortho-chloroaniline was examined. The correlation between phase separation and impact strength of the HPNs is discussed. The composition of HPNs has an effect on their properties.     

Lubricating behavior of iron rhenate and its relation to matching pairs

The iron rhenate was compounded by chemical method, which may be generated during wear process of Fe-Re alloys at elevated temperature. The friction coefficient of iron rhenate has been determined by a pin-on-disc device. The results show that iron rhenate plays role of lubricating at RT-600 °C. The lubricating behavior is related to the matching pairs. The hardness of the materials of matching pairs, compatibility of iron rhenate with materials of matching pairs and surface roughness of disc affect the lubricating behavior of iron rhenate mostly. The principle of matching pairs is proposed. Project supported by the National Natural Science Foundation of China Synopsis of the first author Xiong Dangsheng. associated professor, born in 1960. Current research fields include high-temperature self-lubricating alloys and tribological properties of material.     

InGaAs（P）分别限制应变单量子阱激光器的优化设计

针对较常用的ＩｎＧａＡｓ（Ｐ）分别限制应变单量子阱激光器，给出了为得到最大净增益的优化设计参数。对于激射波长为１．５５μｍ的无应变激光器，最佳的光限制层波长为１．２４μｍ，厚度为１００ｎｍ。当阱材料引入压缩应变后．由于价带的有效状态密度减小，量子阱激光器的微分增益变大，阱深的增大对增大线性增益的效果更加明显．所以最佳光限制层的波长将变短，为１．２０μｍ     

Influence of China‘s WTO Entry on Petroleum Taxation

China has formulated a series of preferential taxation policies for the country 's petroleum enterprises. Those state policies are the important factors influencing reform and development of petroleum enterprises. The taxes turned over to the State by CNPC in 1998, 1999 and 2000 are 31.4 billion yuan, 31.7 billion yuan and 41 billion yuan respectively, accounting for 11.64 percent, 9.06 percent and 10.15 percent of the annual sales income.With China 's entry into WTO, it is necessary for t…     

控制棒钴吸收体的活度分布

应用单组中子微扰理论,对辐照后控制棒钴吸收体内活度分布进行理论分析,得到活度分布计算的解析表达式。对高通量工程试验堆(HFETR)首次出堆的2根控制棒钴吸收体进行数值计算。利用钴靶活度水下测量装置进行这2根钴吸收体活度分布的实验测量。计算与实验测量结果相符。通过理论计算所得到的活度分布可作为辐照后~(60)Co同位素分装依据。本文得到的控制棒相对价值曲线理论计算值与实验测量结果符合良好。     

Anaerobic digestion of alkaline black liquor using an up-flow anaerobic sludge blanket reactor

The anaerobic digestion of alkaline black liquor from a cereal straw pulping mill was studied in batch (serum bottles) and continuous systems (up-flow anaerobic sludge blanket reactor—UASB). The batch digestion studies confirmed that lignin and related compounds (LRC) in the alkaline black liquor were the main inhibitory substances and could not be decomposed by anaerobic bacteria. At organic loading rates of 5–10 kg COD m^?3 day^?1, the UASB reactor achieved 50–60% COD removal efficiencies. Gas production was 2–3 dm³ per dm³ of alkaline black liquor. Two different sludge types were examined in the reactor: granular and cluster-like sludges. Sludge in a cluster, which involved many small granules and flocs, tended to form larger aggregates and possessed good settling ability.     

Site occupations and ordering behaviour of O phase in Ti2AlNb—based intermetallics

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