This paper presents a mathematical model based on the reaction rate expressions to describe the displacement of methane conversion in the steam reforming. The effect of several parameters including weight hourly space velocity (WHSV), load-to-surface ratio, reaction pressure, hydrogen partial pressure in permeate side and reaction temperature were investigated. Simulation and experimental results showed that a conversion higher than 80% could be achieved in a palladium membrane reactor at reaction temperature of 500 °C relative to 850 °C in a conventional fixed bed reactor (FBR). Besides, the yield of CO (<2%) in membrane reactor was much lower than that (>50%) in the FBR, which indicated the significant depression of CO production in use of membrane reactor. 相似文献
A mathematical model of fluid flow and mass transfer in a packed bed was derived and used to evaluate the liquid phase axial dispersion and mass transfer coefficients under high pressure conditions. The least-squares method was used to evaluate the rate parameters from experimental breakthrough curves, and the agreement between the concentration curves predicted from rate parameters and those measured experimentally was good. Experiments were performed at 20 and 200°C with water as a solvent and nonporous soda-lime glass beads as packing. Although the axial dispersion coefficient was independent of temperature and pressure, the mass transport parameters were found to be pressure dependent. 相似文献
The viscoelastic properties of a rubber–resin blend, which influences performance of the blend as a pressure-sensitive adhesive, depend upon the structure of the resin as well as its molecular weight. The effect of the concentration of a compatible resin in the blend was examined using a mechanical spectrometer. Four types of resins were used. These are the rosin esters, polyterpenes, pure monomer resins such as polystyrene and poly(vinyl cyclohexane), and petroleum stream resins. Each was examined in blends with both natural rubber and styrene–butadiene rubber over a range of concentrations. It is shown that the temperature of the tan δ peak for compatible systems can be predicted by the Fox equation, T = W1T + W2T, where W1 and W2 are the weight fractions of the resin and rubber, respectively, and the Tg's are the tan δ peak temperatures in K. The plateau modulus G for a blend can be identified as the G′ value in the rubbery plateau at the point where tan δ is at a minimum. The relationship between G and G, the plateau modulus for the undiluted elastomer, is shown to be proportional to the volume fraction of the elastomer raised to the 2.3–2.4 power for natural rubber with six different compatible resins. The exponent for styrene–butadiene rubber is 2.5–2.6 with four different resins. Using these relationships, both the tan δ peak temperature and plateau modulus can be predicted for a rubber–resin system from data on the unmodified elastomer and on one typical rubber–resin blend. 相似文献
The satellite-based regression model provides the data model that identifies water quality for inland and coastal waters. However, the satellite regression usually depends on the selection of observation, satellite data, and model type. A resampling simulation technique, such as sequential simulation using geographically weighted regression (GWR simulation), can be applied in generating multiple realizations for water quality estimation to reduce the sampling effect and consider spatial heterogeneity. Traditional models often result in considerable underestimation in extreme observations. The GWR simulation provides the best goodness of fit and spatial varying relationship between observed water quality and remote sensing considering parameter outlier and noise removal for parameter stability. This simulation model can increase the sampling diversity from various observations and reduce the neighboring effects of observations using outlier and noise removal. The model that handles spatial uncertainty and heterogeneity is a novel tool for inferring the characteristics of water quality from a series of sample subsets.
Experimental tests show that static pre-loading has a significant effect on the dynamic strength of concrete.Based on meso-scale particle element model,numerical simulations of dynamic bending tests with pre-loading are performed.Complete stress–strain relationships are then obtained.Significant increase in dynamic strength is found when the pre-loadings are imposed within the elastic limit of concrete.However,when the imposition of pre-loadings reaches the plastic or softening range,dynamic strengths may gradually decrease along with the increase in pre-loadings.The distribution of energy components and the failure modes are discussed to explain the mechanisms of the phenomena. 相似文献
The applicability of the rapid iodide migration test was systematically studied. Comparative experimental tests of different test conditions, including several external voltages, test durations, concrete ages and mixing proportions, were carried out to make clear the transport behaviors of iodide under parallel electric fields. Numerical simulations were also done using the finite element method to found the correlation between chloride and iodide transport behaviors. The test and numerical results show that the chloride transport behaviors of RIM and RCM tests have a good correlation under the several conditions used in the present paper. Moreover, the influence of external conditions (external voltages, test durations) on the test results is small. Thus, it can be concluded that the RIM method is available to determine the chloride penetration resistance of the chloride-eroded structural concrete. 相似文献