Long-Term Planning of WDM Networks: A Comparison between Single-Period and Multi-Period Techniques

This paper studies the long-term planning (e.g. a planning horizon of 2 to 5 years) of survivable WDM networks. The problem is formulated as a multi-period model that combines network topology and capacity expansion. The ability to determine network expansion schedules of this type becomes increasingly important to the telecommunications industry and to its customers. Two inherently different solution methods are presented: a sequential single-period approach, which designs the networks for every time period separately in chronological order, and an integrated multi-period approach, which considers all time periods at once. For each of these approaches, different network design cost models can be applied. Extensive simulations on a wide range of problem instances are carried out, to measure the influence of the applied network design cost model and to assess the cost savings that can be expected by opting for a multi-period planning approach instead of a sequential network design method.     

A novel,efficient route for the crosslinking and creep improvement of high modulus and high strength polyethylene fibres

A new route is presented for the chemical crosslinking of solution‐spun, ultra‐drawn Ultra‐High‐Molecular‐Weight Polyethylene (UHMW‐PE) fibres. UHMW‐PE fibres with a range of draw ratio's, Young's moduli and tensile strengths were impregnated with a radical initiator using supercritical carbon dioxide as a carrier. After impregnation, the drawn fibres were crosslinked with ultra‐violet light and fibres with a high gel content (> 90%) were obtained. It was found that the chemical crosslinking strongly reduces the plateau creep rate of the fibres and that the threshold stress for irreversible creep is enhanced. Simultaneously, the high Young's modulus and the high tensile strength of the drawn fibres are preserved which illustrates that the long term properties of the fibres (i. e. creep) are improved without a large sacrifice short term mechanical properties such as Young's modulus.     

Domain size-induced heterogeneity as performance limitation of small-domain monolithic columns and other LC support types

We have computed the band broadening and the flow resistance in a series of apparently self-similar porous LC support structures, all having the same mean geometric ratios and external porosity, but with a decreasing scale and disturbed by a scale-independent variance on the size and position of the porous solid zone elements. The study shows in a general and qualitative way that each type of LC support that is produced using a manufacturing process displaying a fixed (i.e., domain-size independent) variance on the size and position of the produced solid zone elements will eventually encounter a limit beyond which a further reduction of the domain size can no longer be expected to yield a significant gain in separation speed. This is currently observed in practice for silica monoliths and could also compromise the performance of photolithographically etched columns.     

Intercomparison of reflectances observed by GOME and SCIAMACHY in the visible wavelength range

We compare the Earth reflectances of the spectrometers Global Ozone Monitoring Experiment (GOME) and Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) over their overlapping wavelength range (240-800 nm). The goal is to investigate the quality of the radiometric calibration of SCIAMACHY using calibrated GOME data as a reference. However, severe degradation of the GOME instrument in the UV since 2001 prevents it from being a reliable reference below 500 nm. Above 500 nm, GOME is reliable and we find substantial disagreement between GOME and SCIAMACHY, of the order of 15%-20%, which we can attribute completely to the current calibration problems of SCIAMACHY. These numbers are supported by a previous study in which SCIAMACHY was compared with the imager Medium Resolution Imaging Spectrometer (MERIS) onboard the Envisat satellite.     

Radiolabeled gelatin type B analogues can be used for non-invasive visualisation and quantification of protein coatings on 3D porous implants

This study covers the quantification of the covalent attachment of gelatin type B (GelB) and the subsequent adsorption of Fibronectin (Fn) on poly-ε-caprolactone (PCL) surfaces, functionalised with 2-aminoethyl methacrylate (AEMA) by means of post-plasma UV-irradiation grafting. As typical surface characterisation tools do not allow quantification of deposited amounts of GelB or Fn, radiolabeled analogues were used for direct measurement of the amount of immobilized material. Bolton-Hunter GelB (BHG) and Fn were radioiodinated with (131)I and (125)I respectively and S-Hynic GelB (SHG) was labeled with (99m)Tc. Immobilisation of (131)I-BHG or (99m)Tc-SHG on both PCL and PCL-AEMA scaffolds was performed in analogy with earlier work. SPECT images on scaffolds coated with (99m)Tc-SHG conjugates were acquired on a U-SPECT II camera. There was a clear difference in the amount of deposited (131)I-BHG between blanco and AEMA-grafted PCL on 2D samples. No significant differences in immobilization behaviour were observed between (99m)Tc-SHG and (131)I-BHG. Subsequent immobilisation of Fn was successful and depended on the amounts of deposited GelB. SPECT imaging on cylindrical 3D scaffolds confirmed these findings and showed that the amount of immobilized (99m)Tc-SHG was depth dependant. The architecture of the scaffolds strongly influences the distribution of GelB within these structures. Furthermore, there is a clear difference in the homogeneity of the protein coating when different GelB immobilization protocols were applied. This study shows that radiolabeled compounds are a rapid and accurate tool in the quantitative and qualitative evaluation of the biofunctionalisation of AEMA grafted PCL scaffolds.     

Improving the utilization factor of a PEM electrolyzer powered by a 15 MW PV park by combining wind power and battery storage – Feasibility study

So far, the biggest photovoltaic park in Belgium has been injecting all its energy into the electric distribution grid through a power purchase agreement with an electricity supplier. Due to decreasing and volatile wholesale electricity prices, the industrial partners/owners of the photovoltaic park are considering hydrogen storage in an attempt to increase the value proposition of their renewable energy installation. A major objective of the present work is to show how the utilization factor of the electrolyzer is affected by the design of the power supply system when the latter consists only of renewable energy sources instead of using the electric grid. Different hybrid designs were developed, by combining the existing photovoltaic source with wind power and state-of-the-art energy storage technologies (Vanadium Redox Flow or Lithium NMC). Finally, four scenarios were investigated, all considering a 1 MW PEM electrolyzer: A) 15 MW PV, B) 15 MW PV, 2MW Wind, C) 15 MW PV, 2 MW Wind, Battery, D) 15 MW PV, 15 MW Wind. The utilization factor was found as follows, for each scenario respectively: A) 41,5%, B) 65,5%, C) 66,0–86,0%, D) 82,0%. Furthermore, the analysis was extended to include economic evaluations (i.e. payback period, accumulated profit), specifically concerning scenario B and C. The results of this study lead to a number of conclusions such as: i) The utilization of the electrolyzer is limited when its power supply is intermittent. ii) Compared to PV, wind power makes larger contribution to the increase of the utilization factor, iii) 100% utilization can be achieved only if an energy storage system co-exists. iv) With a utilization factor at 65,5% scenario B can deliver a payback period in less than 8 years, if hydrogen is sold above 5€/kg. An analytic overview of all conclusions is presented in the last section of the paper.     

In vitro cell-biological performance and structural characterization of selective laser sintered and plasma surface functionalized polycaprolactone scaffolds for bone regeneration

In the present study a structural characterization and in vitro cell-biological evaluation was performed on polycaprolactone (PCL) scaffolds that were produced by the additive manufacturing technique selective laser sintering (SLS), followed by a plasma-based surface modification technique, either non-thermal oxygen plasma or double protein coating, to functionalize the PCL scaffold surfaces. In the first part of this study pore morphology by means of 2D optical microscopy, surface chemistry by means of hydrophilicity measurement and X-ray photoelectron spectroscopy, strut surface roughness by means of 3D micro-computed tomography (CT) imaging and scaffold mechanical properties by means of compression testing were evaluated before and after the surface modifications. The results showed that both surface modifications increased the PCL scaffold hydrophilicity without altering the morphological and mechanical properties. In the second part of this study the in vitro cell proliferation and differentiation of human osteoprogenitor cells, over 14 days of culture in osteogenic and growth medium were investigated. The O₂ plasma modification gave rise to a significant lower in vitro cell proliferation compared to the untreated and double protein coated scaffolds. Furthermore the double protein coating increased in vitro cell metabolic activity and cell differentiation compared to the untreated and O₂ plasma PCL scaffolds when OM was used.     

Optimising installation (R,Q) policies in distribution networks with stochastic lead times: a comparative analysis of guaranteed- and stochastic service models

This paper studies two modelling approaches to the multi-echelon inventory optimisation problem in a distribution network with stochastic demands and lead times. It compares the performance of a novel guaranteed-service model (GSM), using an installation (R, Q) inventory control policy, with a stochastic service model (SSM) considering ordering, holding and flexibility costs. From both cycle service level and fill rate perspectives, our numerical analysis of the 1-warehouse 2-retailer network shows that cost difference between both models is driven by the internal service level at the warehouse. The GSM outperforms the SSM for over 80% of the simulated instances and realises an average total cost improvement of approximately 10%. This analysis goes against earlier results that showed a relatively low-cost difference between the two approaches, and demonstrates that it is worthwhile to evaluate competing models for multi-echelon inventory optimisation in real-world supply chains with batch ordering and variable lead times.     

Modeling of branching density and branching distribution in low-density polyethylene polymerization

Low-density polyethylene (ldPE) is a general purpose polymer with various applications. By this reason, many publications can be found on the ldPE polymerization modeling. However, scission reaction and branching distribution are only recently considered in the modeling studies due to difficulties in measurement and computation of scission effect and branchings of polymer. Our previous papers [Kim, D.M., et al., 2004. Molecular weight distribution modeling in low-density polyethylene polymerization; impact of scission mechanisms in the case of CSTR. Chemical Engineering Science 59, 699-718; Kim, D.M., Iedema, P.D., 2004. Molecular weight distribution modeling in low-density polyethylene polymerization; impact of scission mechanisms in the case of a tubular reactor. Chemical Engineering Science, submitted for publication] are concerned with the scission reaction during ldPE polymerization and its effect on molecular weight distribution (MWD) of ldPE for various reactor types. Here we consider branching distributions as a function of chain length for CSTR and tubular reactor processes. To simultaneously deal with chain length and branching distributions, the concept of pseudo-distributions is used, meaning that branching distributions are described by their main moments. The computation results are compared with properties of ldPE samples from a CSTR and a tubular reactor. Number and weight average branchings and branching density increase as chain length increases until the longest chain length. The concentrations of long chain branching (LCB) are close to those of first branching moment in both CSTR and tubular reactor systems. The branching dispersity, a measure for the width of the branching distribution at a certain chain length, has the highest value at shorter chain length and then monotonously decreases approaching to 1.0 as chain length increases. Excellent agreements in branching dispersities between calculation with branching moments and prediction with assumption of binomial distribution for a tubular reactor and CSTR processes show that the branching distribution follows a binomial distribution for both processes.     

Experimental study of porous silicon shell pillars under retentive conditions

Experimental measurements of the retention capacity and the band broadening in perfectly ordered porous shell pillar array columns are presented for a wide range of retention conditions and layer thicknesses. The porous silicon shells were obtained using electrochemical anodization of the solid silicon pillars obtained using deep reactive ion etching. Using 10-microm-wide pillars, minimal reduced plate height values of the order of h(min) = 0.4-0.5 were obtained under nonretained conditions, even in cases where the outer shell made up 20% of the total diameter. Under retained conditions, minimal plate heights around h(min) = 0.9 were obtained, even at retention factors up to k' = 12. Using a model based on Giddings nonequilibrium theory, and using a newly calculated value for the stationary zone configuration factor for the case of porous shell cylinders, a plate height model describing the band broadening in porous shell pillar arrays has been established. The validity of this model is demonstrated by showing that the geometrical parameters appearing in the model and fitted using band-broadening measurements under nonretained conditions can be used to relatively accurately predict the band broadening under retained component conditions. Using this model, some speculations on the ultimate performance of porous pillar array columns could be made.